• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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• pp.590-597
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• 2003

Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

• 대한임상독성학회지
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• 제2권1호
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• pp.31-36
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• 2004

Three workers, field operators in lubricating oil processing of petroleum refinery industry were found unconscious by other worker. One of them who were exposed to an high concentration of H2S was presented with Glasgow Coma Score of 5, severe hypoxemia on arterial blood gas analysis, normal chest radiography, and normal blood pressure. On hospital day 7, his mental state became clear, and neurologic examination showed quadriparesis, profound spasticity, increased tendon reflexes, abnormal Babinski response, and bradykinesia. He was also found to have decreased memory, attention deficits and blunted affect which suggest general cognitive dysfunction, which improved soon. MRI scan showed abnormal signals in both basal ganglia and motor cortex, compatible with clinical findings of motor dysfunction. Neuropsychologic testing showed deficits of cognitive functions. SPECT showed markedly decreased cortical perfusion in frontotemporoparietal area with deep white matter. Another case was recovered completely, but the other expired the next day.

• 한국자원리싸이클링학회:학술대회논문집
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• 한국자원리싸이클링학회 2003년도 추계정기총회 및 국제심포지엄
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• pp.22-34
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• 2003

Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 가을 학술논문 발표대회
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• pp.107-108
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• 2021

In the global trend of countries around the world announcing the declaration of carbon neutrality, the development of low-carbon cement in the cement industry can be seen as a very important issue that can determine the future development of the cement industry in the future. Therefore, this study evaluated the strength characteristics of limestone cement paste with limestone powder of CaCO3 and refinery desulfurization waste catalyst of high Al₂O₃ content, and using a Minitab mixture design to optimize a limestone cement content. As a resuls it was confirmed that limestone cement paste with 5-10% of limestone powder and 1.25-2.5% of the waste catalyst exhibits similar compressive strength to that of OPC.

• 대한화학회지
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• 제12권2호
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• pp.47-50
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• 1968

Dowex $1{\times}4$ 陰이온 交煥樹指를 二段階(높이:下段 22cm, 上段 3cm, 直經 1.5cm)로 充塡하여 비스머스 金屬中에 들어있는 不純物인 Pb(II), Ag(I), Cu(II)를 7.5M 鹽酸으로, 그리고 Zn(II), Fe(III)를 0.5M 鹽酸으로 分離하고 上段에 남아있는 Te(IV)은 2M NaOH 용액으로 容出하고 아직도 上段에 남아있는 Au(III)는 樹脂를 태워서 分離하였다. 또 한가지 方法은 같은 樹脂를 10cm 높이로 一段階의 管에 充塡하여 0.5M 鹽酸으로 Pb(II), Ag(I), Cu(II), Fe(III), Zn(II)를 함께 容出하여 비스머스 中에서 分離하였다. 分離된 모든 不純物은 比色法으로 定量하였다.

• 한국환경보건학회지
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• 제43권1호
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• pp.55-63
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• 2017

Objectives: This study estimated the emission quantity of benzo(a)pyrene(BaP) produced by fuel combustion in the Seosan area, and analyzed the uncertainty regarding the emissions. Methods: It was based on data from a national agency and from public institutions. Emissions were estimated by using national-level guidelines. The total estimated emissions were analyzed by performing Monte Carlo analysis. Results: The full emission quantity of BaP which was discharged by fuel combustion in the Seosan area stood at 1,194.79 g/yr. The point source emissions came to 184.16 g/yr (95% CI; 158.40-209.39). The line source emissions reached 315.33 g/yr (95% CI; 284.99-344.03). The area source emissions accounted for 695.31 g/yr (95% CI; 605.10-793.88). Chemical and compound manufacturing was the highest with 639.13 g/yr (95% CI; 542.95-728.24) in terms of emissions and oil refinery emissions were high with 153.10 g/yr (95% CI; 129.19~177.46). It was found in the Seosan area that the major source of BaP is the manufacturing of chemicals and chemical products. Conclusion: The emission quantity of BaP which was discharged by the fuel combustion in Seosan area reached 1,194.79 g/yr. Research needs to be continued for the definite estimation of emission of BaP henceforth.

• 한국가스학회지
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• 제20권5호
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• pp.17-26
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• 2016

현대 화학플랜트 및 석유 가스 산업 시설은 다양한 잠재위험으로 인하여 위험물질의 누출 및 화재가 빈번히 발생하고 있다. 그 중 특히 화재는 직접적인 화염의 접촉 또는 복사열로 인하여 인명피해는 물론 건물, 설비에 대한 피해 발생으로 domino effect가 발생하여 2차, 3차 피해까지도 발생하기도 한다. 따라서 본 연구에서는 발생가능한 화재를 파악하여 사고피해영향과 빈도를 낮추어 화재 위험성을 관리하는 FRA(Fire Risk Assessment)기법의 절차를 제시하였으며, 사고피해영향으로 화염의 직접적인 접촉과 복사열로 인한 주요건물(제어실, 창고, 변전소)의 물리적 특성이 변형되는 시간을 고려하였다. 사례연구를 통하여 수행한 FRA기법으로 국내외 화학공장의 위험성을 경감시킬 수 있었으며, Protection 설정을 통한 사고의 빈도와 피해영향의 감소를 정량적으로 파악할 수 있었다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제20권7호
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• pp.135-147
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• 2015

Remediation of metal(loid)s-contaminated sites is crucial to protect human and ecosystem. Solidification and stabilization of metal(loid)s by the binder amendment is one of the cost-effective technologies. In this study, metal (loid)s in various field-contaminated soils obtained from steel-making, metal refinery and mining tillage were immobilized by the application of single binders such as diammonium phosphate (DAP), lime, and ladle slag. The efficiency of solidification and stabilization was evaluated by Toxicity Characteristic Leaching Procedure (TCLP) and the Standard, Measurements and Testing programme of European Union (SM&T) extraction processes. In terms of TCLP extraction, the binder was effective in order of lime > DAP > ladle slag. All binders were highly effective in the immobilization of Pb, Zn, Cu, Ni, and Cd. The increased immobilization efficiency is attributed to the increase in the Step III and IV fractions of the SM&T extraction. Lime and ladle slag were highly effective in the immobilization of the metal(loid)s, however, As release increased with DAP due to competition between the phosphate originated from DAP and arsenate. A further study is needed for the better immobilization of multi metal(loid)s using binary binders.

• 대한기계학회논문집
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• 제16권1호
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• pp.53-62
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• 1992

본 연구에서는 약 10년 정도 사용하여 경년 열화가 되었다고 예상되는 실구조 물의 일부를 입수하였으며 열화재의 특성과 비교하기 위하여 열처리에 의해 충격치를 회복시킨 재료를 회복재로 하여 두가지 재료에 대해 시험편을 제작하였따.열확현상 을 파악하기 위하여 평활재로 피로과정, 즉 미소 균열의 발생, 진전 및 복수 균열이 간섭합체하여 파단에 달하는 과정에 대하여 파괴역학적 견지에서 열화재와 회복재를 해석하고 이결과로 부터 확율변수를 추정하여 통계학적인 수명예측방법의 하나를 제시 하여 실구조물에 적용하는 방법에 대해 시도해 보았다.

• 한국환경과학회지
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• 제23권5호
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• pp.943-962
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• 2014

Industrial gas drying, dilute gas mixtures purification, air fractionation, hydrogen production from steam reformers and petroleum refinery off-gases, etc are conducted by using adsorptive separation technology. The pressure swing adsorption (PSA) has certain advantages over the other methods, such as absorption and membrane, that are a low energy requirement and cost-effectiveness. A key component of PSA systems is adsorbents that should be highly selective to a gas being separated from its mixture streams and have isotherms suitable for the operation principle. The six standard types of isotherms have been examined in this review, and among them the best behavior in the adsorption of $CO_2$ as a function of pressure was proposed in aspects of maximizing a working capacity upon excursion between adsorption and desorption cycles. Zeolites and molecular sieves are historically typical adsorbents for such PSA applications in gas and related industries, and their physicochemical features, e.g., framework, channel structure, pore size, Si-to-Al ratio (SAR), and specific surface area, are strongly associated with the extent of $CO_2$ adsorption at given conditions and those points have been extensively described with literature data. A great body of data of $CO_2$ adsorption on the nanoporous zeolitic materials have been collected according to pressure ranges adsorbed, and these isotherms have been discussed to get an insight into a better $CO_2$ adsorbent for PSA processes.