• 제목/요약/키워드: red phosphor

검색결과 233건 처리시간 0.027초

적색 형광체 Gd2-x-yLixEuyO3의 발광 특성 (Luminescence Properties of Red Phosphor Gd2-x-yLixEuyO3)

  • 조신호;변송호;김동국;박중철
    • 한국전기전자재료학회논문지
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    • 제15권3호
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    • pp.258-263
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    • 2002
  • We present a new toed phosphor, $Gd_{2-x-y}Li_xEu_yO_3$ with superior luminescent Properties compared to the commercially available red phosphor $Y_2O_3:Eu^{3+}$. The phosphor, with a diameter of about $2\mu\textrm{m}$, consists of the psedospherical particles in a regular array. The photoluminescence measurements as a function of the laser power and the Eu mole fraction were performed at zoom temperature The luminescence intensity linearly increases as both the laser power and the Eu mole fraction Increase. As for the dependence on cathodoluminescence, the incorporation of Eu and Li ions into $Gd_2O_3$ lattice brings about an increase in luminescent efficiency. The highest emission intensity for the phosphor occurs at the applied voltage of 500 V, its value is larger than that of $Y_2O_3:Eu^{3+}$ powder by 70%.

New Red Phosphor with the Improved Color Purity for PDP Applications

  • Mho, Sun-Il
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.257-259
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    • 2002
  • As a new host material for a red phosphor for PDP applications, has studied (Y,Gd)$Al_3(BO_3)_4$ which gives non-centrosymmetric sites for $Eu^{3+}$ activators. Vacuum ultraviolet (VUV) excitation spectrum of new red phosphor (Y,Gd)$Al_3(BO_3)_4$:$Eu^{3+}$ has two broad bands. One band with the absorption edge at ca. 168 nm is the band-gap absorption of aluminoborate and the other broad band centered 240 nm is the charge transfer transition between $Eu^{3+}$ and the neighboring oxygen anions. The PL spectrum shows the strongest emission at 617 nm due to the electric dipole $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$, whose luminescent chromaticity is (0.67, 0.33).

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Luminescence Properties of $Y_2SiO_5:Eu^{3+}$ as Red-Emitting Phosphor for White Light Emitting Diodes

  • Song, Y.H.;Park, W.J.;Yoon, D.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1303-1304
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    • 2009
  • In order to apply to the White light emitting diodes (WLEDs), The $Y_2SiO_5:Eu^{3+}$ as red phosphor was synthesized by solid state reaction method. The highest emission of $Y_2SiO_5:Eu^{3+}$ was shown when the $Eu^{3+}$ concentration was 0.02. A single phase was observed from X-ray diffraction (XRD) analysis of synthesized samples and secondary phase wasn't found.

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Synthesis and photoluminescence of Ca3Si3O8F2: Ce4+, Eu3+, Tb3+ phosphor

  • Suresh, K.;PoornachandraRao, Nannapaneni V.;Murthy, K.V.R.
    • Advances in materials Research
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    • 제3권4호
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    • pp.227-232
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    • 2014
  • $Ce^{4+}$, $Eu^{3+}$, $Tb^{3+}$ co-doped $Ca_3Si_3O_8F_2$ phosphor was synthesized via solid state reaction method using $CaF_2$, $CaCO_3$ and $SiO_2$ as raw materials for the host and $Eu_2O_3$, $CeO_2$, and $Tb_4O_7$ as activators. The luminescent properties of the phosphor was analysed by spectrofluorophotometer at room temperature. The effect of excitation wavelengths on the luminescent properties of the phosphor i.e. under near-ultraviolet (nUV) and visible excitations was investigated. The emission peaks of $Ce^{4+}$, $Eu^{3+}$, $Tb^{3+}$ co-doped $Ca_3Si_3O_8F_2$ phosphor lays at 480(blue band), 550(green band) and 611nm (red band) under 380nm excitation wavelength, attributed to the $Ce^{4+}$ ion, $Tb^{3+}$ ion and $Eu^{3+}$ ions respectively. The results reveal that the phosphor emits white light upon nUV (380nm) / visible (465nm) illumination, and a red light upon 395nm / 535nm illumination. RE ions doped $Ca_3Si_3O_8F_2$ is a promising white light phosphor for LEDs. The emission colours can be seen using Commission international de l'eclairage (CIE) co-ordinates. A single host phosphor emitting different colours under different excitations indicates that it is a potential phosphor having applications in many fields.

Synthesis of the sulfide phosphors and white light generation based on InGaN chip

  • Kim, Kyung-Nam;Kim, Jae-Myung;Choi, Kyoung-Jae;Park, Joung-Kyu;Kim, Chang-Hae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.679-682
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    • 2004
  • $SrGa_2S_4$:Eu green phosphor and SrS:Eu red phosphor have been synthesized by co-precipitation method, respectively. Two sulfide phosphors were influenced by oxygen defect in host materials. Excitation spectra of these phosphors have high efficiency at the long wavelength region. And emission efficiency is increased under the excitation wavelength of 465nm. The combination of thiogallate green phosphor and sulfide red phosphor based on blue light InGaN chip has made it possible to emit white light.

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화학적 방법에 의한 $Ga_{2}O_{3}$적색 형광체 분말의 제조 (Preparation of $Ga_{2}O_{3}$Red Phosphor Powders by Chemical Method)

  • 서강원;박인용;이종원;김선태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.851-854
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    • 2001
  • Europium-activated Ga$_2$O$_3$powders were prepared by modified "Pechini method" from mixed aqueous solutions of gallium nitrate, europium nitrate, ethylene glycol and citric acid. The formation process and structure of the phosphor powders were investigated by means of TG/DTA, XRD and SEM. It has been found that the phosphor powders were amorphous up to 50$0^{\circ}C$ and changed into crystalline $\beta$-Ga$_2$O$_3$phase above $600^{\circ}C$. The resulting nano-sized powders were obtained. Red luminescence in emission spectra were observed at room temperature.

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Al과 Pr이 첨가된 SrTiO$_3$ 적색 형광체의 발광 특성 (The Luminescent Properties of SrTiO$_3$ :Al, Pr Red Phosphor)

  • 박정규;류호진;박희동;최승철
    • 한국세라믹학회지
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    • 제36권5호
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    • pp.478-482
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    • 1999
  • SrTiO3 :Al, Pr phosphor as an oxide compound phosphor is expect to be applied for a field emission display(FED). In this phosphor the excitation spectrum shows a different tendency according to an addition Al3+ and Pr3+ In this excitation spectrum the main peak at 359 nm represent excitation level of Pr3+(1S0longrightarrow1D2 transition) and the absorption characteristic according to Ti/Sr molar ratio is influenced by the structure symmetry. The emission spectrum exhibits the red luminescence with the radiative decay of the 1D2 states(1D2 longrightarrow3H4 transition) The concentration quenching phenomena at 1D2 state shows up as Al3+ and Pr3+ ion concentration increases.

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Luminescent Properties of Two-Ions Doped Phosphors for LED Application

  • Kim, Tae-Gon;Kim, Young-Sic;Im, Seoung-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.52-55
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    • 2009
  • A red phosphor, $(Sr,Ca)_2P_2O_7:Eu^{2+},Mn^{2+}$, for UV-LED was synthesized under a reducing atmosphere, and its luminescent properties were investigated. The phosphor absorbs ultraviolet light at around 400 nm and efficiently emits red light at approximately 610 nm through an energy transfer from $Eu^{2+}$ to $Mn^{2+}$. Using the varied input current test for the phosphor-loaded LED lamps, it was found that the luminescent efficiency of the phosphor decreased with increasing light flux. This might be due to an increased probability of excited-state absorption and the consequent non-radiative relaxation in $Mn^{2+}$ ions in the condition of high photon influx.

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Color-Matching LCD를 위한 형광체 전환효율의 측정과 분석 (Measurement and Analysis of Phosphor Conversion Efficiency for Color-Matching LCDs)

  • 전화준;임교성;나대길;권진혁
    • 한국광학회지
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    • 제24권5호
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    • pp.256-261
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    • 2013
  • 고효율 color-matching LCD (liquid crystal display)에 적용하기 위하여, 445 nm의 청색 여기광을 사용하여 적색 및 녹색 형광체의 전환효율과 양자효율을 측정 분석하였다. 투명한 기판 및 표면이 반사처리된 기판에 각각 두께 50 ${\mu}m$의 적색, 녹색 형광체를 코팅하고, 적분구를 사용하여 형광의 세기를 측정하였다. 적색 형광체 및 녹색 형광체에 대해서 전환효율은 각각 41.4%과 46%였으며, 양자효율은 각각 60.4%와 53.5%였다. 제조사의 제원과의 차이점에 대해서 검토되었다.