• Journal of Soil and Groundwater Environment
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• v.20 no.6
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• pp.117-126
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• 2015

Reductive degradation of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) by nanoscale zero-valent iron (nZVI) was investigated to evaluate the feasibility of using it for in-situ groundwater remediation. Batch experiments were conducted to quantify the kinetics and efficiency of RDX removal by nZVI, and to determine the effects of pH, dissolved oxygen (DO), and ionic strength on this process. Experimental results showed that the reduction of RDX by nZVI followed pseudo-first order kinetics with the observed rate constant (k_obs) in the range of 0.0056-0.0192 min⁻¹. Column tests were conducted to quantify the removal of RDX by nZVI under real groundwater conditions and evaluate the potential efficacy of nZVI for this purpose in real conditions. In column experiment, RDX removal capacity of nZVI was determined to be 82,500 mg/kg nZVI. pH, oxidation-reduction potential (ORP), and DO concentration varied significantly during the column experiments; the occurrence of these changes suggests that monitoring these quantities may be useful in evaluation of the reactivity of nZVI, because the most critical mechanisms for RDX removal are based on the chemical reduction reactions. These results revealed that nZVI can significantly degrade RDX and that use of nZVI could be an effective method for in-situ remediation of RDX-contaminated groundwater.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.1992-1996
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• 2007

This study focuses on the hydrogen embrittlement of iron tube for fuel line of PEMFC (Proton Exchange Membrane Fuel Cell). PEMFC is operated by feed of hydrogen as a reactant and steam for proton conductivity of membrane. However, the environment with hydrogen and steam occur the hydrogen-induced degradation in BOP system. When iron tube was exposed to hydrogen and steam condition for 24 hours, the oxide layer on the surface was decreased by reduction. When the ambient temperature was 90$^{\circ}C$ micro cracks were found on the surface than any other temperature. The mechanical strength of iron tube was 3% lower than that of non-experiment tube. Maximum tensile stress was decreased 8%.

• Journal of the Korean Ceramic Society
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• v.29 no.6
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• pp.441-450
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• 1992

The microstructur and LPG sensing properties of maghemite (${\gamma}-Fe_2O_3$) ceramics have been studied. The acicular and fine spherical shaped iron oxide particles were sintered at below $900^{\circ}C$. The maghemite ceramics were prepared by reduction-oxidation of sintered iron oxide. With the microstructure of acicular and/or fine grains, the maghemite ceramics have good LPG sensing properties. Increased sintering temperature deteriorates the LPG sensitivity of maghemite ceramics due to the grain growth. The maghemite ceramics prepared from the mixed iron oxide, of a large amount of acicular particles and a small amount of spherical ones, have a lower LPG sensitivity than that of the acicular iron oxide ceramics. But, they seem to be of higher mechanical strength. The optimum working temperature for LPG sensing of the maghemite ceramics was found to be $300~350^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.18 no.2
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• pp.105-111
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• 1981

The iron precipitates were prepared by adding sodium carbonate solution to ferrous chloride and ferric chloride solutions to pH=9 and pH=4.5, respectively. The thermal reaction of the iron precipitates was investigated by means of TGA, DTA and X-ray diffraction. In the former the crystallization of $\alpha$-$Fe_2O_3$ begins at about 35$0^{\circ}C$, while in the latter at about 30$0^{\circ}C$, during the calclnation in air. In the iron precipitate from ferrous chloride solution, the activation energy for the crystallite-growth or $\alpha$-TEX>$Fe_2O_3$ in air is about 7.6$\times$104J/mole between 800 and 100$0^{\circ}C$. As the result of X-ray diffration for the reduction product of hematite, it was found that maghemite, magnetite and wustite are formed and that hematite is transformed to magnetite through maghemite.

• Proceedings of the KIEE Conference
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• 2004.07d
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• pp.2347-2349
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• 2004

The iron loss in electric machines takes large part of machine losses and the reduction of iron loss brings the increase of the efficiency. In the rotating machines, however it is very difficult to calculate result because the measuring processes are very complex and laborious. As is well known, the relation between the flux density B and the magnetic field intensity H relation is not linear. For the iron loss, B and H must be measured and usually B becomes the reference wave(sine wave) and the following H is measured using H-coil. To make the B as sine wave, B is controlled by some devices. The error is controlled to become zero by the proposed algorithm which uses the bisection algorithm. The experiments are compared with the simulation results, and they show acceptable agreements.

• Journal of Environmental Science International
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• v.12 no.2
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• pp.201-205
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• 2003

The dechlorination of chlorinated methanes by iron powder and palladium coated iron (Pd/Fe) was studied in batch experiments. Iron powder dechlorinated carbon tetrachloride (CT) with a half-life of 4 days. Three chloromethane was found as major product and less chlorinated daughters. Mass balance found was to be about 93-99%. Pd/Fe showed very enhanced reactivity for CT in comparing with plain iron. The major dechlorination products of CT were also less chlorinated methanes with Pd/Fe. Pd/Fe also degrade the produced less chlorinated compounds. Sequential reactions were occurred on Pd/Fe. As the Pd/Fe content increased, the reaction rate was increased linearly.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.99-100
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• 2006

Cellular metals based on Iron have been intensively investigated during the last two decades. Because of the significant decreasing of the structural density of Iron based cellular structures, numerous technologies have been developed for their manufacturing. Besides the tremendous weight reduction a combination with other properties like energy and noise absorption, heat insulation and mechanical damping can be achieved. This contribution will give an overview about the latest state in Iron based cellular materials, including technologies in manufacturing, properties and potential applications.

• Journal of Korea Foundry Society
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• v.27 no.1
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• pp.24-30
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• 2007

The effects of C, Si and RE additions on the tendency of chill formation of ductile cast iron obtained from metal mold casting were investigated. In case of metal mold cast, the ductile cast iron with 2.5%Si had pearlitic matrix, and specimens with 2.9%Si had bull's eye type regardless of C contents. As-cast specimen with a large amount of fine graphites could be obtained by adding 0.2% RE. Normalizing process was necessary to remove carbide and form a large amount of spheroidal graphites for the as-cast specimens. Good mechanical properties could be obtained by heat-treatment of as-cast specimens with pearlitic matrix. Normalizing the specimens with RE caused the reduction in mechanical properties.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.05a
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• pp.108-111
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• 2000

FeS/FeS$_2$ minerals have been known to be potentially useful reductant to the removal of common organic contaminants in groundwater and soil. This research is aimed at improving our understanding of factors affecting the pathways and rates of reductive transformation of Hexachloroethane by catalytical iron minerals in natural system. Hexachloroethane is reduced by FeS/FeS$_2$ minerals under anaerobic condition to tetrachloroethylene and trichloroethylene with pentachloroethyl radical as the intermediate products. The kinetics of reductive transformations of the Hexachloroethane have been investigated in aqueous solution containing FeS, FeS$_2$. The proposed reduction mechanism for the adsorbed nitrobenzene involves the electron donor-acceptor complex as a precursor to electron transfer. The adsorbed Hexachloroethane undergo a series of electron transfer, proton transfer and dehydration to achieve complete reduction. It can be concluded that the reductive transformation reaction takes place at surface of iron-bearing minerals and is dependent on surface area and pH. Nitrobenzene reduction kinetics is affected by reductant type, surface area, pH, the surface site density, and the surface charge. FeS/FeS$_2$-mediated reductive dechlorination may be an important transformation pathway in natural systems.

• Journal of Microbiology
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• v.37 no.4
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• pp.206-212
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• 1999

In order to isolate a Fe(III)-reducer from the natural environment, soil samples were collected from various patty fields and enriched with ferric citrate as a source of Fe(III) under anaerobic condition. Since the enrichment culture was serially performed, the Fe(III)-reduction activity was serially diluted and cultivated on an agar plate containing lactate and ferric citrate in an anaerobic glove box. A Gram negative, motile, rod-shaped and facultative anaerobic Fe(III)-reducer was isolated based on its highest Fe(III)-reduction activity, Bacterial growth was coupled with oxidation of lactate to Fe(III)-reduction, but the isolate fermented pyruvate without Fe(III), The isolate reduced an insoluble ferric iron (FeOOH) as well as a soluble ferric iron (ferric citrate). Using the BBL crystal enteric/non-fermentor identification kit and 16S rDNA sequence analysis, the isolate was identified as Shewanella putrefaciens IR-1.