• Journal of the Korea Organic Resources Recycling Association
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• v.20 no.2
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• pp.44-52
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• 2012

As an alternative strategy in the era of high level petroleum cost, the study focused to suggest the way on the revitalization of renewable energy through the impact on introduction effect of renewable energy in green village. Total feasible solar energy production is 6.73 GWh/yr along with the biomass energy producing electric power energy is 134.06 GWh/yr, the two category's total electric power energy is 233.19 GWh/yr, which is possible to achieve the selfsufficiency of energy by 33% for total energy consumption of 705.80 GWh/yr in the region. The calculated feasibility on the carbon dioxide reduction, carbon dioxide reduction level is 1,891 ton_$CO_2$ by agricultural byproducts, 43,635 ton_$CO_2$ by livestock waste, 395 ton_$CO_2$ by municipal waste, 50,324 ton_$CO_2$ by forest byproducts, the total biomass shows 96,245 ton_$CO_2$, while the carbon dioxide reduction of solar light energy is 2,251 ton_$CO_2$, 1,383.3 ton_$CO_2$ by solar heat energy, the total solar energy shows 3,634 ton_$CO_2$. So total carbon dioxide reduction effect shows 99,879 ton_$CO_2$.

• Resources Recycling
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• v.17 no.2
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• pp.76-84
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• 2008

There are several kinds of battery such as zinc-air battery, lithium battery, manganese dry battery, silver oxide battery, mercury battery, sodium-sulphur battery, lead battery, nickel-hydrogen secondary battery, nickel-cadmium battery, lithium ion battery and alkaline battery, etc. These days it has been widely studied for the recycling technologies of the used battery from view points of economy and efficiency. In this paper, patents on the recycling technologies of the used manganese dry battery were analyzed. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), and Korea (KR) from 1986 to 2006. Patents were collected using key-words searching and filtered by filtering criteria. The trends of the patents were analyzed by the years, countries, companies, and technologies.

• Resources Recycling
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• v.20 no.3
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• pp.55-61
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• 2011

In order to develop economical production process from metallurgical grade silicon(MG-Si) to solar grade(SOG-Si), removal of boron by slag treatment was investigated at 1823 K using CaO-$SiO_2$ based slags. In the present study boron removal ratio in CaO-$SiO_2$ stags and $CaCO_3-SiO_2$ slags were increased to 63% and 73% respectively with slag basicity (%CaO/$%SiO_2$). However, bubbling time with Ar gas of slag and metal was not affected on removal ratio of boron. The addition of $Na_2CO_3$ to CaO-$SiO_2$ slags did not improve the removal ratio of boron from molten silicon. Boron contend was decreased from 20.6 ppm to 1.03 ppm by three times treatment using $CaCO_3-SiO_2$ slag (basicity=1.2).

• Resources Recycling
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• v.29 no.1
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• pp.3-16
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• 2020

This work provides an overview of the steel production process, pretreatment and tramp elements of scraps and recycling technology of dust generated from steelmaking process. Steel is the most common metal used by mankind, with the world production of crude steel in 2018 exceeding 1.8 billion tonnes. Recycling of ferrous scraps reduces CO₂ emissions by about 42 % and saves about 60 % of energy, compared to production steel from iron ore. Steel scraps are usually recycled to both an electric arc furnace (EAF), scrap-based steelmaking and the basic oxygen furnace (BOF), in ore-based steelmaking. EAF steelmaking, which uses iron scrap as a main raw material, is changing to an energy-saving type with a device for preheating scrap. Dust generated from the steelmaking process is recycled in various ways in the steel mill to recover iron and zinc.

• Journal of Energy Engineering
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• v.8 no.1
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• pp.137-142
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• 1999

지구 온난화 현상의 주된 원인인 CO2 가스의 분해를 위해, 스트론튬 페라이트를 이용한 CO2 가스 분해 반응에 대해 연구하였다. CO2 가스 분해를 위한 반응 매체로 스피넬형 조성과 마그네토프롬바이트형 조성의 스트론튬 페라이트 미세분말을 공침법으로 제조한 후, H2 가스로 환원시켜 산소부족형 스트론튬 페라이트 분말을 제조하였다. 이 산소부족형 스트론튬 페라이트 분말은 CO2 가스를 환원, 분해시키면서 산화된다. 이러한 원리를 이용한 CO2 분해 반응에서 스피넬형 조성 스트론튬 페라이트 분말이 마그네토프롬바이트형 조성 분말 보다 빠르게 많은 양의 CO2 가스를 분해 시켰다. 페라이트 중의 스트론튬이 산화·환원 반응을 촉진시키는 것을 관찰할 수 있었다.

• Resources Recycling
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• v.5 no.1
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• pp.42-49
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• 1996

The synthesis or amorphous calc~um carbonale in the reacllons oi cslcn~m hydroxide suspension - CO1 systcni !\.;is studied by uslng rneasulemel~ts of eleclrical conductivity, x-ray diftractorneter and t~ansmission eleclron microscope. The m~tial product of reactious was noncrystalline shape oI amorphous calcium carbo~iale confirmed by x-ray diffraction analyses. The amorphous calcium carbonate covered lhc surlace of calcium hydroxldc grains. Tlic electrical conductivity of suspension dec~eascd dramatically when the amorphous calcium carhonate was synlliesizcd. A portion or the amorplious calcmm carbonale clia~iged ilito [he chain calcite as an intermcdrate product. Thc continuo~~cso nrluctivity measurements of suspension were ahle to delennine the starting point of the synthesis and the mechallism of carbonation process

• Resources Recycling
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• v.20 no.1
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• pp.28-36
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• 2011

More than 50% of refractory materials generated from high-temperature melting furnace was not carbonized and could be recycled by adopting proper separation process. In the present work, the separation of refractory materials has studied by adopting color sorting technology to promote the recycling of waste refractory. Purity of the refractory materials was obtained with at 97.2%, color temperature of sorter light source 6,500K, which gives less interference of surrounding light source. Purity and separation efficiency were improved as size is setting bigger and lower conveyer belt speed. It is revealed that optimum conditions were color temperature 6,500K, conveyer belt speed 1,000 mm/sec, particle size -20 mm, etc. To improve purity and separation efficiency on below 10mm size, the resolution of should be fixed camera and it narrow recognition range. As a result of the study, color sorting technology could be used for separation of waste refractory materials and will contribute to promote the waste recycling.

• Resources Recycling
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• v.29 no.6
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• pp.65-72
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• 2020

Black dross is a dark gray dross generated during the aluminum recycling process that uses flux, and contains NaCl, KCl, Al2O3, MgO, etc. Black dross is separated into soluble substances (NaCl, KCl) and insoluble substances (Al2O4, MgO) through the dissolution process. Soluble materials can be reused as salt flux, and Al2O3 and MgO can be upcycled to various ceramic materials through the synthesis process. In this study, Mayenite was synthesized using Al2O3 and MgO recovered from black dross, and the synthesis was performed according to the mixing ratio and reaction temperature. It was confirmed that when Mayenite was synthesized using black dross (spinel) and CaCO3, precursors were changed to Mg0.4Al2.4O4 and CaO at 700 ℃, and to Ca12Al14O33 (Mayenite) after 800 ℃. In the mixing conditions experiment, it was confirmed that the Mayenite XRD peak increased with increase of the CaCO3 content, and the Mg0.4Al2.4O4 XRD peak decreased. As a result of the BET analysis of the synthesized powder, the surface area decreased as the fine particles were grown and agglomerated in the process of generating mayenite.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.532-536
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• 2001

LD slag, that is, a by-product of steel making process, has been mainly used as land construction materials. Recently, the seashore application of LD slag was tried in Japan and Korea but the reaction between LD slag and seawater was not studied yet. We tried to clarify the leaching reaction and/or mechanism of LD slag and the reaction between seawater and LD slag. We tried to apply these results to the decarbonization of seawater for seawater magnesia process. The high pH solution(over 12) was injected into the sea water and the pH of mixed liquid was adjusted to 9.8. This mixed solution was aged for 8 hours and the 104ppm of CO$_3$$^{-2}$ in the sea water was decreased to 23ppm with the negligible loss of $Mg^2$$^{+}$. The slag particle was directly inserted into the seawater fur practical application. The 0.5~1mm particles were suitable for decarbonization when 5 grade slags mentioned above were reacted with sea water. In this case, the content of CO$_3$$^{-2}$ in the sea water was 53 ppm with the negligible loss of $Mg^2$$^{+}$ after 8 hours aging. The direct application of slag particle fur the decarbonization of seawater takes more reaction time.ime.

• Resources Recycling
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• v.3 no.1
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• pp.9-16
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• 1994

Fine cobalt metal powders was produced from domestic Stellite scrap by decomposing it with molten sodium hydroxide. Complete decomposition of the scrap could be obtained with the weigth ratio of sodium hydroxide to Stellite being about 2 at the temperature ranges of $750~800^{\circ}C$ for an hour. The cobalt-bearing compound was identified as $Co_2O_3{\dot}H_2O$ by X-ray analysis and D.T.-T.G.a.. The compound was then digested in HCI to form cobalt chloride, and after iron removal by adjusting the pH of the solution, cobaltous or cobaltic hydroxide was precipitated at the pH of about 13 or 4, respectively. The precipitates were reduced by hydrogen in the temperatures of $400~500^{\circ}C$ to fine cobalt powders of high purity with the size of 1.0 to $1.5\mu\textrm{m}$. The recovery of cobalt from Stellite scrap was about 75~86% by weight.