• Bulletin of the Korean Chemical Society
• /
• v.30 no.7
• /
• pp.1588-1592
• /
• 2009

Lithium cyanoaluminum hydride (LCAH) was prepared by the metal cation exchange reaction of sodium cyanoaluminum hydride with lithium chloride in tetrahydrofuran. The reducing characteristics of LCAH were explored systematically by the reaction with selected organic compounds containing representative functional groups under the standardized conditions (tetrahydrofuran, 0 ${^{\circ}C}$). The reducing ability of LCAH was also compared with of the sodium derivative, sodium cyanoaluminum hydride (SCAH). Generally, the reducing behavior of LCAH resembles that of SCAH closely, but the reactivity of LCAH toward representative organic functional groups appeared to be stronger than that of SCAH. Thus, the regent reduces carbonyl compounds, epoxides, amides, nitriles, disulfides, carboxylic acids and their acyl derivatives to the corresponding alcohols or amines, at a relatively faster rate than that of SCAH. The cyano substitution, a strong election-withdrawing group, diminishes the reducing power of the parent metal aluminum hydrides and hence effects the alteration of their reducing characteristics.

• Bulletin of the Korean Mathematical Society
• /
• v.53 no.5
• /
• pp.1471-1481
• /
• 2016

We characterize reducing subspaces of weighted shifts with operator weights as wandering invariant subspaces of the shifts with additional structures. We show how some earlier results on reducing subspaces of powers of weighted shifts with scalar weights on the unit disk and the polydisk can be fitted into our general framework.

• Journal of Acupuncture Research
• /
• v.15 no.2
• /
• pp.211-225
• /
• 1998

It is very important to understand objectively the Qi variation induced by the reinforcing-reducing manipulation method in the therapy of acupuncture. The Qi variation in the meridian treated by O-Haeng Reinforcing-Reducing Manipulation Acupuncture Method and the recovery of Five Phase deviation were measured by choosing complex acupoints. By using O-Haeng Reinforcing-Reducing Manipulation Acupuncture Method, we increased or decreased the Qi of the phase which caused the unbalance state. We observed whether the Qi of the treated meridian can be increased or not and if the state of unbaIance can be recovered. To achieve the effect of reinforcing-reducing, we need a correct choice of treating method and a selection of a proper meridian in advance. We discovered that the effects of reinforcing-reducing by each manipulation method could be superposed each other, when two counteracting O-Haeng Reinforcing-Reducing Manipulation Acupuncture Method were treated at the left and the right side of human body. We found that the Qi variation of the traeted meridian, which was induced by O-Haeng Reinforcing-Reducing Manipulation Acupuncture Method, is lineary proportioned to the reduction of Five Phase deviation.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2003.11a
• /
• pp.269-272
• /
• 2003

This study is intended to investigate the properties of concrete using AE Water Reducing Agent of Early-Strength Type. According to the results, as for the replacing method of mineral admixture, setting time is shortened faster in order of replacement for fine aggregate, combination and replacement for cement, and when AE Water Reducing Agent of Early-Strength Type is used, it is shortened by about 4 hours, compared with normal AE Water Reducing Agent Compressive strength is lower in the case of replacement for fine aggregate, but higher in the other case than that of plain concrete. And When AE Water Reducing Agent of Early-Strength Type is used, early compressive strength is very high in comparison to normal AE Water Reducing Agent. Early strength development is very favorable by the use of AE Water Reducing Agent of Early-Strength Type regardless of the replacing method of mineral admixture at $20^{\circ}C$, but at $l0^{\circ}C$, it is effective for Early strength development that W/B is lowered to below 45%, BS of 20% is replaced for fine aggregate, and AE Water Reducing Agent of Early-Strength Type is used.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2003.11a
• /
• pp.69-72
• /
• 2003

This study is intended to investigate the fundamental properties of concrete which AE water reducing agent for reduction of bleeding is used, and the properties of bleeding reduction. According to the results, when the adding ratio of AE water reducing agent for reduction of bleeding increases, a range of normal fluidity and aimed air content arc satisfied, setting time is faster than that of normal AE water reducing agent. And bleeding amount decreases, bleeding speed is highest between 60 and 90 min, and sinking depth increases drastically in 60 min. When, AE water reducing agent for reduction of bleeding is added, compressive strength shows a slight variation by air content, but there is not a large influence by addition of AE water reducing agent for reduction of bleeding. Synthetically, it proves that AE water reducing agent for reduction of bleeding satisfies aimed air content in the range of normal slump and can reduce only bleeding without quality variation of compressive strength.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2003.05a
• /
• pp.69-72
• /
• 2003

This study is intended to investigate the fundamental properties of concrete which AE water reducing agent for reduction of bleeding is used, and the properties of bleeding reduction. According to the results, when the adding ratio of AE water reducing agent for reduction of bleeding increases, a range of normal fluidity and aimed air content are satisfied, setting time is faster than that of normal AE water reducing agent. And bleeding amount decreases, bleeding speed is highest between 60 and 90 min, and sinking depth increases drastically in 60 min. When. AE water reducing agent for reduction of bleeding is added, compressive strength shows a slight variation by air content, but there is not a large influence by addition of AE water reducing agent for reduction of bleeding. Synthetically, it proves that AE water reducing agent for reduction of bleeding satisfies aimed air content in the range of normal slump and can reduce only bleeding without quality variation of compressive strength.

• Archives of Pharmacal Research
• /
• v.20 no.2
• /
• pp.184-190
• /
• 1997

A new method based on the chemical reaction has been devised for the sequential analysis of reducing oligosaccharides using 8-amino-2-naphthalenesulfonic acid (ANS), a fluorescent precolumn derivatization reagent for reducing saccharides. The procedure established includes 1) the derivatization of a reducing oligosaccharide to produce a Schiff base, 2) the reduction of the base with sodium cyanoborohydride $(NaBH_3/CN), 3)$ the methoxycarbonylation of the resultant secondary amino group, 4) the cleavage of the glycoside bond next to the reducing end, based on the intramolecular acid hydrolysis by the action of a sulfonic acid group of the ANS derivative, 5) the identification of the liberated reducing end by high-performance liquid chromatography (HPLC), and finally 6) the recovery of the resultant oligosaccharide fragment from the cleavage reaction mixture. The extensive examination of the conditions for the sequential analysis of reducing oligosaccharides resulted in the procedure of simplicity , high selectivity and high recovery. This procedure was found to be useful for the sequential analysis of di-, tri- and tetrasaccharides.

• Journal of Korean Society of Industrial and Systems Engineering
• /
• v.43 no.3
• /
• pp.41-52
• /
• 2020

This paper investigates the stress-reducing preventive maintenance model through numerical experiments. The preventive maintenance model is used to analyze the relationship between related conditions and variables to gain insight into the efficient operation of the system when performing preventive maintenance in real-world situations. Various preventive maintenance models have been developed over the past decades and their complexity has increased in recent years. Increasing complexity is essential to reflect reality, but recent models can only be interpreted through numerical experiments. The stress-reducing preventive maintenance is a newly introduced preventive maintenance concept and can only be interpreted numerically due to its complexity, and has received little attention because the concept is unfamiliar. Therefore, for information purposes, this paper investigates the characteristics of the stress-reducing preventive maintenance and the relationship between parameters and variables through numerical experiments. In particular, this paper is focusing on the economic feasibility of stress-reducing preventive maintenance by observing changes in the optimal preventive maintenance period in response to changes in environmental stress and the improvement factor. As a result, when either the environmental stress or the improve effect of stress-reducing preventive maintenance is low, it is not necessary to carry out the stress-reducing preventive maintenance at excessive cost. In addition, it was found that the age reduction model is more economical than the failure rate reduction model.

• Journal of the Korea Institute of Building Construction
• /
• v.7 no.3
• /
• pp.123-130
• /
• 2007

This study investigated the fundamental properties and shrinkage properties of high performance concrete with water/binder ratio of 0, 30 and with combination of expansive additive and shrinkage reducing agent. According to the results, the fluidity of high performance concrete showed lower the using method in combination with expansive additive and shrinkage reducing agent than the separately using method of that, so the amount of superplasticizer increased when the adding ratio of expansive additive and shrinkage reducing agent increased. However the air content of concrete increased when used in combination with expansive additive and shrinkage reducing agent, so the amount of AE agent decreased. The compressive strength showed the highest at 5% of expansive additive, and decreased with an increase of the amount of shrinkage reducing agent. Furthermore, in order to reduce the shrinkage of high performance concrete, it was found that the using method in combination with expansive additive and shrinkage reducing agent was more effective than separately using method of that. Autogenous shrinkage was predicted using JCI model. Because JCI model is unable to consider the effect of EA and SRA, correction factor should be added to enhance the accuracy.

• Journal of the Korea Institute of Building Construction
• /
• v.4 no.1
• /
• pp.133-140
• /
• 2004

This study is intended to investigate the properties of bleeding reduction of concrete using AE water reducing agent for the type of bleeding reduction with the replacement admixture. According to the results, when the adding ratio of AE water reducing agent for the type of bleeding reduction increases, a range of normal fluidity and aimed air content are satisfied, setting time is faster than that of normal AE water reducing agent. And bleeding amount decreases, bleeding speed is highest between 60 and 90 min, and sinking depth increases drastically in 50 min. When AE oater reducing agent for the type of bleeding reduction is added, compressive strength shows a slight variation by air content, but there is not a large influence by addition of AE water reducing agent for the type of bleeding reduction. Synthetically, it proves that AE water reducing agent for the type of bleeding reduction satisfies aimed air content in the range of normal slump and can reduce only bleeding without quality variation of compressive strength.