• Title/Summary/Keyword: recombination zone

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Low-Molecular-Weight White Organic-Light-Emitting-Devices using Direct Color Mixing Method

  • Lee, Sung-Soo;Song, Tae-Joon;Ko, Myung-Soo;Cho, Sung-Min
    • Journal of Information Display
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    • v.3 no.2
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    • pp.6-12
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    • 2002
  • In order to achieve white emission from organic light emitting devices (OLEDs), five distinct structures were fabricated and tested. The white emission was obtained using two different color-emitting materials (yellow from rubrene-doped $Alq_3$ and blue from DPVBi) with or without a carrier-blocking layer. For enhancing the red emission, two types of devices with three-color emitting materials were fabricated. The white emission, close to the CIE coordinate of (0.3,0.3), was achieved by using two blocking layers as well that as without a blocking layer. This paper covers the subject of controlling the location of exciton recombination zone. It has been found that there is a trade-off in that the devices with three color emitting layers do not show as much luminescence efficiency compared to those with two color emitting layers, but rather, show distinct red emission in the resultant emission spectra. The highest power efficiency was measured to be 1.15lm/W at 2,000 $cd/m^2$ for a structure with two color-emitting layers.

Simulation Study of Front-Lit Versus Back-Lit Si Solar Cells

  • Choe, Kwang Su
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.38-42
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    • 2018
  • Continuous efforts are being made to improve the efficiency of Si solar cells, which is the prevailing technology at this time. As opposed to the standard front-lit solar cell design, the back-lit design suffers no shading loss because all the metal electrodes are placed on one side close to the pn junction, which is referred to as the front side, and the incoming light enters the denuded back side. In this study, a systematic comparison between the two designs was conducted by means of computer simulation. Medici, a two-dimensional semiconductor device simulation tool, was utilized for this purpose. The $0.6{\mu}m$ wavelength, the peak value for the AM-1.5 illumination, was chosen for the incident photons, and the minority-carrier recombination lifetime (${\tau}$), a key indicator of the Si substrate quality, was the main variable in the simulation on a p-type $150{\mu}m$ thick Si substrate. Qualitatively, minority-carrier recombination affected the short circuit current (Isc) but not the opencircuit voltage (Voc). The latter was most affected by series resistance associated with the electrode locations. Quantitatively, when ${\tau}{\leq}500{\mu}s$, the simulation yielded the solar cell power outputs of $20.7mW{\cdot}cm^{-2}$ and $18.6mW{\cdot}cm^{-2}$, respectively, for the front-lit and back-lit cells, a reasonable 10 % difference. However, when ${\tau}$ < $500{\mu}s$, the difference was 20 % or more, making the back-lit design less than competitive. We concluded that the back-lit design, despite its inherent benefits, is not suitable for a broad range of Si solar cells but may only be applicable in the high-end cells where float-zone (FZ) or magnetic Czochralski (MCZ) Si crystals of the highest quality are used as the substrate.

Highly Efficient Blue Organic Light-emitting Devices Based on Copper Phthalocyanine/Aromatic Diamine Composite Hole Transport Layer

  • Liao, Chi Hung;Tsai, Chih Hung;Chen, Chin H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.724-726
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    • 2004
  • Highly efficient blue organic light-emitting devices (OLEDs) utilizing the idea of copper phthalocyanine (CuPc)/N,N'-bis-(1-naphthyl)-N,N'-diphenyl,1,1'-biphenyl- 4,4'-diamine (NPB) composite hole transport layer (CPHTL) have been fabricated. The effect of inserting CPHTL upon the performance of blue OLEDs with 2-methyl-9,10-di(2-naphthyl)anthracene (MADN) as the blue emitter has been investigated. Compared with the luminous efficiency of the standard blue device without CPHTL (1.33 cd/A), that of the device with 40:60 CuPc/NPB CPHTL has been increased by more than twice up to 2.96 cd/A with a Commission Internationale d'Eclairage (CIE) coordinates of(x = 0.15, y = 0.10) and a power efficiency of 1.46 lm/W (20 mA/$cm^2$) at 6.39 V. The increased device efficiency is attributed to an improved balance between hole and electron currents arriving at the recombination zone.

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Interlayer Engineering with Different Host Material Properties in Blue Phosphorescent Organic Light-Emitting Diodes

  • Lee, Jong-Hee;Lee, Jeong-Ik;Lee, Joo-Won;Chu, Hye-Yong
    • ETRI Journal
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    • v.33 no.1
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    • pp.32-38
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    • 2011
  • We investigated the light-emitting performances of blue phosphorescent organic light-emitting diodes, known as PHOLEDs, by incorporating an N,N'-dicarbazolyl-3,5-benzen interlayer between the hole transporting layer and emitting layer (EML). We found that the effects of the introduced interlayer for triplet exciton confinement and hole/electron balance in the EML were exceptionally dependent on the host materials: 9-(4-tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole, 9-(4-tert-butylphenyl)-3,6-ditrityl-9H-carbazole, and 4,4'-bis-triphenylsilanyl-biphenyl. When an appropriate interlayer and host material were combined, the peak external quantum efficiency was greatly enhanced by over 21 times from 0.79% to 17.1%. Studies on the recombination zone using a series of host materials were also conducted.

Fluorescent white organic light-emitting diode structures with dye doped hole transporting layer

  • Galbadrakh, R.;Bang, H.S.;Baek, H.I.;Lee, C.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1407-1410
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    • 2007
  • This work reports on three primary color fluorescent white organic light emitting diode (WOLED) with simple device structure where only a part of the hole transporting layer was doped with dye. The maximum luminance of the device reaches $35000\;cd/m^2$ at a drive voltage below 11V and external quantum efficiency of the device is above 1% in the wide range of luminance from 10 to $35000\;cd/m^2$ and reaches its highest 1.6% at $500\;cd/m^2$. The chromaticity coordinate shift of the device is negligible in this wide range of luminance. The blue shift of emission color with an increase of current density was attributed to the narrowing of recombination zone width with raise of current density.

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Efficient Deep-Blue Organic Light-emitting Diodes with Double-Emission Layers

  • Seo, Ji-Hoon;Park, Jung-Sun;Seo, Bo-Min;Lee, Kum-Hee;Park, Jung-Keun;Yoon, Seung-Soo;Kim, Young-Kwan
    • Journal of Information Display
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    • v.10 no.3
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    • pp.107-110
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    • 2009
  • Efficient deep-blue organic light-emitting diodes were demonstrated using 4,4'-bis(9-ethyl-3-carbazovinylene)-1,1'-biphenyl doped in double-emission layers (D-EMLs). The D-EML system, which consists of 2-methyl-9,10-di(2-naphthyl)anthracene and 1,4-(dinaphthalen-2-yl)-naphthalene as blue hosts, was employed to broaden the recombination zone and to ensure the good confinement of the holes and electrons. The optimized device showed a peak current efficiency of 4.47 cd/A, a peak external quantum efficiency of 4.09%, and Commission Internationale de L'Eclairage coordinates of (0.16, 0.10).

Acoustic Response of Hydrogen/Liquid Oxygen Flame in Stagnation-Point Flow (정체점 유동장에서 수소-액체산소 화염의 음향파 응답 특성)

  • Park, Sung-Woo;Chung, Suk-Ho;Kim, Hong-Jip
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.4
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    • pp.440-446
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    • 2003
  • Steady-state structure and acoustic pressure responses of GH$_2$-LOx diffusion flames in stagnation-point flow configuration have been studied numerically with a detailed chemistry to investigate the acoustic instabilities. The Rayleigh criterion is adopted to judge the instability of the GH$_2$-LOx flames from amplification and attenuation responses at various acoustic pressure oscillation conditions for near-equilibrium to near-extinction regimes. Steady state flame structure showed that the chain branching zone is embedded in surrounding two recombination zones. The acoustic responses of GH$_2$-LOx flame showed that the responses in near-extinction regime always have amplification effect regardless of realistic acoustic frequency. That is, GH$_2$-LOx flame near-extinction is much sensitive to pressure perturbation because of the strong effect of a finite-chemistry.

Stable efficiency roll-off in blue phosphorescent organic light-emitting diodes using a mixed host structure

  • Lee, Jong-Hee;Lee, Jeong-Ik;Lee, Jun-Yeob;Chu, Hye-Yong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.192-195
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    • 2009
  • We developed highly efficient blue PHOLEDs with reduced roll-off by using a mixed host structure. The balanced charge carrier injection and the distributed recombination zone within emissive layer resulted in a highly stable efficiency roll-off with quantum efficiencies of 20.1 and 18.1 % at a luminance of 1000 and 10000 cd/$m^2$.

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Charge Balance in High Efficiency Blue Phosphorescent Organic Light Emitting Diodes

  • Chopra, Neetu;Lee, Jae-Won;So, Franky
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.184-187
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    • 2009
  • In this paper, we study effect of charge balance on performance of blue phosphorescent organic light emitting diodes (OLEDs). Charge balance determines the location of recombination zone in the OLEDs. By tuning the charge balance in iridium (III) bis[(4,6-difluorophenyl)-pyridinate-N,C2']picolinate (FIrpic) based blue phosphorescent organic light-emitting devices (PHOLEDs) with a high mobility and high triplet energy electron transporting material, we were able to achieve a high current efficiency of 60 cd/A which is a 3X improvement over previous devices with 3,5'-N,N'-dicarbazole-benzene (mCP) host.

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Fabrication and Properties of OLEDs using PECCP Langmuir-Blodgett(LB) Films (PECCP LB 박막을 이용한 유기 발광 타이모드의 제작과 이의 특성)

  • Lee, Ho-Sik;Lee, Won-Jae;Park, Myung-Gyu;Songe, Min-Jeng;Park, Jong-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.831-834
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    • 2000
  • Characteristics of organic light-emitting diodes(OLEDs) were studied with devices made by PECCP[poly(3,6-N-2-ethylhexyl carbazolyl cyanoterephthalidene)] Langmuir-Blodget(LB) films. The emissive organic material was synthesized and named PECCP, which has a strong electron donor group and an electron accepter group in main chain repeated unit. The LB technique was employed to investigate the identification of the recombination zone in the ITO/PECCP LB films/Alq$_3$/Al structure by varying the LB film thickness. PECCP was considered as an emissive layer and Alq$_3$was used as an electron-transport layer. We measured current-voltage(I-V) characteristics, UV/visible absorption, PL spectrum, and EL spectrum of those devises.

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