• Title/Summary/Keyword: reducing agent

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Feasibility Study on Stabilization Technique of Cr(VI)-contaminated Site (Cr(VI)으로 오염된 부지의 안정화 기술에 의한 정화 타당성 연구)

  • Yoon, Geun Seok;Yoo, Jong Chan;Ko, Sung-Hwan;Shim, Myung-Ho;Cho, Myung-Hyun;Baek, Kitae
    • Journal of Soil and Groundwater Environment
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    • v.22 no.4
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    • pp.27-32
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    • 2017
  • In this study, a remedial investigation using reductive stabilization was conducted to treat Cr(VI)-contaminated soil. The influences of various operational parameters, including reaction time and the mass of ferrous iron, were also evaluated. The study site was contaminated with a large amount of Cr(III) and Cr(VI), and the selected treatment method was to stabilize Cr(VI) with ferrous iron, which reduced Cr(VI) to Cr(III) and stabilized the chromium, although a greater mass of ferrous iron than the stoichiometric amount was required to stabilize the Cr(VI). However, some Cr(III) re-oxidized to Cr(VI) during the drying process, and addition of a strong reducing agent was required to maintain reducing conditions. With this reducing agent, the treated soil met the required regulatory standard, and the mass of Cr(III) re-oxidized to Cr(VI) was significantly reduced, compared to the use of only Fe(II) as a reducing agent.

Fundamental Properties on the Development of High Performance Shrinkage Reducing Agent for Concrete (콘크리트용 고성능 수축저감제 개발에 대한 기초적 특성)

  • Park, Jong-Pil;Jung, Yong-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.6
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    • pp.4298-4307
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    • 2015
  • The expenses of maintenance and reinforcement for aged concrete structures are significantly on the increase as their durability and general performance has been naturally degraded. Due to this reason, interests on concrete crack reduction technology are growing but more researches are required to fulfill such fast growing demands. Particularly in the underground power facilities, it is difficult to maintain the quality of aging concrete spheres for underground power as their deterioration caused by long-term operation is on-going. In recent years, many studies have been made to overcome the issues and now it is determined that the shrinkage reducing technology which can dramatically reduce the crack at the design stage is one of the most effective solutions. In this study, the test investigated fundamental propertiesof concrete using various shrinkage reducing materials to develop low shrinkage mortar. According to results of experimental study, for mortar and concrete, glycol based material showed excellent shrinkage property and compressive strength. For the later study to generic application of the shrinkage reducing materials, performance reviews on the shrinkage reducing materials with variable factors and various materials such as changes in the amount and type of materials should be followed.

Development of thermo-sensor used liquid crystal-polymer composite films (온도센서로서 액정잉크의 개발)

  • 남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.1
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    • pp.25-38
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    • 1998
  • The developing agent is the materials which first acts on silver grain and make it into metallic silver by reducing reaction. There are several types in developing agent, and according to Lumiere-Andresen principle, substitution product which has amino or hydroxyl group in benzen nucleus has a developing power, but all reduing substances are not in used. In the developing effect, not only the role of developing agent but also that of assistant materials are important. But in this work, we have studied effect, change by lith developing agent which require high contrast image. We made an developing experiment after having manufactured developing solution used hydroquinone and another developing agents like chlorohydroquinone, pyrocatechol and pyrogallol as developing agent. And we added that did in addition of diethanolamine and ascorbic acid, and then we examined the possibility of use.

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Identification of Soil Actinomycetes Producing Anticancer Agent and Its Biological Activities (항암활성물질을 생산하는 토양방선균의 동정 및 함암물질의 생물학적 활성)

  • 박정민;문순옥;오두환
    • Microbiology and Biotechnology Letters
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    • v.22 no.4
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    • pp.347-352
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    • 1994
  • Cytotoxic test was performed by SRB assay on human epidermoid carcinoma HEp-2 cell line for screening the soil microorganism, secreting anticancer agent. One microorganism was selected among two thousand microorganisms for its highest cytotoxicity. And this microorganism was identified with Streptomyces species after performing of diaminopimeric acid and reducing sugar analysis of cell wall and analysing the cultural characteristics and named Streptomyces sp. SM 1119. The effect of anticancer agent in SM 1119 culture extract on the cell cycle was studied by using GG$_{o}$ synchronized NIH 3T3 cells. The extract inhibited the serum stimulation of GG$_{o}$ NIH 3T3 cell only within 1 hour after serum stimulation but not after 6 hours. The extract also reduced the amount of c-myc mRNA in Colo 320 cell. These results suggest that the anticancer agent in the extract inhibits the progression of cell cycle very early stages, probably from G$_{0}$ to G$_{1}$.

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Mechanical Properties of PMMA Mortars without Crosslinking Agent (가교제 무첨가 PMMA 모르타르의 역학적 특성)

  • 최낙운;김완영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.425-428
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    • 2003
  • This study deals with the mechanical properties of polymethyl methacrylate(PMMA) mortars without crosslinking agent. Waste expanded polystyrene(EPS) is used as a multifunctional admixture such as a thickener, a extender, a shrinkage reducing agent, a assistant to polymerization. PMMA mortars are prepared with various EPS contents of binder and subjected to a dry and a dry/heat combined curing, and tested for working life, flexural and compressive strengths. From the test results, the working life of PMMA mortars without crosslinking agent is shortened with raising EPS content of binder. The flexural and compressive strengths of the PMMA Mortars are decreased somewhat with increase in the EPS content. PMMA mortars with good mechanical properties could be manufactured without any crosslinking agent and their properties would be controled by adjusting EPS content of binder.

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Physical Properties and Dyeability of Fine Count Wool Yarns and Its Fabrics by Drawing Process of Fineness Control (섬도제어 연신공정에 의한 세섬화 양모 소재의 물성 연구)

  • Kim, Mikyung;Jeon, Byeongdae;Jeong, Jaeseok
    • Textile Coloration and Finishing
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    • v.28 no.4
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    • pp.253-270
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    • 2016
  • In the wool textile industry, the necessity for technology development has been steadily raised to create improved fineness and yarn count of existing wool yarns with thick fineness for ensuring higher quality grades of wool yarn. Recently, through controlling fineness of wool yarn for making finer wool in relation with environmentally-friendly and high-sensitivity trend, a differentiated continuous drawing process where the quality of wool can be artificially manipulated has been suggested in the latest textile industry. This study investigated the basic conditions during the continuous drawing process which enable to manufacture wool yarn with fine count by controlling reducing agent treatment, physical drawing and drying after reducing agent treatment, and oxidizing agent post-treatment conditions. Furthermore, this study reviewed the drawing effects by applying the basic conditions for reduction and oxidation reaction in the drawing processes of wool/cashmere, wool/silk, wool/polyester blended yarns as well as such wool yarns. Also, in order to review the practicability, this study examined the physical properties and dyeability of drawn wool yarn applied textile materials in comparison with normal wool yarn applied textile materials.

A Datagram Delivery Strategy for Reducing Retransmission Overheads During Handover (핸드오버시 재전송 부담 감소를 위한 데이터그램 전송 정책)

  • Heo, Seong-Jin;Kim, Jeong-Sam;Jeong, Jae-Yeol;Kang, Sang-Yong;Han, Ki-Jun
    • Journal of the Korean Institute of Telematics and Electronics S
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    • v.36S no.1
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    • pp.20-28
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    • 1999
  • In this paper, we propose a new datagram delivery strategy at the home agent to improve the end-to-end performance by reducing retransmission overheads during handover. Changed routing might be able to cause packet disordering and this in turn could cause unnecessary retransmission at the fixed host and finally results in performance degradation. In our proposal, the home agent begins to buffer received datagrams instead of transmitting them after receiving a registration request message from the foreign agent and then transmits them again after for a certain time. Simulation results show that our proposal may successfully solve this problem at little cost.

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The Effect of an Optical Clearing Agent on Tissue Prior to 1064-nm Laser Therapy

  • Youn, Jong-In
    • Medical Lasers
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    • v.10 no.3
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    • pp.146-152
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    • 2021
  • Background and Objectives Although lasers have been widely applied in tissue treatment, the light penetration depth in tissues is limited by the tissue turbidity and affected by its absorption and scattering characteristics. This study investigated the effect of using an optical clearing agent (OCA) on tissue to improve the therapeutic effect of 1064 nm wavelength laser light by reducing the heat generated on the skin surface and increasing the penetration depth. Materials and Methods A diode laser (λ = 1064 nm) was applied to a porcine specimen with and without OCA to investigate the penetration depth of the laser light and temperature distribution. A numerical simulation using the finite element method was performed to investigate the temperature distribution of the specimen compared to ex-vivo experiments using a thermocouple and double-integrating sphere to measure the temperature profile and optical properties of the tissue, respectively. Results Simulation results showed a decrease in tissue surface temperature with increased penetration depth when the OCA was applied. Furthermore, both absorption and scattering coefficients decreased with the application of OCA. In ex-vivo experiments, temperatures decreased for the tissue surface and the fat layer with the OCA, but not for the muscle layer. Conclusion The use of an OCA may be helpful for reducing surface heat generation and enhance the light penetration depth in various near-infrared laser treatments.

Analysis of Crack Control Effect of Ultra-low Shrinkage Concrete through Wall Mock-up Test (벽체 실물대부재실험을 통한 초 저수축 콘크리트의 균열제어 효과 분석)

  • Seo, Tae-Seok;Lee, Hyun-Seung;Kim, Kang-Min
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.1
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    • pp.45-55
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    • 2022
  • Ultra-low shrinkage concrete is very effective for securing the quality and appearance of a concrete structure because it can control the drying shrinkage cracks of the concrete structure to within a certain limit. In this study, with the purpose of commercializing ultra-low shrinkage concrete, the optimal amount of expansive agent and shrinkage reducing agent was determined through a lab test, and a concrete wall mock-up test was conducted to examine the shrinkage properties and crack control effects of ultra-low shrinkage concrete. As a result, it was confirmed that there was little drying shrinkage deformation in the wall specimen, and furthermore that no cracks were generated.

Rhodium-Catalyzed Reductive Decyanation of Nitriles Using Hydrosilane as a Reducing Agent: Scope, Mechanism and Synthetic Application

  • Tobisu, Mamoru;Nakamura, Ryo;Kita, Yusuke;Chatani, Naoto
    • Bulletin of the Korean Chemical Society
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    • v.31 no.3
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    • pp.582-587
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    • 2010
  • A rhodium-catalyzed reductive cleavage reaction of carbon-cyano bonds is developed using hydrosilane as a mild reducing agent. A wide range of nitriles, including aryl, benzyl, and $\beta$-hydrogen containing alkyl cyanides are applicable to this decyanation reaction. The method is also applicable to organic synthesis, in which benzyl cyanide is used as a benzyl anion equivalent and a cyano group functions as a removable ortho-directing group.