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Visible Light-based Photocatalytic Degradation by Transition Metal Oxide (전이 금속 산화물을 이용한 가시광선 기반 광촉매 분해)

  • Lee, Soomin;Park, Yeji;Lee, Jae Hun;Patel, Rajkumar
    • Membrane Journal
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    • v.29 no.6
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    • pp.299-307
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    • 2019
  • Photocatalysis is an environment friendly technique for degrading organic dyes in water. Tungsten oxide is becoming an active area of research in photocatalysis nanomaterials for having a smaller bandgap than the previously favored titanium dioxide. Synthesis of hierarchical structures, doping platinum (Pt), coupling with nanocomposites or other semiconductors are investigated as valid methods of improving the photocatalytic degradation efficiency. These impact the reaction by creating a redshift in the wavelength of light used, effecting charge transfer, and the formation/recombination of electron-hole pairs. Each of the methods mentioned above are investigated in terms of synthesis and photocatalytic efficiency, with the simplest being modification on the morphology of tungsten oxide, since it does not need synthesis of other materials, and the most efficient in photocatalytic degradation being complex coupling of metal oxides and carbon composites. The photocatalysis technology can be incorporated with water purification membrane by modularization process and applied to advanced water treatment system.

Do Bars Trigger Activity in Galactic Nuclei?

  • Lee, Gwang-Ho;Woo, Jong-Hak;Lee, Myung-Gyoon;Hwang, Ho-Seong;Lee, Jong-Chul;Sohn, Ju-Bee;Lee, Jong-Hwan
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.75.1-75.1
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    • 2011
  • We investigate the connection between the presence of bars and AGN activity, using a volume-limited sample of ~6,000 late-type galaxies with axis ratio b/a > 0.6 and $M_r=-19.5+5logh$ at low redshift (0.02 < z ${\leq}$ 0.055), selected from Sloan Digital Sky Survey Data Release 7. Although bars are believed to play an important role in fueling AGNs, it is still an open question whether AGN activity is connected with the presence of bars. We find that the bar fraction in AGN-host galaxies (44.1%) is 2.5 times higher than in non-AGN galaxies (17.6%), implying an AGN-bar connection. However, this trend is simply caused by the fact that AGN-host galaxies are on average more massive and redder than non-AGN galaxies since the bar fraction increases with u-r color and velocity dispersion. When AGN-host and non-AGN galaxies with fixed u-r color and velocity dispersion are compared, the excess of bar fraction in AGN-host galaxies disappears. Among AGN-host galaxies we find no strong difference of the Eddington ratio distributions between barred and non-barred systems. These results indicate that AGN activity is not directly connected with the presence of bars.

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Improved and quality-assessed emission and absorption line measurements in Sloan Digital Sky Survey galaxies

  • Oh, Kyu-Seok;Sarzi, Marc;Schawinski, Kevin;Yi, Suk-Young K.
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.73.2-73.2
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    • 2011
  • We present a new database of absorption and emission-line measurements based on the entire spectral atlas from the Sloan Digital Sky Survey (SDSS) 7th data release of galaxies within a redshift of 0.2. Our work makes use of the publicly available penalized pixel-fitting(pPXF) and gas and absorption line fitting (gandalf) IDL codes, aiming to improve the existing measurements for stellar kinematics, the strength of various absorption-line features, and the flux and width of the emissions from different species of ionized gas. Our fit to the stellar continuum uses both standard stellar population models and empirical templates obtained by combining a large number of stellar spectra in order to fit a subsample of high-quality SDSS spectra for quiescent galaxies. Furthermore, our fit to the nebular spectrum includes an exhaustive list of both recombination and forbidden lines. Foreground Galactic extinction is implicitly treated in our models, whereas reddening in the SDSS galaxies is included in the form of a simple dust screen component affecting the entire spectrum that is accompanied by a second reddening component affecting only the ionised gas emission. Most notable of our work is that, we provide quality of the fit to assess reliability of the measurements. The quality assessment can be highly effective for finding new classes of objects. For example, based on the quality assessment around the Ha and [NII] nebular lines, we found approximately 1% of the SDSS spectra which classified as "galaxies" by the SDSS pipeline are in fact type I Seyfert AGN.

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On the Nature of LINERs: A Clue from Keck/LRIS Observations

  • Bae, Hyun-Jin;Yagi, Masafumi;Woo, Jong-Hak;Yoshida, Michitoshi;Yoon, Suk-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.61.2-61.2
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    • 2011
  • Low-ionization nuclear emission-line regions (LINERs) have been generally regarded to be powered by active galactic nuclei (AGNs), yet still a number of alternative explanations on the origin of LINER emission are suggested; for example, planetary nebulae nuclei of massive stars, supernovae shocks from death of massive stars, and old stellar populations. Interestingly, a majority of recent star formation early-type galaxies (ETGs) in local universe presents such LINER emission lines. Given that situation, revealing the true nature of LINERs is a crucial step to constrain the evolution path to quiescent ETGs. To resolve the issue, we use Keck/LRIS to obtain spatially resolved spectra on a carefully selected ETG. The ETG SDSS J091628.05+420818.7 at redshift z ~ 0.024 shows modest LINER emission line features without any detection of 21 cm radio continuum nor X-ray emission. We perform a stellar continuum subtraction and measure emission line strengths and their uncertainties for each spectrum from five apertures along the slit with size of 1 arcsecond (~0.5 kpc). We find that extended spatial distributions of four emission lines $H{\alpha}$, $H{\beta}$, [OIII]${\lambda}5007$, and [NII]${\lambda}6583$, and they can be explained by central emission blurring effect. We conclude that the emissions seem to be centrally concentrated, indicating the AGN-nature of LINERs.

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KVN Observation on Radio-selected AGNs hosted by Elliptical Galaxies

  • Park, Song-Youn;Yi, Suk-Young K.;Sohn, Bong-Won
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.61.1-61.1
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    • 2011
  • We have performed simultaneous observations at 22GHz and 43GHz on AGNs hosted by elliptical galaxies using KVN radio telescope. We have constructed the sample, based on two major surveys in radio and optical band, i.e. Faint Images of the Radio Sky at Twenty-Centimeters (FIRST) and Sloan Digital Sky Survey (SDSS) DR7, respectively. We restricted the redshift range 0.01 < z < 0.06 and the absolute magnitude Mr < -19.4 in order to satisfy volume limited sample. We also checked clear detection of four distinctive emission lines ([NII], [OIII], $H{\alpha}$, $H{\beta}$) so as to utilize on BPT diagram, distinguishing AGNs from star-forming galaxies. Elliptical galaxies have been selected by visual inspection making use of SDSS optical images. Then, we cross-matched the elliptical galaxies with FIRST detections. About 35% of the galaxies have been detected throughout KVN observations. We derive spectral index, applying the flux of different radio frequencies from FIRST (1.4GHz) and KVN (22GHz) and classify into steep, flat or inverted spectrum. We have found that most of the detected galaxies have flat spectrum while the rest of them have steep spectrum. This implies that a number of detected galaxies might have compact structure associated with the central region of the galaxies. The relation between black hole mass and radio luminosity has shown relatively tighter correlation in high frequency than in low frequency, which confirms that high frequency in radio band is appropriate to study the center of the galaxies.

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Semiconductor CdTe-Doped CdO Thin Films: Impact of Hydrogenation on the Optoelectronic Properties

  • Dakhel, Aqeel Aziz;Jaafar, Adnan
    • Korean Journal of Materials Research
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    • v.30 no.1
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    • pp.1-7
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    • 2020
  • Doping or incorporation with exotic elements are two manners to regulate the optoelectronic properties of transparent conducting (TCO) cadmium oxide (CdO). Nevertheless, the method of doping host CdO by CdTe semiconductor is of high importance. The structural, optical, and electrical properties of CdTe-doped CdO films are studied for the sake of promoting their conducting parameters (CPs), including their conductivity, carrier concentration, and carrier mobility, along with transparency in the NIR spectral region; these are then compared with the influence of doping the host CdO by pure Te ions. X-ray fluorescence (XRF), X-ray diffraction (XRD), optical absorption spectroscopy, and electrical measurements are used to characterise the deposited films prepared by thermal evaporation. Numerous results are presented and discussed in this work; among these results, the optical properties are studied through a merging of concurrent BGN (redshift) and BGW (blue shift) effects as a consequence of doping processes. The impact of hydrogenation on the characterisations of the prepared films is investigated; it has no qualitative effect on the crystalline structure. However, it is found that TCO-CPs are improved by the process of CdTe doping followed by hydrogenation. The utmost TCO-CP improvements are found with host CdO film including ~ 1 %Te, in which the resistivity decreases by ~ 750 %, carrier concentration increases by 355 %, and mobility increases by ~ 90 % due to the increase of Ncarr. The improvement of TCO-CPs by hydrogenation is attributed to the creation of O-vacancies because of H2 molecule dissociation in the presence of Te ions. These results reflect the potential of using semiconductor CdTe -doped CdO thin films in TCO applications. Nevertheless, improvements of the host CdO CPs with CdTe dopant are of a lesser degree compared with the case of doping the host CdO with pure Te ions.

Demography of SDSS Early-type galaxies from the perspective of radial color gradients

  • Suh, Hye-Won;Jeong, Hyun-Jin;Oh, Kyu-Seok;Yi, Suk-Young K.;Ferreras, Ignacio;Schawinski, Kevin
    • Bulletin of the Korean Space Science Society
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    • 2009.10a
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    • pp.34.4-35
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    • 2009
  • We have studied the radial g-r color gradients of early-type galaxies in the Sloan Digital Sky Survey (SDSS) DR6 in the redshift range 0.00 < z < 0.06. The color profiles of ~30 per cent of the galaxies in this sample show positive color gradients (centers being bluer). These positive gradient galaxies often show strong $H\beta$ absorption line strengths or emission line ratios that are consistent with star-forming populations. Combining the optical data with Galaxy Evolution Explorer (GALEX) UV photometry, we find that all positive gradient galaxies show blue UV-optical colors. They also exhibit a tendency of having a lower stellar velocity dispersion. Positive gradient galaxies tend to live in lower density regions than negative gradient galaxies and are likely to have a late-type companion galaxy. On the other hand, massive early-type galaxies show negative color gradients. A simplistic population analysis shows that these positive color gradients are visible only for half a billion years after a star burst. Although the effective radius decreases and mean surface brightness increases due to this centrally concentrated star formation, the positions of the positive gradient galaxies on the fundamental plane cannot be reproduced by any amount of recent star formation. Instead it required a lower velocity dispersion.

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AUTO-GUIDING SYSTEM FOR CQUEAN (CAMERA FOR QUASARS IN EARLY UNIVERSE)

  • Kim, Eun-Bin;Park, Won-Kee;Jeong, Hyeon-Ju;Kim, Jin-Young;Kuehne, John;Kim, Dong-Han;Kim, Han-Geun;Odoms, Peter S.;Chang, Seung-Hyuk;Im, Myung-Shin;Pak, Soo-Jong
    • Journal of The Korean Astronomical Society
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    • v.44 no.4
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    • pp.115-123
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    • 2011
  • To perform imaging observations of optically red objects such as high redshift quasars and brown dwarfs, the Center for the Exploration of the Origin of the Universe (CEOU) recently developed an optical CCD camera, Camera for QUasars in EArly uNiverse (CQUEAN), which is sensitive at 0.7-1.1 ${\mu}m$. To enable observations with long exposures, we develop an auto-guiding system for CQUEAN. This system consists of an off-axis mirror, a baffle, a CCD camera, a motor and a differential decelerator. To increase the number of available guiding stars, we design a rotating mechanism for the off-axis guiding camera. The guiding field can be scanned along the 10 arcmin ring offset from the optical axis of the telescope. Combined with the auto-guiding software of the McDonald Observatory, we confirm that a stable image can be obtained with an exposure time as long as 1200 seconds.

Environment of radio-sources over 8 decades of radio luminosity

  • Karouzos, Marios;Im, Myungshin;Kim, Jae Woo;Lee, Seong Kook;Chapman, Scott
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.41.1-41.1
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    • 2014
  • Although the link between activity in the nuclei of galaxy and galactic mergers has been under scrutiny for several years, it is still unclear to what extent and for which populations of active galaxies merger-triggered activity is relevant. The environment of AGN allows an indirect probe of the past merger history and future merger probability of these systems, suffering less from sensitivity issues while extending to higher redshifts, compared to traditional morphological studies of AGN host galaxies. Here we present results from our investigation of the environment of radio selected sources out to redshift z=2. We employ the first data release J-band catalog from the new near-IR Infrared Medium-Deep Survey (IMS) and 1.4 GHz radio data from the Faint Images of the Radio Sky at Twenty-cm (FIRST) survey and a deep dedicated VLA survey of the VIMOS field, covering a combined total of ~20 sq. degrees. Given the flux limit of the combined radio catalog (0.1 mJy), we probe a radio luminosity range of 10^36-10^44 erg/s. Using the second and fifth closest neighbor density parameters, we test whether active galaxies inhabit denser environments and study these overdensities in terms of both distance to the AGN and its luminosity. We find evidence for a sub-population of radio-selected AGN that resides in significantly overdense environments at small scales, although we do not find significant overdensities for the bulk of our sample. We do not recover any dependence between the AGN radio-luminosity and overdensities. We show that radio-AGN inhabiting the most underdense environments in the field have vigorous ongoing star formation. We interpret these results in terms of the triggering and fuelling mechanism of radio-AGN.

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ON THE NATURE OF SODIUM EXCESS OBJECTS

  • Jeong, Hyunjin;Yi, Sukyoung K.;Kyeong, Jaemann;Sarzi, Marc;Sung, Eon-Chang;Oh, Kyuseok
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.47.2-47.2
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    • 2014
  • Several studies have reported the presence of sodium excess objects having neutral atomic absorption lines at $5895{\AA}$ (NaD) and $8190{\AA}$ that are deeper than expected based on stellar population models that match the stellar continuum. The origin of these lines is therefore hotly debated. van Dokkum & Conroy proposed that low-mass stars (0.3M) are more prevalent in massive early-type galaxies, which may lead to a strong NaI 8190 line strength. It is necessary to test this prediction, however, against other prominent optical line indices such as NaD, Mgb, and Fe5270, which can be measured with a significantly higher signal-to-noise ratio than NaI 8190. We identified a new sample of roughly one thousand NaD excess objects (NEOs; ~8% of galaxies in the sample) based on NaD line strength in the redshift range 0.00$H{\beta}$ line strengths and significant emission lines, which are indicative of the presence of young stellar populations. This result implies that the presence of the interstellar medium and/or dust contributes to the increase in NaD line strengths observed for these galaxies.

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