• Title/Summary/Keyword: regeneration energy

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Catalytic Oxidation of Aromatic Compounds over Spent Ni-Mo and Spent Co-Mo based Catalysts: Effect of Physico-chemical Pretreatments (폐 Ni-Mo 및 폐 Co-Mo계 촉매상에서 방향족 화합물의 촉매산화: 물리화학적 전처리 효과)

  • Shim, Wang Geun;Kang, Ung Il;Kim, Chai
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.63-70
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    • 2010
  • Transition metal based spent catalysts (Ni-Mo and Co-Mo), which were scrapped from the petrochemical industry, were reused for the removal processes of volatile organic compounds (VOCs). Especially the optimum regeneration procedures were determined using the removal efficiency of VOCs. In this work, the spent Ni-Mo and spent Co-Mo catalysts were pretreated with different physic-chemical treatment procedure: 1) acid aqueous solution, 2) alkali solution, 3) chemical agent and 4) steam. The various characterization methods of spent and its regenerated catalysts were performed using nitrogen adsorption, X-ray diffraction (XRD) and scanning electron microscopy (SEM) equipped with an energy dispersive spectrometry (EDS). It was found that all spent catalysts were found to be potentially applicable catalysts for catalytic oxidation of benzene. The experimental results also indicated that among the employed physico-chemical pretreatment methods, the oxalic acid aqueous (0.1 N, $C_2H_2O_4$) pretreatment appeared to be the most efficient in increasing the catalytic activity, although the catalytic activity of spent Ni-Mo and spent Co-Mo catalysts in the oxidation of benzene were greatly dependent on the pretreatment conditions. The pretreated spent catalysts at optimum condition could be also applied for removing other aromatic compounds (Toluene/Xylene).

Performance Evaluation of Absorbent Solution for Draw Solute Recovery in Forward Osmosis Desalination Process (정삼투식 담수공정의 유도용질 회수를 위한 흡수용액 성능 평가)

  • Kim, Young;Lee, Jong Hoon;Lee, Kong Hoon;Kim, Yu-Chang;Oh, Dong Wook;Lee, Jungho
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.240-244
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    • 2013
  • Although forward osmosis desalination technology has drawn substantial attention as a next-generation desalination method, the energy efficiency of its draw solution treatment process should be improved for its commercialization. When ammonium bicarbonate is used as the draw solute, the system consists of forward-osmosis membrane modules, draw solution separation and recovery processes. Mixed gases of ammonia and carbon dioxide generated during the draws solution separation, need to be recovered to re-concentrate ammonium bicarbonate solution, for continuous operation as well as for the economic feasibility. The diluted ammonium bicarbonate solution has been proposed as the absorbent for the draw solution regeneration. In this study, experiments are conducted to investigate performance and features of the absorption corresponding to absorbent concentration. It is concluded that ammonium bicarbonate solution can be used to recover the generated ammonia and carbon dioxide. The results will be applied to design and operation of pilot-scale forward-osmosis desalination system.

The Research for effect of lubricant oil aging on environmental performance (자동차 윤활유의 성상 및 열화가 환경성에 미치는 영향 연구)

  • Kim, Jeong-Hwan;Kim, Ki-Ho;Ha, Jong-Han;Jin, Dong-Young;Myung, Cha-Lee;Jang, Jin-Young
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.12-24
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    • 2017
  • The main purpose of this research is for the investigation on the impact of engine oil aging on PM and DPF. It is widely known that lubricant specifications and consumption from an ICE have significantly influenced on the regulated and unregulated harmful emissions as the engine operating conditions. Considering DPF clogging phenomena with lubricant-derived soot/ash components, simulated aging mode for the DPF was newly designed for engine dynamometer testing. PM/ash accumulation cycle were developed in reflecting real-world engine operating conditions for the increment of engine oil consumption and natural DPF regeneration for the ash accumulation. The test duration for DPF aging reached around 100hrs with high- and low-SAPS engine oils, respectively. Using high SAPs engine oil made more PM/ash accumulation compared with low SAPs engine oils and it could accelerate fouling of EGR in engine. Fouling of EGR made effects on more harmful exhaust gases emissions. The test results on engine lubricant under engines operating conditions will deliver for the establishment of regulated and unregulated toxic emissions policy, lubricant quality standard.

Study on design methods for museum restoration of modern architecture - Centering on cases of restoration modern architecture which fulfilled its epochal function to museum - (근대건축물의 뮤지엄 재생을 위한 디자인방법에 관한 연구 - 시대적 기능을 다한 근대건축물이 뮤지엄으로 재생된 사례를 중심으로 -)

  • Kim, In-Seob;Lee, Sung-Hoon
    • Korean Institute of Interior Design Journal
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    • v.20 no.3
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    • pp.215-224
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    • 2011
  • Throughout the world, interest in issues relevant to energy, resources, environment, etc, is ever soaring. Therefore, the restoration of modern architecture that fulfilled its epochal function is working as a cultural, historic medium. In addition, it also plays its role in the side of environmental approach and so on. Moreover, the museum, which was only used for the possession of art collections and exhibition purposes, is currently expanding its scale and range as the center of culture and education. Also in reality, with the use of various programs, it is globally pursuing urban vitalizations. This study looks at the meaning of modem architecture restoration as well as its relationship with urban area. Furthermore, the purpose of this study is to look for design method's direction by finding the relevance between modem architecture restoration and museum during the restoration. This study is based on transformation and preservation scale during the restoration of modern architecture. It analyzed plane and design direction. Additionally, this study analyzed the architectural and regional effect caused by restoration. As a result, in accordance with the direction of museum and the usage, scale, structure as well as superficial aging condition of previous architecture, it shows difference in design methods in the process of restoration. The exterior of architecture was restored and preserved to its original form in order to show the symbolical form through historical value. This is essential to the modern museum. On the other hand, the interior of architecture put more value on utilization concept that its preservation and thus was restored accordingly. However, in all the cases, previous architecture were commonly used and even when alterations and additions were made due to aging and their change in usage, they were restored in a way that preserved and harmonized previous architecture. If the design method for restoration of modern architecture selects the restoration method by considering problems related to location, building value, structure, if it is studied from various angles and is restored after considering its usage as a museum, then we will be able to generate cultural and historical synergy effect. Furthermore, apart from architecture, it will have great impact on urban vitalizations.

A study on the Changes in form and spatial uses of Urban Hanok in Bukchon, Seoul (서울 북촌한옥의 변화양상에 관한 연구 - 북촌 가꾸기 사업에 따른 2002~2007 한옥 대수선 사례를 대상으로 -)

  • Song, In-Ho;Kim, Young-Soo;Cho, Eun-Joo
    • Journal of architectural history
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    • v.18 no.2
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    • pp.47-63
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    • 2009
  • This study focused on changes in form and spatial uses of Urban Hanok in Bukchon, Seoul. There are 10 representative cases which have been renovated through the policy of 'Preservation & Regeneration of Bukchon' by Seoul metropolitan government and other experts. Changes in form and spatial uses of Urban Hanok in Buckon are as follows. First, Changes of scale. Trough removing extension parts, facade of renovated Hanoks are 'transformed' into recovering their identity. Using basements or lofts, intensive application of spaces is transformation which promotes the vitality of Hanoks. Second, changes of space organization. As Hanok changes its function from residence to commercial or cultural use, il a1so changes space character or reorganizes space organization. It is important that deciding function of Hanok has to adjust its scale and organization. Third, changes of construction performance. Through introducing new material and constructing method, performance of wall has been changed respecting its wooden structure and interior-exterior figure. However, technical studies must back it up not to destroy its value of eco-friendly architecture. Fourth, changes of facility systems, like floor heating system. They changes floor level of Hanok equally, and then sections of Hanok have became simple. Furthermore, inserting new facility space, such as boiler room, stand-up kitchen, bathroom and toilet, organization of space also changed. It is necessary that wise alternative proposal through the method of transformation or mutation must be presented. These four changes can be classification into method of 'transformation' and 'mutation'. Changes of scale are method of transformation and changes of space organization are method of mutation. Also, while changes of construction performance are mutation, changes of facility systems are transformation. Recently, as price of lots have been increased, a lot of Hanoks have been commercialized. Thc commercial energy threat 'the identity of Bukchon as residential area'. From now on, to operate 'identity' and 'vitality' complementary, it is necessary to make up for the preservation policy of Hanok and consolidate renovating standards of Hanok which correspond to character of particular region and building usage.

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A Study of the Diagnosis of Downtown Deterioration in Busan (부산시 도심 노후화 진단에 관한 연구)

  • Kwon, Il-Hwa;Nam, Kwang-Woo
    • Journal of the Korean Association of Geographic Information Studies
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    • v.16 no.4
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    • pp.39-53
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    • 2013
  • Although the efficient formation of urban space structure is a key factor in energy saving and environmentally-friendly aspect, the maintenance of the center and sub-center of the city that are key factors has been becoming increasingly difficult due to the variability and complexity of urban activities. In the case of Busan, amid the expansion of urban scale due to rapid economic development and overpopulation, systematic approaches to professional diagnosis and maintenance have been significantly insufficient - other than the city basic plan which has been conducted at an interval of 20 years. For the effective management of urban central area, systematic monitoring of the CBD through demand forecast and blight forecast at a city level must first be implemented. In order to fulfill this goal, this study is to figure out the current state of the CBD through the diagnosis on blight of the urban central area in the viewpoint of rehabilitation of the CBD and to propose the measures for practical utilization of the information about space for the further management of the central area of the city. For analysis, the study looks into the present state in terms of physical index, economic index, and social index. And then as a micro-approach by utilizing economic index, the study has thoroughly examined the economic blight of the Seomyun urban central area of Busan. The outcome of the analysis shows that in terms of population distribution and land utilization the area is in the stage of inefficient dispersion after having gone through the stage of suburbanization. It is expected that this study, as the material that proves the necessity of enhancing the function of the CBD, can propose the direction for the management of the urban center of Busan through blight prediction and management of the urban center and can provide the basic data for the long-term urban development that aims at the efficient strengthening of functions of the CBD.

Growth Characteristics and Physiological Adaptation of Pinus densiflora Seedling in the Canopy Gap (소나무 묘목(苗木)의 Gap내 생장(生長) 및 생리적(生理的) 적응과정(適應過程))

  • Jin, Yonghuan;Lee, Don Koo
    • Journal of Korean Society of Forest Science
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    • v.89 no.3
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    • pp.452-460
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    • 2000
  • This study was to investigate the growth characteristics, physiological adaptation of Pinus densiflora(Japanese Red Pine) seedlings at the artificial canopy gap in the Quercus acutissima plantation and to analyze its natural regeneration mechanism. Photosynthetic and transpiration rates were analyzed by different levels of photosynthetically active radiation and by seedling growth. Comparing to seedlings at the open area, those at the canopy gap showed more growth in height than in diameter with different levels of light quality and low light intensity, and the increase rate of dry weight was higher in the aboveground than in the underground, maintaining relatively high T/R rate. The C/F(the ratio of non-photosynthetic organs to photosynthetic organs in dry weight) of the aboveground at the canopy gap was higher than that at the open area by 0.1~0.2, while light saturation and light compensation points at the canopy gap were lower than that at the open area by $300{\mu}mol\;m^{-2}s^{-1}$ and 40%, respectively. The seedlings appeared to have shade tolerance to a certain extent at the young growth stage despite Pinus densiflora is typically classified shade-intolerant species. With light intensity lower than $400{\sim}450{\mu}mol\;m^{-2}s^{-1}$, photosynthetic rate and water use efficiency relatively increased by effective use of light energy.

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Healing Effects of Squalene on the Epidermis in Burned Mouse (생쥐의 화상에 미치는 Squalene의 치료 효능)

  • Kim, Jong-Se;Kim, Jeong-Sang;Yoon, Jung-Sik;Choi, Young-Bok;Cho, Kwang-Phil;Kim, Jae-Sung;Chung, Su-Man
    • Applied Microscopy
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    • v.29 no.2
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    • pp.163-175
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    • 1999
  • The purpose of this experiment was to know the healing effects of saualene on the burned mouses. The experimental groups were divided into seven groups: the control group, the burned groups, and 50 treated groups after burned. All groups except the control group burned with second degree on a dorsoanterior part. All groups that treated with 50 adapted three drops of pure squalene at 10 seconds interval; one time a day. The histological and ultrastructural changes during 10 days after burned were observed by light and electron microscope. Under the light microscope, all parts of epidermal layer of the burned groups were wounded deeper than the 50 treated groups. At 6 and 10 days groups with 50 treated, especially 10 days, the basal layer was greatly differentiated, and the prickle cells in the spinous layer were greatly increased in number. Under the electron microscope, the cell divisions of basal layer in all groups that treated with 50 were more activated and rapidly regenerated than the all burned groups. Especially, some fantastic results obtained from the 10 days group with SQ treated; much thicker spinous layer than the control group, many prickle cells, fine intercellular bridges, and healthy basal layer contained melanocytes. These results suggest that squalene may active the epidermis growth factor (EGF), acts as scavenger, and provide sources of energy in the membrane system. The results of this experiment consider that squalene has specific effects for burn healing and regeneration.

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Development of Adsorbent for Vapor Phase Elemental Mercury and Study of Adsorption Characteristics (증기상 원소수은의 흡착제 개발 및 흡착특성 연구)

  • Cho, Namjun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.5
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    • pp.1-6
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    • 2021
  • Mercury, once released, is not destroyed but accumulates and circulates in the natural environment, causing serious harm to ecosystems and human health. In the United States, sulfur-impregnated activated carbon is being considered for the removal of vapor mercury from the flue gas of coal-fired power plants, which accounts for about 32 % of the anthropogenic emissions of mercury. In this study, a high-efficiency porous mercury adsorption material was developed to reduce the mercury vapor in the exhaust gas of coal combustion facilities, and the mercury adsorption characteristics of the material were investigated. As a result of the investigation of the vapor mercury adsorption capacity at 30℃, the silica nanotube MCM-41 was only about 35 % compared to the activated carbon Darco FGD commercially used for mercury adsorption, but it increased to 133 % when impregnated with 1.5 % sulfur. In addition, the furnace fly ash recovered from the waste copper regeneration process showed an efficiency of 523 %. Furthermore, the adsorption capacity was investigated at temperatures of 30 ℃, 80 ℃, and 120 ℃, and the best adsorption performance was found to be 80 ℃. MCM-41 is a silica nanotube that can be reused many times due to its rigid structure and has additional advantages, including no possibility of fire due to the formation of hot spots, which is a concern when using activated carbon.

Research Trends on the Therapeutic Potential of Cordycepin, an Active Ingredient of the Insect Fungus Cordyceps spp., for the Prevention of Sarcopenia (동충하초(Cordyceps spp.)의 유효 생리활성 성분인 cordycepin의 근감소증 예방에 대한 연구 동향)

  • Kim, Sung Ok;Choi, Yung Hyun
    • Journal of Life Science
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    • v.32 no.6
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    • pp.482-490
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    • 2022
  • Sarcopenia, a geriatric and multifactorial syndrome characterized by progressive systemic skeletal muscle disorder, may be associated with many comorbidities. Sarcopenia caused by a decrease in muscle mass and muscle strength is accompanied by the aggravation of various pathological conditions, and as life expectancy increases, its prevalence will continue to increase in the future. During the aging process, chronic oxidative stress and increased inflammatory responses act as major contributors to skeletal muscle loss. In addition, disruption of autophagy and apoptosis signals associated with dysfunction of mitochondria, which are essential for energy metabolism, accelerates the loss of muscle proteins. The pharmacological effect of cordycepin, a major physiologically active substance in the genus Cordyceps, which has been widely used for the prevention and treatment of various diseases for a long time, is directly related to its antioxidant and anti-inflammatory actions. In this review, we present the correlation between apoptosis, autophagy, protein catabolism, and satellite cell activity important for muscle regeneration using cordycepin for the prevention and treatment of sarcopenia. Although there have been few studies so far on the use of cordycepin for sarcopenia, previous studies suggest that cordycepin may contribute to inhibiting the age-related weakening of mitochondrial function and blocking the breakdown of muscle proteins. In addition, the protective effect of cordycepin on muscle cell damage is considered to be closely related to its antioxidant and anti-inflammatory activities. Therefore, it is considered that more continuous basic research is needed, focusing on the molecular biological mechanism of cordycepin, which is involved in the anti-aging of muscle cells.