• 제목/요약/키워드: recovery process

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실제(實際) 사진폐액(寫眞廢液)의 순환(循環) 전해채취(電解採取) 공정(工程)에 의한 은(銀)의 환원(還元) 특성(特性) (Silver recovery from photographic wastewater by electrowinning process with electrolyte recirculation)

  • 정원주;김동수
    • 자원리싸이클링
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    • 제16권1호
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    • pp.54-58
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    • 2007
  • 실제 사진폐액에서 은의 회수를 위한 연속순환식 환원 공정을 적용하여 전해시간 및 두 전극간의 전압 차, 농도에 따른 영향을 검토하였다. 희석된 사진폐액에서의 은의 전해효율은 적용전압이 증가하면서 효율이 증가하다가 6V 정도에서 최고의 효율을 보였다. 그러나 그 이상 전압이 증가할수록 은의 회수율은 낮아지는 경향을 보였다. 희석되지 않은 원 사진폐액의 경우에서는 실험조건 하, 전해반응 시 적용 전압이 낮아질수록 효율을 높일 수 있음을 확인하였다.

250kW급 폐열회수 시스템용 유기랭킨사이클 배관 열유동해석에 관한 연구 (Thermal and Flow Analysis of Organic Rankine Cycle System Pipe Line for 250 kW Grade Waste Gas Heat Recovery)

  • 김경수;방세경;서인호;이상윤;이중섭
    • 한국기계가공학회지
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    • 제18권4호
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    • pp.26-33
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    • 2019
  • This study is a thermal and flow analysis of Organic Rankine Cycle (ORC) pipe line for 250 kW grade waste gas heat recovery. We attempted to obtain the boundary condition data through the process design of the ORC, which can produce an electric power of 250 kW through the recovery of waste heat. Then, we conducted a simulation by using STAR-CCM+ to verify the model for the pipe line stream of the 250 kW class waste heat recovery system. Based on the results of the thermal and flow analyses of each pipe line applied to the ORC system, we gained the following conclusion. The pressure was relatively increased at the pipe outside the refracted part due to the pipe shape. Moreover, the heat transfer amount of the refrigerant gas line is relatively higher than that of the liquid line.

Pd 분리막을 이용한 수소동위원소 회수 실험과 공정 시뮬레이션 (Hydrogen Isotopes Recovery Using Pd Membrane and Process Simulation)

  • 정우찬;박종환;한상우;장민호;이현곤
    • 한국수소및신에너지학회논문집
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    • 제32권4호
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    • pp.219-227
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    • 2021
  • Hydrogen isotopes, which are used as raw materials in fusion reaction, participate in the reaction only in small amount, and most of them are released together with impurities. In order to recover and reuse only hydrogen isotopes from this exhaust gas, a recovery process is required, and most of the hydrogen isotopes can be recovered using a Pd Membrane. In this study, the recovery rate of hydrogen isotopes was measured through the first and second stage Pd membrane experiments. In the case of the experiment using a single stage Pd membrane, about 99.2%, and in the case of the first stage and second stage Pd membrane connection experiments, a recovery rate of 99.9% or more was obtained. Therefore, the recovery rate of Pd membrane process applied to hydrogen can be applied to hydrogen isotopes. In addition, the simulation model was established using aspen custom modeler, a commercial software, and the validity of the simulation was checked by applying the references and experimental data. The simulation results based on the experimental data showed a difference of 2% or less.

Optimization of operating parameters to remove and recover crude oil from contaminated soil using subcritical water extraction process

  • Taki, Golam;Islam, Mohammad Nazrul;Park, Seong-Jae;Park, Jeong-Hun
    • Environmental Engineering Research
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    • 제23권2호
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    • pp.175-180
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    • 2018
  • Box-Behnken Design (BBD) under response surface methodology (RSM) was implemented to optimization the operating parameters and assess the removal and recovery efficiencies of crude oil from contaminated soil using subcritical water extraction. The effects of temperature, extraction time and water flow rate were explored, and the results indicate that temperature has a great impact on crude oil removal and recovery. The correlation coefficients for oil removal ($R^2=0.74$) and recovery ($R^2=0.98$) suggest that the proposed quadratic model is useful. When setting the target removal and recovery (>99%), BBD-RSM determined the optimum condition to be a temperature of $250^{\circ}C$, extraction time of 120 min, and water flow rate of 1 mL/min. An experiment was carried out to confirm the results, with removal and recovery efficiencies of 99.69% and 87.33%, respectively. This result indicates that BBD is a suitable method to optimize the process variables for crude oil removal and recovery from contaminated soil.

습식 화학적 방법에 의한 하수 슬러지 소각재에서의 인 회수 기술동향 (Trends of phosphorus recovery technology from sewage sludge ash by wet chemical method)

  • 이민수;김동진
    • 상하수도학회지
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    • 제32권2호
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    • pp.131-143
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    • 2018
  • Phosphorus (P) is a limited, essential, and irreplaceable nutrient for the biological activity of all the living organisms. Sewage sludge ash (SSA) is one of the most important secondary P resources due to its high P content. The SSA has been intensively investigated to recover P by wet chemicals (acid or alkali). Even though $H_2SO_4$ was mainly used to extract P because of its low cost and accessibility, the formation of $CaSO_4$ (gypsum) hinders its use. Heavy metals in the SSA also cause a significant problem in P recovery since fertilizer needs to meet government standards for human health. Therefore, P recovery process with selective heavy metal removal needs to be developed. In this paper some of the most advanced P recovery processes have been introduced and discussed their technical characteristics. The results showed that further research is needed to identify the chemical mechanisms of P transformation in the recovery process and to increase P recovery efficiency and the yields.

$\theta$-정합을 이용한 QAM 복조용 Carrier Recovery (A New Carrier Recovery Algorithm Usign $\theta$-matching method for QAM Demodulator)

  • 박휘원;장일순정차근조경록
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1998년도 추계종합학술대회 논문집
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    • pp.179-182
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    • 1998
  • Carrier recovery, the process of recoverying the carrier in receiver, removes the phase difference between VCO and the received signal. However, the conventional structure of carrier recovery cannot be applied to multi-level QAM demodulator because of the increasing decision interval and the complexity of control as the number of symbol increases. In this paper, we suggest a new carrier recovery algorithm using $\theta-matching$ algorithm for multi-level QAM demodulation to overcome this problem and analysis the performance and implement it.

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고순도 질소생산용 초저온 공기분리장치 개발 연구 (A Study on the Development of a Cryogenic Air Separation Unit to Produce High Purity Nitrogen)

  • 용평순;문흥만;이성철
    • 한국초전도ㆍ저온공학회논문지
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    • 제3권1호
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    • pp.69-73
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    • 2001
  • For developing the cryogenic air separation unit, it requires some technology such as basic process design. equipment design and manufacturing based on the cryogenic physical properties and separation theory. In this study, we developed a process and equipment for producing high purity nitrogen which has the production capacity of 1600N㎥/h under 1 ppm $O_2$ and $H_2O$. Also we found that the number of theoretical plate(NTP) of distillation column was 44 and maximum nitrogen recovery ration of this process was 42% from the process simulation. The performance test was also carried out for the nitrogen recovery ratio and equipment efficiency. The results showed that the optimum nitrogen recovery was 41% and the maximum equipment efficiency was attained.

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PSA 공정을 이용한 다성분 혼합가스의 수소 분리 (Hydrogen Separation from Multi-Component Mixture Gases by Pressure Swing Adsorption Process)

  • 양세일;안의섭;장성철;최도영;최대기
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.447-450
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    • 2006
  • Hydrogen separation from multi-component mixture gases by the four-bed PSA process was studied experimentally and theoretically using layered bed of activated carbon and zeolited 5A. Effects of the adsorption time, the linear velocity on the process performance were investigated. The adsorption time and linear velocity affected the purity and recovery of the product $H_2$ purity is increases according as the adsorption time and linear velocity decrease; however, $H_2$ recovery shows an opposite phenomena to the purity. PSA process simulation studied to find optimum operation condition. In the results, 50sec adsorption time, 3cm/s linear velocity might be optimal values to obtain more than 99.999% purity and 65% recovery hydrogen.

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Rapid Quenching Dynamics of F Center Excitation by $OH^-$ Defects in KCI

  • 장두전;김필석
    • Bulletin of the Korean Chemical Society
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    • 제16권12호
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    • pp.1184-1189
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    • 1995
  • The rapid quenching dynamics of F center excitation by OH- defects in KCl crystals are investigated by monitoring ground state absorption bleach recovery, using a picosecond streak camera absorption spectrometer. F center absorption bleach in OH--doped crystals shows three distinguishable recovery components with the current temporal resolution, designated as slow, medium and fast components. The slow one is due to the normal relaxation process of F* centers as found in OH--free crystals. The others are consequent on energy transfer from electronically excited F centers to OH--vibrational levels. The fast component is a minor energy transfer process and resulting from the relaxation of somewhat distant, not the closest, associated pairs of F* and OH- defects. The energy transfer between widely separated F* and OH- defects opens up a recovery process via the medium component which is assisted by OH- librations, lattice vibrations and OH- dipole reorientations. The quenching behaviors of F* luminescence and photoionization by OH- are explained well by the relaxation process of the medium component.

습식산화법을 이용한 제강분진 내 아연회수를 위한 최적조건 도출에 관한 연구(Part I; 침출공정) (The Optimization of Hydrometallurgical Process for Recovery of Zinc from Electric Arc Furnace Dust (Part I : leaching process))

  • 문대헌;안상우;김한래;김지태;장순웅
    • 자원리싸이클링
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    • 제24권3호
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    • pp.27-33
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    • 2015
  • 제강분진(Electric Arc Furnace Dusts)은 유해폐기물로 지정되어있는 유해한 환경오염물질이다. 이 분진은 철강산업의 부산물로써 철, 아연, 니켈, 구리 등 많은 유가금속을 포함하고 있어 적절한 처리를 거치면 폐기물이 아닌 자원으로 재활용이 가능하다. 본 연구에서는 국내 전기로에서 발생하는 제강분진을 대상으로 가장 높은 함유량을 가진 아연의 회수를 위한 최적조건을 도출하기 위해 습식침출법을 적용하였다. 분진과 황산의 고액비, 침출시간, $MnO_2$ 투입량 등의 조건을 종합하여 실험을 진행하여 최적 아연회수조건을 도출하였다. 황산농도 3 M, 고액비 1:2, 철 제거를 위한 폭기 1.8 L/min 강도로 2시간에서 95%의 아연 회수율이 관찰되었다. 그러나, 현장 적용의 현실성을 고려한 다른 최적의 조건은 저농도 황산과 $MnO_2$ 3.5 g을 투입했을 경우 약 80 %의 아연 회수율을 나타내었다.