• Title/Summary/Keyword: reduction mechanism

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Generation of a skeletal mechanism of coal combustion based on the chemical pathway analysis

  • Ahn, Seongyool;Watanabe, Hiroaki;Shoji, Tetsuya;Umemoto, Satoshi;Tnno, Kenji
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.5-7
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    • 2014
  • A skeletal mechanism of coal combustion was derived from a detailed coal combustion kinetic mechanism through an importance analysis of chemical pathways. The reduction process consists of roughly two parts. The first process is performed based on a connectivity analysis between species. In this process, DRGEPSA is chosen for reduction process. Strongly connected species and related reactions from the important species set as start species by the operator are sorted into the reduced mechanism. About 70% of species and reactions can be removed with a limited accuracy loss. Subsequently the second reduction process, CSP, is performed. This method focuses on an importance of each reaction and can reduce a volume of mechanism appropriately. Through these analyses, a skeletal mechanism is generated that is including 65 species and 150 reactions. The generated skeletal mechanism is verified through a comparison with the detailed mechanism in the homogeneous reactor model of CHEMKIN-PRO under wide range of conditions. The generated mechanism can give an advantage in the analysis of coal combustion characteristics in detail in large scale simulations such as LES and DNS.

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MODELLING STUDY OF THE EFFECT OF CHEMICAL ADDITIVES ON SOOT PRECURSORS REDUCTION

  • Park, J.K.
    • International Journal of Automotive Technology
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    • v.7 no.4
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    • pp.501-508
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    • 2006
  • The effect of chemical additives, such as dimethyl ether(DME), ethanol, carbon disulfide on the soot formation were examined numerically. ill this study, the Frenklach soot mechanism was used as a base mechanism to predict the soot formation in the ethane flame. The combination of Westbrook's DME mechanism, Marinov's ethanol mechanism, and chemical kinetic mechanism for hydrogen sulfide and carbon disulfide flames was made with the base mechanism because the DME, ethanol, $CS_2$ additives are added into the ethane fuel. CHEMKIN code was used as a numerical analysis software to simulate the effect of chemical additives on reduction of the polycyclic aromatic hydrocarbons(PAH's) which are soot precursors. From the numerical results it is observed that addition of DME, ethanol and $CS_2$ into ethane fuel can reduce PAH species significantly. That means theses additives can reduce soot formation significantly. Results also strongly suggest suppression of soot formation by these additives to be mainly a chemical effect. Hand OH radicals may be the key species to the reduction of PAH species for additives.

Chemical Mechanism Reduction and Validation of Methyl Butanoate by Automatic Reduction Procedure (Methyl Butanoate의 상세 화학 반응 메커니즘 자동 축소화를 통한 기초 반응 메커니즘의 생성 및 검증)

  • Lee, Youngjae;Huh, Kang Y.
    • Journal of the Korean Society of Combustion
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    • v.21 no.3
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    • pp.16-23
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    • 2016
  • In this study, skeletal mechanisms are produced by directed relation graph with specified threshold value and sensitivity analysis based on species database from the directed relation graph. Skeletal mechanism is optimized through the elimination of unimportant reaction steps by computational singular perturbation importance index. Reduction is performed for the detailed mechanism of methyl butanoate consisting of 264 species and 1219 elementary reactions. Validation shows acceptable agreement for auto-ignition delays in wide parametric ranges of pressure, temperature and equivalence ratio. Methyl butanoate has been proposed as a simple biodiesel surrogate although the alkyl chain consists of four carbon atoms. The resulting surrogate mechanism for n-heptane and MB consists of 76 species and 226 reaction steps including those for NOx.

Investigation on flutter mechanism of long-span bridges with 2d-3DOF method

  • Yang, Yongxin;Ge, Yaojun;Xiang, Haifan
    • Wind and Structures
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    • v.10 no.5
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    • pp.421-435
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    • 2007
  • A two-dimensional flutter analysis method (2d-3DOF method) was developed to simultaneously investigate the relationship between oscillation parameters and aerodynamic derivatives of three degrees of freedom, and to clarify the coupling effects of different degrees of freedom in flutter instability. With this method, the flutter mechanism of two typical bridge deck sections, box girder section and two-isolated-girder section, were numerically investigated, and both differences and common ground in these two typical flutter phenomena are summarized. Then the flutter stabilization effect and its mechanism for long-span bridges with box girders by using central-slotting were studied by experimental investigation of aerodynamic stability and theoretical analysis of stabilizing mechanism. Possible explanation of new findings in the evaluation trend of critical wind speed through central vent width is finally presented.

Mechanism of the Electrode Reduction of Cupferron in Neutral and Alkaline Media (중성 및 알카리성수용액에서 Cupferron 의 전극환원메카니즘)

  • Hwang, Kum-Sho;Hwang, Jung-Ui
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.11 no.1
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    • pp.32-55
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    • 1975
  • The ammonium salt of N-Nitrosophenylhydroxiamine, namely Cupferron, is a well-known analytical reagent which precipitates a great number of metal ions in acid medium. Various structures of electrode reduction for N-Nitrosophenylhydroxiamine have been suggested in acid and alkaline media by many researchers, but not in neutral medium. So the mechanism of electrode reaction of Cupferron was investigated by both chronopotentiometric and polarographic methods. It was estimated that the reduction of Cupferron occurs in a three-step mechanism through which a chemical step is interposed between two charge transfer, the ECE (charge transfer-chemical reaction-charge transfer) mechanism, over a range of neutral and alkaline media. The chemical reaction of the process was assumed to be acid-base catalyzed from the fact that kapp (over all rate constant) of chemical reaction is pH dependent.

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SWM Utilized Cable Drive System (SWM을 이용한 케이블 드라이브 시스템)

  • Lee, Bum-Joo;Kim, Kab Il
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.63 no.2
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    • pp.272-276
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    • 2014
  • In this paper, cable drive mechanism is proposed to implement high reduction gear ratio. Cable drive mechanism has great advantages such as light weight, high degree of freedom about design aspect and zero backlashes. However, it is restrictively utilized for robotic applications because it is difficult to implement high reduction gear ratio more than 10 to 1. Proposed mechanism enables multi-level reductions by adopting seamless winding method (SWM) which links the previous output axis and the next input axis. Consequently, this reduces the mechanical complexity significantly and enables high reduction with only one single wire cable. 3D CAD design was provided and prototype was manufactured.

A Study on the Reduction of Reaction Mechanism for the Ignition of Dimethyl Ether (디메틸 에테르 착화에 관한 반응기구 축소 연구)

  • Ryu, Bong-Woo;Park, Sung-Wook;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.1
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    • pp.75-82
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    • 2011
  • The numerical analysis of the reduction of reaction mechanism for the ignition of dimethyl ether (DME) was performed. On the basis of a detailed reaction mechanism involving 79 species and 351 reactions, the peak molar concentration and sensitivity analysis were conducted in a homogeneous reactor model. The reduced reaction mechanism involving 44 species and 166 reactions at the threshold value $7.5{\times}10^{-5}$ of the molar peak concentration was established by comparing the ignition delays the reduced mechanism with those the detailed mechanism. The predicted results of the reduced mechanism applied to the single-zone homogeneous charge compression ignition (HCCI) engine model were in agreement with those of the detailed mechanism. Therefore, this reduced mechanism can be used to accurately simulate the ignition and combustion process of compression ignition engine using DME fuel.

The bonding mechanism and bond strength of cold pressure welding (엡셋팅에 의한 냉간 압접의 결합 기구와 결합강도)

  • 한인철;김재도
    • Journal of Welding and Joining
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    • v.8 no.3
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    • pp.31-38
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    • 1990
  • The bonding mechanism and bond strength were investigated for the cold pressure welding of Al to Al, Cu to Cu and Al to Cu by upsetting. A phenomenon of bonding betweenthe metallic components has been observed by a scanning electron microscope and metallurgical microscope. A modified equation for bond strength with respect to the reduction of height shows reasonably a good agreement with the experimental data. When the values of the hardening factor and threshold deformation for the given materials could be determined, the theoretical bond strength can be calculated.

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Experimental Investigation on the Drag Reduction Mechanism of Outer-layer Vertical Blades Array using Stereoscopic Time-Resolved PIV (스테레오 시간분해 입자영상유속계를 이용한 외부경계층 수직날 배열에 의한 마찰저항 저감 기구에 관한 실험적 조사)

  • Lee, Inwon;Park, Seong-Hyeon;Chun, Ho-Hwan;Hwang, Arom;An, Nam-Hyun
    • Journal of Power System Engineering
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    • v.17 no.6
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    • pp.95-101
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    • 2013
  • A stereo PIV measurements in a circulating water channel has been performed to investigate the skin friction reduction mechanism of the outer-layer vertical blades first devised by Hutchins. In a recent PIV measurement study, considerable skin friction reduction was achieved as much as 2.73%~7.95% by outer-layer vertical blades array. In the present study, the influence of vertical blades array upon the characteristics of the turbulent coherent structures was analyzed by proper orthogonal decomposition method. It is observed that the vortical structures are cut and deformed by blades array and also the turbulent intensity and the Reynolds stress were weakened by the blades. These phenomena strongly associate the skin-friction drag reduction mechanism in the turbulent boundary layer flow.