• Title/Summary/Keyword: reducing atmosphere

Search Result 318, Processing Time 0.028 seconds

Second-harmonic Generation of Treated-STO Surface

  • Kang, Bong-Hoon
    • Journal of the Korean Ceramic Society
    • /
    • v.49 no.2
    • /
    • pp.142-145
    • /
    • 2012
  • In order to investigate the surface SHG, (110) pure STO single crystals were exposed to a reducing atmosphere to induce the reduction of the Ti ion and the release of oxygen from the lattice compensating the reduction of the Ti ions. The anisotropy and asymmetry of SHG intensity explains a slight shrinkage. The incoming fundamental wave was polarized either in the $p$-in or $s$-in to the plane of incidence for the reflection geometry. The SH polarization diagram could be described by the electric dipole and/or quadrupole contribution of reduced STO single crystal surface.

Review : Present Status of Green Chemistry (녹색화학 기술동향)

  • Lee, Jun-Wung
    • Journal of the Korea Institute of Military Science and Technology
    • /
    • v.14 no.2
    • /
    • pp.246-263
    • /
    • 2011
  • Mankind has just begun to recognize that the most crucial factor to achieve the sustainable society in the future is green technology. Most countries support the development of green technology to prevent catastrophes from global warming, mainly in the areas of reducing carbon dioxide from the atmosphere. However, most products we consume in everyday life are produced through chemical processes, and we often oversee the fact that the huge amount of waste and energy during these chemical processes will seriously influence our goal to achieve our future society sustainable. Thus the technologies to minimize the amount of disposed waste and energy consumption during chemical processes may be more important than to reduce the greenhouse gases. In this regard this review introduces the recent status of green chemistry and future prospects in order to help our chemists and engineers establish research projects based on the green chemistry principles.

Analysis of Nano-contact Between Nano-asperities Using Atomic Force Microscopy (나노스케일 표면돌기 간의 미세접촉에 대한 해석)

  • Ahn, Hyo-Sok;Jang, Dong-Young
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.18 no.4
    • /
    • pp.369-374
    • /
    • 2009
  • In micro/nano-scale contacts in MEMS and NEMS, capillary and van der Waals forces generated around contacting micro-asperities significantly influence the performance of concerning device as they are closely related to adhesion and stiction of interacting surfaces. In this regard, it is of prime importance to accurately estimate the magnitude of surface forces so that an optimal solution for reducing friction and adhesion of micro/nano-surfaces may be obtained We introduced an effective method to calculate these surface forces based on topography information obtained from an atomic force microscope. This method was used to calculate surface forces generated in the contact interface formed between diamond-like carbon coating and $Si_3N_4$ ball. This method is shown to effectively demonstrate the influence of capillary force in the contact area, especially in humid atmosphere.

  • PDF

A Study on the Improvery Efficiency of Heavy Water Vapour for CANDU Reactor Systems (CANDU형 원자력 발전소의 중수 증기 회수율 증대 방안에 관한 연구)

  • 김윤제;박이동;황영규;이도영
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
    • /
    • 1995.05a
    • /
    • pp.101-112
    • /
    • 1995
  • In order to improve the recovery efficiency of heavy water vapour from the atmosphere inside a reactor building, and to recover and upgrade the heavy water which escape, special treatments, such as reducing the ingress of light water vapour, are studied in the design of the CANDU reactor systems. This is considered in controlled method of the humidity over drawing fresh air through a desiccant dehumidifier which dries the air by absorption. Comparing with the moisture loads between summer and winter operations, the moisture removal rates are calculated. Those are proportional to the difference between the controlled space and the surrounding environment Installation of a new dehumidifier will be able to reduce the moisture loads from the cooling systems, improving overall system efficiency and saving operating costs.

  • PDF

Electrical Conductivities of [(ZrO2)$_{1-x}$(CeO2)$_x$]$_{0.92}$(Y$_2$O$_3$)$_{0.08}$ Solid Solution ([(ZrO2)$_{1-x}$(CeO2)$_x$$_{0.92}$(Y$_2$O$_3$)$_{0.08}$ 고용체의 전기전도도)

  • 이창호;최경만
    • Journal of the Korean Ceramic Society
    • /
    • v.35 no.12
    • /
    • pp.1323-1328
    • /
    • 1998
  • The electrical conductivities of the yttria (8mol%) stabilizedzirconia-ceria solid solutions were measured as a function of oxygen partial between 80$0^{\circ}C$ and 100$0^{\circ}C$ using 4-probe d.c. method Under pure oxygen atmosphere the oxygen ionic conductivity of CeO2-ZrO2 decreased with the concentration of CeO2 Under reducing condition electronic conduction due to the redox equilibrium of Ce ion was observed. Total ionic and electronic conductivities fitted by a defect model enabled to determine the electronic transference number(tei) which increased with the concentration of CeO2 and with the degree of reduction.

  • PDF

Properties of Powders and Sintered Bodies of $\beta$-SiC Prepared from Jecheon Quartzite (제천규석으로부터 제조한 $\beta$-SiC분말 및 소결체의 특성)

  • 이홍림;신석호;배철훈;김무경
    • Journal of the Korean Ceramic Society
    • /
    • v.24 no.2
    • /
    • pp.139-146
    • /
    • 1987
  • ${\beta}$-SiC powders were prepared by the simultaneous reduction and carbiding of Jecheon quartzite at 1400$^{\circ}C$ for 7 hours in hydrogen atmosphere, using graphite or carbon black as the reducing and carbiding reagent. The prepared SiC powder was acid-treated with the mixture of fluoric acid and hydrochloric acid at room temperature and also by heating on an alcohol lamp for one hour, respectively. The impurities were mostly eliminated and the purity of SiC became 98.5% after hot acid treatment. The specific surface area of SiC powder was also increased up to 115㎡/g by hot acid treatment. This pure and fine SiC powder was hot-pressed at 1900$^{\circ}C$ for 30min, using 5wt% Al2O3 as a sintering aid. The density, M.O.R., KIC and hardness of the hot-pressed SiC ceramics were 3.195g/㎤, 48.7Kgf/$\textrm{mm}^2$, 5.4MN/㎥/2 and 2,182Kgf/$\textrm{mm}^2$, respectively.

  • PDF

Performance Evaluation of Window Ventilation System for Reducing Indoor particulate matter (실내 미세먼지 저감을 위한 창호형 환기시스템 성능평가)

  • Yang, Young Kwon;Park, Jin Chul
    • Land and Housing Review
    • /
    • v.10 no.3
    • /
    • pp.1-7
    • /
    • 2019
  • Indoor particulate matter(PM) is a carcinogen and needs to be removed and managed. It is generally reduced and removed through ventilation and filtration. Owing to the recent occurrence of high-concentration fine dust and yellow dust in the atmosphere, however, it is difficult to expect the purification of indoor air through the simple introduction of the outside air. For residential buildings, in particular, they are highly dependent on natural ventilation but the lack of natural ventilation is worsening because concerns over the inflow of external pollutants are increasing. Therefore, this study designed and manufactured a window ventilation system that does not require a duct to improve the maintenance and management problems of general ventilation system, and constructed indoor PM concentration change data through performance evaluation.

Luminescent Properties of Two-Ions Doped Phosphors for LED Application

  • Kim, Tae-Gon;Kim, Young-Sic;Im, Seoung-Jae
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2009.10a
    • /
    • pp.52-55
    • /
    • 2009
  • A red phosphor, $(Sr,Ca)_2P_2O_7:Eu^{2+},Mn^{2+}$, for UV-LED was synthesized under a reducing atmosphere, and its luminescent properties were investigated. The phosphor absorbs ultraviolet light at around 400 nm and efficiently emits red light at approximately 610 nm through an energy transfer from $Eu^{2+}$ to $Mn^{2+}$. Using the varied input current test for the phosphor-loaded LED lamps, it was found that the luminescent efficiency of the phosphor decreased with increasing light flux. This might be due to an increased probability of excited-state absorption and the consequent non-radiative relaxation in $Mn^{2+}$ ions in the condition of high photon influx.

  • PDF

The Effect of Catalytic Metal Work Functions and Interface States on the High Temperature SiC-based Gas Sensors (금속 (Pt)과 4H-SiC의 계면상태에 따른 실리콘 카바이드 기반 고온 가스센서 특성 분석)

  • Jung, Ji-Chul;Koo, Sang-Mo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.24 no.4
    • /
    • pp.280-284
    • /
    • 2011
  • Silicon carbide (SiC)-based gas sensors can be operated at very high temperatures. So far, catalytic metal-schottky diodes respond fast to a change between a reducing and an oxidizing atmosphere. Therefore SiC diodes have been suggested for high temperature gas sensor applications. In this work, the effect of reactivity of the catalytic surface on the 4H-SiC sensor-structures in 375 K~775 K have been studied and some fundamental simulations have also been performed.

Preparation and Characteristics of Pt/GDE Loaded with Pd Promoter for PEMFC (Pd 조촉매가 도입된 PEMFC용 Pt/GDE 제조 및 특성)

  • LEE, HONGKI;LEE, WOOKUM
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.27 no.3
    • /
    • pp.264-269
    • /
    • 2016
  • A simple dry chemical approach was developed in order to load palladium (Pd) as a promoter on Pt/gas diffusion electrode (GDE) for polymer electrolyte membrane fuel cell (PEMFC). Palladium(II) bis (acetylacetonate), $Pd(acac)_2$ was sublimed, penetrated into Pt/GDE and then reduced to Pd nanoparticles simultaneously without any reducing agent and any solvent in a glass reactor of $N_2$ atmosphere at $180^{\circ}C$ for 3, 5 and 15 min. Pd distribution was analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), and I-V curve was estimated by using a unit cell with $5{\times}5cm^2$ active area.