• Title/Summary/Keyword: reduce CO2

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Exploring Rational Design of Single-Atom Electrocatalysts for Efficient Electrochemical Reduction of CO2 to CO

  • Joonhee Ma;Jin Hyuk Cho;Kangwon Lee;Soo Young Kim
    • Korean Journal of Materials Research
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    • v.33 no.2
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    • pp.29-46
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    • 2023
  • The electrochemical reduction of carbon dioxide (CO2) to value-added products is a remarkable approach for mitigating CO2 emissions caused by the excessive consumption of fossil fuels. However, achieving the electrocatalytic reduction of CO2 still faces some bottlenecks, including the large overpotential, undesirable selectivity, and slow electron transfer kinetics. Various electrocatalysts including metals, metals oxides, alloys, and single-atom catalysts have been widely researched to suppress HER performance, reduce overpotential and enhance the selectivity of CO2RR over the last few decades. Among them, single-atom catalysts (SACs) have attracted a great deal of interest because of their advantages over traditional electrocatalysts such as maximized atomic utilization, tunable coordination environments and unique electronic structures. Herein, we discuss the mechanisms involved in the electroreduction of CO2 to carbon monoxide (CO) and the fundamental concepts related to electrocatalysis. Then, we present an overview of recent advances in the design of high-performance noble and non-noble singleatom catalysts for the CO2 reduction reaction.

Comparison of Construction Costs of Masonry Wall Types, including CO2 Emission Costs (조적벽의 CO2 배출비용을 포함한 건설원가 비교에 관한 연구)

  • Lee, Byung-Yun;Kim, Bo-Ra;Kim, Gwang-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.3
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    • pp.83-90
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    • 2010
  • The carbon dioxide($CO_2$) emissions that result from construction are one of the main factors causing a global warming problem. It is therefore necessary to make efforts to reduce $CO_2$ emissions in the construction industry. Some researchers have studied $CO_2$ emissions in the industry ; however, there has been a lack of study on $CO_2$ emissions cost. Therefore, in this study, the construction costs, including the $CO_2$ emission cost, of masonry wall type, which is a common brick wall, concrete brick wall, and fired brick wall, were examined. The purpose of this study is to compare the construction costs of masonry wall types, including $CO_2$ emission costs. The study found that the $CO_2$ emission costs were highest for the fired brick wall, followed by the concrete brick wall. This research could provide basic information that can be used in other engineering methods to convert $CO_2$ emissions to $CO_2$ emission cost.

Characteristics for Effects of Co2 Addition to Oxygen-Enriched Combustion (산소부화연소에서 Co2 첨가에 대한 연소 특성)

  • Kim, Han-Seok;Kim, Ho-Keun;Ahn, Kook-Young;Kim, Yong-Mo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.1
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    • pp.9-15
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    • 2004
  • $CO_2$ is a well-known green house gas as well as the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. Because its adiabatic flame temperature is relatively too high, existing facilities must be changed or the flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were investigated experimentally for the various oxygen-enriched ratios(OER) by the addition of $CO_2$, under constant $O_2$ flow rate. Results showed that the reaction zone was quenched and broadened as the addition of $CO_2$ was increased. The emission of NOx in flue gas was decreased as decreasing temperature in reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone was increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0%, but the composition of CO was decreased by quenching effect at OER=50% and 100%.

Effects of $CO_2$ addition to Oxygen-Enriched Combustion (산소부화연소에서 $CO_2$ 첨가에 대한 영향)

  • Kim, Ho-Keun;Kim, Han-Seok;Ahn, Kook-Young;Kim, Yong-Mo
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1389-1394
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    • 2003
  • $CO_2$ is a well-known green house gas, which is the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. But the adiabatic flame temperature is too high. So existing facilities must be changed, or the adiabatic flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were studied experimentally for the various oxygen-enriched mtios(OER) by addition of $CO_2$ under coustant $O_2$ flowrate. Results showed that the reaction zone was quenched, broadened, as addition of $CO_2$ was increased. Temperature has a large effect on the NOx emission. The emission of NOx in flue gas decreased due to the decreased temperature of reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0, but the composition of CO decreased by quenching effect at OER=50 and 100%.

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A Study on Effect of Applying Energy Storage System on SeoulMetro Line 2 (에너지저장시스템의 서울메트로 2호선 적용 효과에 관한 연구)

  • An, Cheon-Heon;Lee, Han-Min;Kim, Gil-Dong;Lee, Hi-Sung
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.966-971
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    • 2009
  • The recent environmental protection trend requires more strict energy saving, therefore every transportation system should reduce energy consumption to the minimum value. High-efficiency operation system, energy saving and CO2 emissions shall be addressed as important issue in railway system. These issues are the most essential factors of railway, compared to major public transportation system. Recently, saving energy in the electric railway system has been studied. For such new energy saving, the Energy storage system is considered for saving energy. Energy saving is possible by efficient use of regenerated energy. Regenerated energy is recycled amongst vehicles by mean of charge and discharge corresponding to powering and braking of electric vehicle operations. This energy saving contributes to cut CO2 to reduce greenhouse gas emissions. Recycling regenerated energy demonstrate significant effect on peak cut of consumption energy in railway substation. Absorption of excess energy avoids regeneration failure due to high traction voltage. This paper presents effects by applying the energy storage system to SeoulMetro Line 2.

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Performance analysis of $CO_{2}$ refrigeration cycle with two-phase ejector (2상류이젝터를 이용하는 $CO_{2}$ 냉동사이클의 성능해석)

  • Lee Yoon-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.8
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    • pp.946-952
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    • 2005
  • The $CO_{2}$ refrigeration cycle is expected to reduce the compressor work and increase the COP by applying two-phase ejector as a device for the recovery of dissipated expansion energy. In this study, the performance of the cycle was simulated and effects of the ejector shapes on the performance of the $CO_{2}$ refrigeration cycle were investigated. The following results were obtained through the cycle simulation. The COP of the $CO_{2}$ refrigeration cycle with two-phase ejector flow which expansion is occured in the isentropic manner is increased by a maximum of 24 $\%$ than the basic cycle with expansion valve If the velocity nonequilibrium in the mixing process is assumed the COP of the cycle is increased with the increase of the length and the decrease of the section area of the mixing tube. The best cycle performance is obtained when the divergent angle of diffuser is 7.

Study on the Analysis of the CO2 Emissions Reduction Effect through the Development of Internet Real Estate Information in Seoul (인터넷 부동산거래정보 발달에 따른 탄소저감효과 분석)

  • Lim, Mi-Hwa
    • Journal of Information Technology Services
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    • v.12 no.2
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    • pp.73-84
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    • 2013
  • The development of the information on the internet brought a lot of changes in the real estate market. Because the real estate has local distinctiveness and individuality household who want to move must to visit place for housing information. But now household use internet real estate information at every decision-moving step and that is able to reduce not only the cost of real estate information but also social benefit like $CO_2$ emissions reduction effect. In this study, I analyzed the effect of $CO_2$ emissions reduction with Seoul household residential mobility data when household take informations from internet real estate site. As increasing a single family who is good at internet service, the effect of $CO_2$ reduction from the development of the Internet real estate information has more increased.

Estimation of the Shadow Price of Carbon Dioxide Emissions, the Potential Reduction, and Substitution Possibility for fuels in the Chinese Fossil-fueled Power Generation Sector (중국 화력발전산업의 CO2 암묵가격 및 잠재감축량, 연료에 대한 대체가능성 분석)

  • Jin, Yingmei;Lee, Myunghun
    • Environmental and Resource Economics Review
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    • v.22 no.1
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    • pp.77-98
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    • 2013
  • China, the world's largest $CO_2$ producer, is likely to be obligated to reduce greenhouse gas emissions under the post-Kyoto protocol. This paper estimates a Shephard input distance function for the Chinese fossil-fueled power generation sector to measure the shadow price of $CO_2$ emissions, technical efficiency, and indirect Morishima elasticities of substitution between inputs. Empirical results show that, on average, it costs approximately 3.2 US dollars per year to reduce $CO_2$ emissions by one ton over the period 1981-2009. This finding indicates that Chinese power sector is expected to benefit from selling emission permits to other countries such as Korea and Japan, given that our estimate for China is lower than the ones previous literatures estimated for the power sector in these countries. The maximum attainable average $CO_2$ reduction potential amounts to approximately 25 million tons per year by improving technical efficiency. Capital is substitutable with both coal and oil and capital is relatively more readily substituted for these fuels.

Low-Carbon trawl design with analysis of a gear drags and calculation of construction costs using numerical methods (수치해석기법에 의한 어구 저항 분석 및 저탄소 트롤어구 설계와 비용 분석)

  • Lee, Ji-Hoon;Lee, Chun-Woo
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.46 no.4
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    • pp.313-323
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    • 2010
  • Fuel consumption in fisheries is a primary concern due to environmental effects and costs to fishermen. Much research has been carried out to reduce the fuel consumption related to fishing operations. The fuel consumption of fishing gear during fishing operation is generally related to hydrodynamic resistance on the gear. This research demonstrates a new approach using numerical methods to reduce fuel consumption. By designing the fishing gear using drawing software, the whole and partial resistance force on the gear can be calculated as a result of simulations. The simulation results will suggest suitable materials or gear structure for reducing the hydrodynamic forces on the gear while maintaining the performance of the gear. This research will helpful to reduce the $CO_2$ emissions from fishing operations and lead to reduce fishing costs due to fuel savings.

Design and Exergy Analysis for a Combined Cycle of Liquid/Solid $CO_2$ Production and Gas Turbine using LNG Cold/Hot Energy

  • Lee, Geun-Sik
    • International Journal of Air-Conditioning and Refrigeration
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    • v.15 no.1
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    • pp.34-45
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    • 2007
  • In order to reduce the compression power and to use the overall energy contained in LNG effectively, a combined cycle is devised and simulated. The combined cycle is composed of two cycles; one is an open cycle of liquid/solid carbon dioxide production cycle utilizing LNG cold energy in $CO_2$ condenser and the other is a closed cycle gas turbine which supplies power to the $CO_2$ cycle, utilizes LNG cold energy for lowering the compressor inlet temperature, and uses the heating value of LNG at the burner. The power consumed for the $CO_2$ cycle is investigated in terms of a solid $CO_2$ production ratio. The present study shows that much reduction in both $CO_2$ compression power (only 35% of the power used in conventional dry ice production cycle) and $CO_2$ condenser pressure could be achieved by utilizing LNG cold energy and that high cycle efficiency (55.3% at maximum power condition) in the gas turbine could be accomplished with the adoption of compressor inlet cooling and regenerator. Exergy analysis shows that irreversibility in the combined cycle increases linearly as a solid $CO_2$ production ratio increases and most of the irreversibility occurs in the condenser and the heat exchanger for compressor inlet cooling. Hence, incoming LNG cold energy to the above components should be used more effectively.