• Title/Summary/Keyword: reduction iron

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A Study on the Artificial Defect Sensitivity of Fatigue Limit in Austempered Ductile Iron (오스템퍼링처리한 구상흑연주철에서 인공결함에 대한 피로한도 민감도에 관한 연구)

  • Kim, M.G.;Kim, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.3
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    • pp.215-220
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    • 1999
  • Rotary bending fatigue tests were carried out to investigate the artificial defect sensitivity of fatigue limit in annealed and austempered ductile irons. Artificial defect(hole, diameter${\leq}0.4mm$) machined on specimen surface did not bring about an obvious reduction of fatigue limit in austempered ductile iron as compared with annealed. As a result of investigation on $\sqrt{area}$ c which is the critical artificial defect size. $\sqrt{area}$ c of austempered ductile iron is larger than that of annealed. This means that the crack initiation at artificial defect in austempered ductile iron is more difficult in comparison with annealed. In case that the $\sqrt{area}$ c of artificial defect and graphite nodule are same, the rate of crack initiation for graphite nodule is higher than that of artificial defect.

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A study on Iron Loss Measurement in Electric Machines (데이터 분석 알고리즘을 이용한 철손 측정)

  • Lee, Dong-Hyun;Hong, Sun-Ki
    • Proceedings of the KIEE Conference
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    • 2004.10a
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    • pp.49-51
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    • 2004
  • The iron loss in electric machines takes large part of machine losses and the reduction of iron loss brings the increase of the efficiency. In the rotating machines, however it is very difficult to calculate the iron loss and to get the exact experiment result because the measuring precesses are very complex and laborious. As is well known, the relation between the flux density B and the magnetic field intensity H relation is not linear. For the iron loss, B and H must be measured and usually B becomes the reference wave(sine wave) and the following H is measured using H-coil. To make the B as sine wave, B is controlled by some devices. The error is controlled to become zero by the proposed algorithm which uses the bisection algorithm. The experiments are compared with the simulation results, and they show acceptable agreements.

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Effects of Mn on Sulfur Segregation and Magnetic Induction in Thin-gauged 3%Si-Fe Strip (극박 3%규소강에서 Mn이 황의 편석 거동 및 자성특성에 미치는 효과)

  • 조성수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.917-920
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    • 2001
  • Effects of addition of manganese and final reduction on segregation behavior of sulfur and final mangetic induction during final annealing have been investigated in the 300 ppm sulfur-contained 3% silicon-iron alloy strips with or without manganese. At the same concentration of sulfur, lower final reduction is favorable for final Goss texture. This is because the probability that the initial Goss grains survive under the highly segregated sulfur atmosphere and grow selectively within the segregated sulfur-free time range becomes higher. In the case of 3% silicon-iron with manganese, much lower magnetic induction was obtained, although the weak final reduction of 30% is given to the alloy, comparative to the 40%. This is because MnS particles acted as an reducer in the primary grain size.

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A study on the Reduction of the Stator iron loss on Permanent Magnet Synchronous Motor for Light Railway Transit Propulsion System (경량전철 추진용 영구자석 동기전동기의 고정자 철손 저감 연구)

  • Park, Chan-Bae;Lee, Hyung-Woo;Lee, Byung-Song
    • Journal of the Korean Society for Railway
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    • v.15 no.4
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    • pp.376-380
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    • 2012
  • A study on the iron-loss reduction of 110kW-class Interior Permanent Magnet Synchronous Motor (IPMSM) for Light Railway Transit (LRT) is conducted. In general, the iron loss of IPMSM depends on the characteristics of core material and non-oriented electrical steel is used as a core material of IPMSM. In order to reduce the iron-loss of IPMSM, both non-oriented electrical steel and grain oriented electrical steel are applied as core material. Iron loss of 110kW-class IPMSM can be reduced approximately 40% comparing to an existing IPMSM by applying grain oriented electrical steel to the stator teeth.

Reduction of RDX in Ground Water by Bio-Regenerated Iron Mineral: Results of Field Verification Test at a Miliary Shooting Range (생물환원 철광물촉매에 의한 지하수 내 RDX 환원:군사격장 현장적용 실증결과)

  • Gong, Hyo-young;Lee, Kwang-pyo;Lee, Jong-yeol;Kyung, Daeseung;Lee, Woojin;Bae, Bumhan
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.62-72
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    • 2015
  • This study investigates the in-situ implementation of bio-regenerated iron mineral catalyst to remove explosive compounds in ground water at a military shooting range in operation. A bio-regenerated iron mineral catalyst was synthesized using lepidocrocite (iron-bearing soil mineral), iron-reducing bacteria Shewanella putrefaciens CN32, and electron mediator (riboflavin) in the culture medium. This catalyst was then injected periodically in the ground to build a redox active zone acting like permeable reactive barrier through injection wells constructed at a live fire military shooting range. Ground water and core soils were sampled periodically for analysis of explosive compounds, mainly RDX and its metabolites, along with toxicity analysis and REDOX potential measurement. Results suggested that a redox active zone was formed in the subsurface in which contaminated ground water flows through. Concentration of RDX as well as toxicity (% inhibition) of ground water decreased in the downstream compared to those in the upstream while concentration of RDX reduction products increased in the downstream.

Influences of silicate fertilizers containing different rates of iron slag on CH4 emission and rice (Oryza sativa L.) growth

  • Ji-Hoon Kim;Yun-Gu Kang;Jun-Yeong Lee;Jun-Ho Kim;Ji-Won Choi;Taek-Keun Oh
    • Korean Journal of Agricultural Science
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    • v.51 no.2
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    • pp.227-238
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    • 2024
  • Methane (CH4) is an important greenhouse gas, with a short-term greenhouse effect 80-fold that of carbon dioxide. Blast furnace slag used as a base ingredient for silicate fertilizer, and contained Fe3+, which acts as reduction of CH4 emissions in flooded rice paddy. This study was evaluated the effects of the silicate fertilizer with different rates of the iron slag on CH4 emissions and rice growth. In this study, the SF 0.0% was applied with silicate fertilizer containing 0.0% of the iron slag, while the SF 2.5% and SF 5.0% were treated with silicate fertilizer containing 2.5 and 5.0%, respectively. The CH4 emissions during rice cropping period were assessed using a closed-chamber method and then determined by Gas chromatography. The CH4 fluxes were reduced by 17% (SF 0.0%), 17% (SF 2.5%), and 8% (SF 5.0%) compared to the treatment with only-inorganic fertilization (control). Conversely, rice grain yield increased by 15 - 30% compared to the control owing to the improvement of soil quality by silicate fertilization. In particular, soil pH, available phosphorus and available silicic acid content were increased with the increase in the iron slag rates from 0.0 to 5.0%. These contributed to a significant increase in rice growth such as 1,000-grains weight and percentage of filled grains. Consequently, these findings were indicated that the application of silicate fertilizer containing 2.5 - 5.0% of iron slag would be the most effective in both CH4 reduction and rice growth.

Comparison of Sulfate Reduction Rates Associated with Geochemical Characteristics at the Continental Slope and Basin Sediments in the Ulleung Basin, East Sea (동해 울릉분지에서 대륙사면과 분지 퇴적물의 지화학적 특성에 따른 황산염 환원 비교)

  • You, Ok-Rye;Mok, Jin-Sook;Kim, Sung-Han;Choi, Dong-Lim;Hyun, Jung-Ho
    • Ocean and Polar Research
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    • v.32 no.3
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    • pp.299-307
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    • 2010
  • In conjunction with geochemical characteristics, rate of sulfate reduction was investigated at two sediment sites in the continental slope and rise (basin) of the Ulleung Basin in the East Sea. Geochemical sediment analysis revealed that the surface sediments of the basin site (D2) were enriched with manganese oxides (348 ${\mu}mol$ $cm^{-3}$) and iron oxides (133 ${\mu}mol$ $cm^{-3}$), whereas total reduced sulfur (TRS) in the solid phase was nearly depleted. Sulfate reduction rates (SRRs) ranged from 20.96 to 92.87 nmol $cm^{-3}$ $d^{-1}$ at the slope site (M1) and from 0.65 to 22.32 nmol $cm^{-3}$ $d^{-1}$ at the basin site (D2). Depth integrated SRR within the top 10 cm depth of the slope site (M1; 5.25 mmol $m^{-2}$ $d^{-1}$) was approximately 6 times higher than that at the basin site (D2; 0.94 mmol $m^{-2}$ $d^{-1}$) despite high organic content (>2.0% dry wt.) in the sediment of both sites. The results indicate that the spatial variations of sulfate reduction are affected by the distribution of manganese oxide and iron oxide-enriched surface sediment of the Ulleung Basin.

Improving the Reactivity and Harmlessness of Recalcitrant Contaminants by Reduction-oxidation-linked Process (환원-산화 연계처리를 통한 니트로벤젠의 반응성 향상 및 무해화 연구)

  • Kwon, Hee-Won;Hwang, Inseong;Kim, Young-Hun
    • Journal of Environmental Science International
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    • v.29 no.12
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    • pp.1205-1211
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    • 2020
  • In this study, the applicability of reduction-oxidation-linked treatment was evaluated for nitrobenzene and a by-product by analyzing the reaction kinetics. Nitrobenzene showed very low reactivity to persulfate that was activated using various methods. Nitrobenzene effectively reacted through the reduction process using Zero-Valent Iron (ZVI). However, aniline, a toxic substance, was produced as a by-product. Reduction-oxidation-linked treatment is a method that can allow the oxidative degradation of aniline after reducing nitrobenzene to aniline. The experimental results show improved reactivity and complete decomposition of the by-product. Improved reactivity and decomposition of the by-product were observed even under conditions in which the reduction-oxidation reaction was induced simultaneously. No activator was injected for persulfate activation in the process of reducing oxidant linkage, and the activation reaction was induced by ferrous iron eluted from the ZVI. This indicates that this method can be implemented relatively simply.

Biotic and Abiotic Reduction of Goethite (α-FeOOH) by Subsurface Microorganisms in the Presence of Electron Donor and Sulfate (전자공여체와 황산염 이용 토착미생물에 의한 침철석(α-FeOOH) 환원 연구)

  • Kwon, Man Jae;Yang, Jung-Seok;Shim, Moo Joon;Lee, Seunghak;Boyanov, Maxim;Kemner, Kenneth;O'Loughlin, Edward
    • Journal of Soil and Groundwater Environment
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    • v.19 no.1
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    • pp.54-62
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    • 2014
  • To better understand dissimilatory iron and sulfate reduction (DIR and DSR) by subsurface microorganisms, we investigated the effects of sulfate and electron donors on the microbial goethite (${\alpha}$-FeOOH) reduction. Batch systems were created 1) with acetate or glucose (donor), 2) with goethite and sulfate (acceptor), and 3) with aquifer sediment (microbial source). With 0.2 mM sulfate, goethite reduction coupled with acetate oxidation was limited. However, with 10 mM sulfate, 8 mM goethite reduction occurred with complete sulfate reduction and x-ray absorption fine-structure analysis indicated the formation of iron sulfide. This suggests that goethite reduction was due to the sulfide species produced by DSR bacteria rather than direct microbial reaction by DIR bacteria. Both acetate and glucose promoted goethite reduction. The rate of goethite reduction was faster with glucose, while the extent of goethite reduction was higher with acetate. Sulfate reduction (10 mM) occurred only with acetate. The results suggest that glucose-fermenting bacteria rapidly stimulated goethite reduction, but acetate-oxidizing DSR bacteria reduced goethite indirectly by producing sulfides. This study suggests that the availability of specific electron donor and sulfate significantly influence microbial community activities as well as goethite transformation, which should be considered for the bioremediation of contaminated environments.

A cost-effective method to prepare size-controlled nanoscale zero-valent iron for nitrate reduction

  • Ruiz-Torres, Claudio Adrian;Araujo-Martinez, Rene Fernando;Martinez-Castanon, Gabriel Alejandro;Morales-Sanchez, J. Elpidio;Lee, Tae-Jin;Shin, Hyun-Sang;Hwang, Yuhoon;Hurtado-Macias, Abel;Ruiz, Facundo
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.463-473
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    • 2019
  • Nanoscale zero-valent iron (nZVI) has proved to be an effective tool in applied environmental nanotechnology, where the decreased particle diameter provides a drastic change in the properties and efficiency of nanomaterials used in water purification. However, the agglomeration and colloidal instability represent a problematic and a remarkable reduction in nZVI reactivity. In view of that, this study reports a simple and cost-effective new strategy for ultra-small (< 7.5%) distributed functionalized nZVI-EG (1-9 nm), with high colloidal stability and reduction capacity. These were obtained without inert conditions, using a simple, economical synthesis methodology employing two stabilization mechanisms based on the use of non-aqueous solvent (methanol) and ethylene glycol (EG) as a stabilizer. The information from UV-Vis absorption spectroscopy and Fourier transform infrared spectroscopy suggests iron ion coordination by interaction with methanol molecules. Subsequently, after nZVI formation, particle-surface modification occurs by the addition of the EG. Size distribution analysis shows an average diameter of 4.23 nm and the predominance (> 90%) of particles with sizes < 6.10 nm. Evaluation of the stability of functionalized nZVI by sedimentation test and a dynamic light-scattering technique, demonstrated very high colloidal stability. The ultra-small particles displayed a rapid and high nitrate removal capacity from water.