• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.425-431
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• 2005

New type of supercapacitor using high surface area activated carbons mixed with high conductivity polypyrrole (Ppy) has been prepared in order to achieve low impedance and high energy density. Mixed carbons of BP-20 and MSP-20 were used as the active electrode material, and polypyrrole doped with 2-naphthalenesulfonic acid (2-NSA) and carbon black (Super P) as conducting agents were added to activated carbons in order to enhance good electric conductivity. Electrodes prepared with the activated electrode materials and the conducting agents were added to a solution of organic binder [P(VdF-co-HFP) / NMP]. The ratio of optimum electrode composition was 78 : 17 : 5 wt.％ of (MSP20 : BP-20=1 : 1), (Super P : Ppy=10 : 7) and P(VdF-co-HFP) respectively. The performance of unit cell with addition of 7 wt％ Ppy have shown specific capacitance of 28.02 F/g, DC-ESR of $1.34{\Omega}$, AC-ESR of $0.36{\Omega}$, specific energy of 19.87 Wh/kg and specific power of 9.77 kW/kg. With addition of Ppy, quick charge-discharge of unit cell was possible because of low ESR, low charge transfer resistance and quick reaction rate. And good stability up to 500 chargedischarge cycles were retained about 80％ of their original capacity. It was concluded that the specific capacitance originated highly from compound phenomena of the pseudocapacitance by oxidation-reduction of polypyrrole and the nonfaradaic capacitance by adsorption-desorption of activated carbons.

• Journal of the Korean GEO-environmental Society
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• v.21 no.1
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• pp.5-12
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• 2020

Vibration propagated from seismic sources has damping according to distance and amplification and reduction characteristic in different regions according to topography and geological structure. The vibration propagated from the seismic source to the bedrock is largely affected by the damping according to the separation distance, which can be simply estimated through the damping equation. However, it is important to grasp geological information by location because vibration estimation transmitted to the surface are affected by the natural period of the soil located above the bedrock. Geotechnical investigation data are needed to estimate the seismic intensity based on geological information. If there is no Vs profile, the standard penetration tests are mainly used to determine the soil parameters. The Integrated DB Center of National Geotechnical Information manages the geotechnical survey data performed on the domestic ground, and there is the standard penetration test information of 400,000 holes. In this study, the possibility of quantitation the amplification coefficient for each region was examined to calculated the physical interactive seismic intensity based on geotechnical information. At this time, the shear wave column diagram was generated from the SPT-N value and ground response analysis was performed in the target area. The site coefficients for each zone and the seismic intensity distribution for the seismic motion present a significant difference according to the analysis method and the regional setting.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.9
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• pp.604-612
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• 2012

Self-management plan for GHG (Greenhouse Gas) reduction should be prepared in academic facilities, which occupy a large amount of energy consumption. In this study, a university was chosen as one of the major academic facilities and its energy consuming pattern and GHG emission were analyzed. The results have shown that annual $CO_2$ emission from university buildings was 10,452 ton-$CO_2$ (0.65 ton-$CO_2/m^2$), and dependent upon 78.0% electricity, 20.5% LNG and 1.5% oil, respectively as energy sources. According to more detail analysis by usage of energy consumption, appliances occupies 36.7% followed by gas heating (18.9%), lighting (18.6%), heating with electricity (12.5%), cooling with electricity (10.2%), transportation (1.5%), gas cooling (1.2%) and cooking (0.4%). Furthermore, annual $CO_2$ emissions per unit area and a student by electricity usage were evaluated to 51.30 kg-$CO_2/m^2$ and 981.86 kg-$CO_2$/capita, respectively and those by LNG usage were 14.61 kg-$CO_2/m^2$ and 241.01 kg-$CO_2$/capita.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.1
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• pp.88-96
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• 2020

It were found that the heavyweight waste glass can be used as a construction materials including concrete from previous experimental studies. In this study, in order to evaluate the structural behavior of RC members using heavyweight waste glass as fine aggregate, a flexural behavior test was performed. And then, its results were compared with those obtained from non-linear finite element model analysis. From the results, when the heavyweight waste glass as fine aggregate in RC member, the area of compressive crushing and the number of cracks increased, however, the mean of cracking spacing decreased. Also it had reduced the ductility at high loading stage. For this reason, the same analysis method about the RC member using natural sand as fine aggregate did not predict the initial stiffness, yield load and maximum load on the flexural behavior of the RC members using heavyweight waste glass as fine aggregate. On the other hand, when it is analytically implemented the reduction of neutral axis depth due to developed compression crushing, the results of non-linear finite element analysis could be predicted the experimental results, relatively well.

• International Area Studies Review
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• v.20 no.2
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• pp.113-140
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• 2016

This paper first extracts the main basis for the Middle-Income Trap(MIT) to apply these grounds to reality of the Chinese economy. And then confirmed crisis factors of China economy. Also discussed then the economic reforms of China in order to not fall into the MIT. After reviewing previous research extracted six factors the results will correspond to comply with the Chinese economy. Those are 'Over-investment', 'excess capacity' 'reduction of TFP continued,' 'disappearance and the aging of the population bonus', 'excessive debt and structural adjustment and financial instability of the company', 'income unequal expansion', 'low financial and information infrastructure accessibility', and 'low transparency index'. China's policy direction to avoid the MIT generally set properly, but proof that implementation process not easy, was appearing everywhere. After all, China economy should be modified now to a reforms of 'government failure' and promotion of function for ongoing restructuring system in the market. Because of the SDR incorporation from 2015, it is inevitable to face major constraints in the external aspects.

• Journal of Soil and Groundwater Environment
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• v.13 no.3
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• pp.52-58
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• 2008

Mn-impregnated activated carbon (Mn-AC) prepared at different conditions was applied in the treatment of synthetic wastewater containing both organic and inorganic contaminants. Phenol and As(III) was used as the representative organic and inorganic contaminants, respectively. After evaluation of the physicochemical characteristic and stability of Mn-AC, oxidation of As(III) as well as adsorption of phenol by activated carbon(AC) and Mn-AC were investigated in a batch reactor. To investigate the stability of Mn-AC, dissolution of Mn from each Mn-AC was measured pH ranging from 2 to 4. Although Mn-AC was unstable at a strong acidic condition, the dissoluted Mn was below 3 ppm at pH 4. XRD analysis of Mn-AC indicated that the mineral type of the impregnated manganese was $Mn_2O_3$. From the simultaneous treatment of As(III) and phenol by AC and Mn-AC, As(III) oxidation by Mn-AC was greater than that by AC at lower pH, while the reverse order was observed at higher pH. After impregnation of Mn onto AC, 13% decrease of the surface area was observed, causing 8% reduction of phenol removal. Considering removal properties of As(III) and phenol, Mn-AC could be applied in the simultaneous treatment of wastewater contaminated with multi-contaminants.

• Applied Chemistry for Engineering
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• v.32 no.6
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• pp.599-606
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• 2021

In this study, an experiment and a reaction characteristic study were conducted to enhance the reaction activity of V₂O₅/WO₃/TiO₂ at 300 ℃ or less by adding selenium to the support, in a selective catalytic reduction method using ammonia as a reducing agent to remove nitrogen oxides. Se-TiO₂ and TiO₂ were synthesized using the sol-gel method, and used as a support when preparing V₂O₅/WO₃/TiO₂ and V₂O₅/WO₃/Se-TiO₂ catalysts. The reaction activity of our catalyst was compared with that of a commercial catalyst. The denitration efficiency of the catalyst using TiO₂ prepared by the sol-gel method was lower than that of the catalyst prepared using commercial TiO₂, but was improved by the addition of selenium. Thus, the effect of selenium addition on the catalyst structure was analyzed using BET, XRD, Raman, H₂-TPR, and FT-IR measurements and the effect of the increase in specific surface area by selenium addition and the formation of monomer and complex vanadium species on reaction characteristics were confirmed.

• International Area Studies Review
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• v.15 no.2
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• pp.427-447
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• 2011

In global, there is an active movement to reduce the green house gas. Allowance and carbon tax are the one of effective alternatives to mitigate green gas effect. In addition, the clean development machinism(CDM) can be applied between the ANNEX 1 and developing countries. It could be an one good solution to reduce the GHG. In the Northern Asia, the CDM can be the one of the possible solution to reduce the GHG because the Japan has a responsibility to reduce GHG and the China and Korea have a room to supply CDM credit. It is suffice to say that if these three countries decide to collaborate, the new international carbon market can be established that can be the similar form of EU-ETS. It is clear that few barriers must be removed to launched such new form of carbon market. Protection of domestic technology, excessive financial request of business opportunities by CDM, and irrational needs of carbon credit that created by CDM, listed constraints define as an one single word, the national selfishness. Once it is cleared, there is high possibility that the Northern Asia CDM trading system can be launched.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.167-172
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• 2011

In this work, the effect of surface treatment on mesoporous carbons (MCs) supports was investigated by analyzing surface functional groups. MCs were prepared by a conventional templating method using mesoporous silica (SBA-15) for using catalyst supports in direct methanol fuel cells (DMFCs). The MCs were treated with different phosphoric acid ($H_3PO_4$) concentrations i.e., 0, 1, 3, 4, and 5 M at 343 K for 6 h. And then Pt-Ru was deposited onto surface treated MCs (H-MCs) by chemical reduction method. The characteristics of Pt-Ru catalysts deposited onto H-MCs were determined by specific surface area and pore size analyzer, X-ray diffraction, X-ray photoelectron, transmission electron microscopy, and inductive coupled plasma-mass spectrometer. The electrochemical properties of Pt-Ru/H-MCs catalysts were also analyzed by cyclic voltammetry experiments. From the results of surface analysis, an oxygen functional group was introduced to the surface of carbon supports. From the results, the H4M-MCs carbon supports surface treated with 4 M $H_3PO_4$ led to uniform dispersion of Pt-Ru onto H4M-MCs, resulting in enhancing the electro-catalytic activity of Pt-Ru catalysts.

• The Journal of the Korea Contents Association
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• v.20 no.12
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• pp.74-81
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• 2020

As of 2020, due to the influence of fine dust from China and domestic dust, the cloudy sky of Korea has become a daily routine not only in spring but also in autumn/winter. In 2013, the International Cancer Institute under the World Health Organization designated fine dust as a group 1 carcinogen that has been confirmed to be carcinogenic to humans. The purpose of this study is to theoretically review 5 fine dust-related design studies, by analyzing the case of three types of wearable air purifiers on the market, it is to propose an improved open wearable air purifier. As a verification method, a working prototype was produced to measure the amount of fine dust reduction. Therefore, this study derived three design insights of wearable air cleaner through case analysis. First, it maximizes openness by minimizing the area touching the face. Second, the nozzle where the air comes out should be close to the respiratory organ. Third, position of the motor is to be as far away as possible from the ear considering the noise. Based on this, I suggested an open-type wearable air purifier design that maximizes the user openness and improves the wearing comfort. I hope that it will be an opportunity to increase the coverage of wearable air cleaner and protect the respiratory health of users.