• Resources Recycling
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• v.28 no.1
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• pp.47-54
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• 2019

In this study, the wastes were used as fuels for direct reduction iron (DRI) production to reduce production cost and recycle the wastes. We examined the effects of wastes on the reduction behavior of DRI manufacture and the possibility of using wastes as auxiliary fuels. The proximate and Ultimate analysis were carried out to confirm the properties of wastes as fuels, and high-quality reduced irons were fabricated by using the waste as an auxiliary fuel. The metallization of reduced irons increased as the calorific value increase of auxiliary fuel. Especially, the reduced irons fabricated from the waste tires and vinyl plastics which had high heat energy and volatile matters showed higher metallization than the others. The high calorific value and volatility of waste were significant properties as fuel. The high quality DRI could be fabricated with wastes as auxiliary fuels through optimization of reaction conditions.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.1
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• pp.163-170
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• 2019

In recent years, various types of industrial wastes are rapidly increasing with the development of high-tech industries. Specially, high-density waste glass of CRT TV containing heavy metals are buried or disposed of due to reprocessing costs and environmental pollution problems. Thus, more basic research is needed to recycle waste such as CRT waste glass such. In this study, the fundamental properties and radiation shielding performance of mortar specimens substituted CRT waste glass as a fine aggregate were analyzed and their application to shielding materials was evaluated. According to the results, the bulk density of mortar specimen replaced with CRT waste glass was increased and the compressive strength and flexural strength were decreased. Meanwhile, the CRT waste glass substitute specimen containing a large amount of lead component showed a higher shielding performance than the general mortar specimen. Especially, the linear attenuation coefficient of CRT waste glass in $122KeV{\cdot}^{57}Co$ of the low energy field was 2.5 times higher than that of normal specimen.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.1
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• pp.22-28
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• 2019

Cement is a basic material for the construction industry and it requires high temperature sintering when manufacturing cement. $CO_2$ emissions from raw materials and fuels are recognized as new environmental problems and efforts are underway to reduce them. Techniques for reducing $CO_2$ in concrete are also recommended to use blended cement such as blast furnace slag or fly ash. In addition, the construction waste generated in the dismantling of concrete structures is recognized as another environmental problem. Thus, various methods are being implemented to increase the recycling rate. The purpose of this study is to utilize the inorganic raw materials generated during the dismantling of the structure as a raw material for the low carbon type cement binder. Such as, waste concrete powder, waste cement block, waste clay brick and waste textile as raw materials for low carbon type cement binder. From the research results, low carbon type cement binder was manufactured from the raw material composition of waste concrete powder, waste cement block, waste clay brick and waste textile.

• Journal of the Korean Geosynthetics Society
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• v.18 no.1
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• pp.79-89
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• 2019

The field measurement and laboratory experiment were conducted to investigate the effect of reducing the surface temperature of the functional aspect of the heat island phenomenon of the permeable block which is made the recycled synthetic resin rather than the existing concrete permeable block. Field measurement was taken for 3 days in consideration of dry condition and wet condition and laboratory experiment was divided into dry condition, rainfall simulating condition, and wetting condition. The variations of temperature and the evaporation rate of water moisture content after experiment were confirmed. As a result of field measurement, it is confirmed that the surface temperature decreases due to the difference in albedo of the pore block surface rather than the cooling effect due to the latent heat of vaporization. The evaporation of moisture in a dry state where drought persisted or a certain level of moisture was not maintained in the surface layer. As a result of laboratory experiment, resin permeable block gives higher surface temperature when it is dry condition than concrete permeable block, but the evaporation of water in the pore is kept constant by capillary force in rainfall simulation condition, and higher temperature reduction rate. As a result of measuring the evaporation rate after laboratory experiment, it is confirmed that the effect of reducing temperature is increased as the evaporation rate of water is higher. Based on these results, correlation formula for evaporation rate and temperature reduction rate is derived.

• Journal of the Korean Geotechnical Society
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• v.35 no.10
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• pp.33-45
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• 2019

In this study, in order to recycle a large amount of rocks and weathered mudstones produced by civil engineering projects such as railways and highways, as materials for roadbeds or embankment materials, circumferential specimens with a diameter of 5 cm and a height of 10 cm were made. A mudstone that weathered rapidly during rainfall was collected from Pohang construction sites. The weathered mudstone passed through a 2 mm sieve. It was prepared with the cement ratio, the sand ratio, curing condition and curing days. Three specimens were prepared according to each condition and then the unconfined compressive test, durability test and SEM analysis were performed to evaluate the engineering properties of the cemented soil. In the case of 28 days cured specimen, the strength of under-water cured specimens was 32-55% and the durability index was about 15% higher than air cured specimens. In addition, when the CR increased from 8% to 16%, the unconfined compressive strength (UCS) of pure mudstone cemented soil under water increased by about 1.6 times and the durability index increased by about 1.9 times. When the SR increased from 0% to 50%, the UCS of the specimen with SR = 10% was slightly less than or equal to specimen with SR = 0%. Then, as the SR became 30-50%, the UCS increased up to 51%. Unlike the UCS, the durability index increased continuously as the SR increased. As a result of SEM analysis, when SR was 50% rather than SR = 0%, the contact between sand particles increased and they were connected to each other. Such contact between these particles resulted in the increase of strength.

• Journal of Forest and Environmental Science
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• v.37 no.1
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• pp.52-61
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• 2021

Decay fungi can decompose plant debris to recycle carbon in the ecosystem. Still, they can also be fungal pathogens, which can damage living trees and/or wood material and cause a large amount of timber loss. We isolated and identified basidiomycetous fungi from the decayed bark of Mongolian oak wrapped with sticky roll traps. The degrading enzyme activities were then tested for all fungal isolates. The decay ability of selected isolates was assessed based on the weight loss of wood discs after inoculating with culture suspension of decay fungi under the different humidity levels. A total of 46 basidiomycetous fungal isolates belonged to 12 species, and 10 genera were obtained from Jong Myo (16 isolates), Chang Kyung palace (7 isolates), Cheong Gye (10 isolates), and Gun Po (13 isolates). Gymnopus luxurians was the most dominant fungus in the present study, and this species distributed in all survey sites with 9 isolates in Jong Myo, followed by 3 isolates in Chang Kyung palace, while Cheong Gye and Gun Po had only 1 isolate each. Among 46 isolates, 44 isolates secreted at least one enzyme, while 25 isolates produced both cellulase and phenol oxidase enzymes, and 2 isolates produced neither. The assessment of decay ability by artificial inoculation indicated that the weight loss of wood discs was significantly influenced by humidity conditions when inoculated with bark decay fungi. The percent weight losses by G. luxurians inoculation in RH of 90-100% and RH of 65-75% were 4.61% and 2.45%, respectively. The weight loss caused by Abortiporus biennis were 6.67% and 0.46% in RH of 90-100% and RH of 45-55%, respectively. The humidity reduction approach should be applied for further studies to control the growth and spread of bark decay fungi on the trunks wrapped with sticky roll traps.

• Journal of the Korean GEO-environmental Society
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• v.12 no.12
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• pp.71-78
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• 2011

This paper aims to present the evaluation of engineering characteristics and reusing possibility of waste powders produced in dolomite and limestone nonmetal mining by physical and mechanical experiments on compaction, uniaxial compressive strength, permeability, chemical composition, and so on. Granite soil, 2 types of limestone waste powder, and 1 type of dolomite waste powder were used for main materials, and cement and bentonite were used for admixed materials in this experiments. The findings based on the experimental results are the severe difference of chemical composition of the dolomite & limestone waste powder and the crushed rock waste powder, and the outstanding of engineering characteristics of the dolomite waste powder with high content of MgO compared with the limestone waste powder. The engineering properties on compaction, uniaxial compressive strength, and permeability are enhanced with increase of admixed ratio of waste powder on granite soil. From the experimental results, it can be suggested that the dolomite waste powder admixed with in-situ granite soil is useful as geo-materials with considering of distribution costs.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.555-561
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• 2011

The objective of this study is the development of carbon recycle technology which converts $CO_2$ captured from flue gas to CO or carbon and reuse in industrial fields. Since $CO_2$ is very stable and difficult to decompose, metal oxide was used as an activation agent for the decomposition of $CO_2$ at low temperature. Metal oxides which convert $CO_2$ to CO or carbon at $500^{\circ}C$ were prepared using Zn-ferrite by the solid state reaction and hydrothermal synthesis. The behaviors of $CO_2$ decomposition were studied using temperature programmed reduction/oxidation (TPR/TPO) and thermogravimetric analyzer (TGA). Zn-ferrite containing 5 wt% ZnO showed the largest reduction and oxidation. Reduction by $H_2$ was 26.53 wt%, oxidation by $CO_2$ was 25.73 wt% and 96.98% of adsorbed $CO_2$ was decomposed to $CO_2$ and carbon with excellent oxidation-reduction behaviors.

• Clean Technology
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• v.27 no.1
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• pp.24-32
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• 2021

Unburned carbon (UC) was successfully separated from fly ash by up to 85.8% in weight via froth flotation using soybean oil as a collector. An 18 wt% yield of microceramics (CM) could be achieved by employing a hydro cyclone separator located immediately after the flotation equipment. UC and CM were tested as alternatives to weight-adding material and polymer (especially polypropylene in this study) filler, respectively. Large particles of UC were broken down into smaller ones via ball milling to have an average particle diameter of 10.2 ㎛. When crushed UC was used as an alternative to clay as a rubber weight-adding material, a somewhat lower tensile strength and elongation rate than the allowed values were unfortunately obtained. In order to satisfy the standard limits, further treatment of UC is required to enhance surface energy for more intimate bonding with rubber. CM was observed in spherical forms with an average diameter of 5 ㎛. The surface of the CM particles was modified with phenol, polyol, stearic acid, and oleic acid so that the surface modified CM could be used as a polypropylene-filling agent. The flowability was good, but due to the lack of coupling forces with polypropylene, successful impact strength and flexural strength could not be obtained. However, when mixing the surface-modified CM with 1% silane by weight, a drastic increase in both the impact strength and flexural strength were obtained.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.6
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• pp.180-188
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• 2020

To replace Japanese coal ash used in the domestic cement production and to recycle large quantities of domestic pond ash, it is essential to develop the technologies for quality control of cement by using the domestic pond ash. Thus, in this study, the feasibility of using the pond ash as a raw material for cement was investigated through chemical composition and microstructure analysis. As a result, most of the domestic pond ash contained slightly more Fe2O3, chloride, and unburned carbon contents than Japanese coal ash. In particular, the contents of chloride were considerably low in the pond ash that was transferred to fresh water or collected from surface of landfill area. However, since circulating fluidized bed boiler coal ash had relatively high SO3 contents causing durability problems of cement, it was not suitable for use as a raw material for cement. Thus, to replace Japanese coal ash with the domestic pond ash, it is necessary to introduce the adjustment of mixture proportion of cement raw materials and the process of removing chloride in the pond ash.