• 제목/요약/키워드: reactive aggregate

검색결과 49건 처리시간 0.032초

폴리에스테르/카티온화 면 혼방품의 분산염료/반응성염료에 의한 일욕염색계에 관한 연구 (Studies on the One Bath Exhaust Dyeing System of Polyester/Cationized Cotton Blends with Disperse Dye/Reactive Dye)

  • 성우경
    • 한국염색가공학회지
    • /
    • 제10권2호
    • /
    • pp.18-28
    • /
    • 1998
  • in order to overcome disadvantage of the conventional two bath dyeing method of polyester/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish sayings in time, energy and water usage. Also, when dyeing polyester/cotton blends by the one bath dyeing method, the high salt concentrations needed for the reactive dye can cause particles of disperse dye, used for the polyester component, to aggregate. A supplementary problem that can occasionally be happened is the change of hue that occurs on dyed polyester in an alkaline dyebath. To improve dyeing property of polyester/cotton blends, cotton component was pretreated with epichlolohydrine-trimethylamine hydrochloride in aqueous solution of sodium hydroxide to produce a cationized cotton that can be dyed under neutral conditions with reactive dye in a non-electrolytic or il little electrolytic dyebath. The one bath dyeing method of polyester/cationized cotton blends with disperse dye/reactive dye mixture resulted in a satisfactory dyeing property and color yield in comparison with ordinary two bath dyeing method.

  • PDF

국내 쇄석 골재의 알카리-실리카 반응성 암석 판정에 관한 실험적 연구(2) (An Experimental Study on the Identification of Alkali-Silica Reactivity of Crushed Stone(2))

  • 정재동;노재호;조일호;이선우
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 1992년도 가을 학술발표회 논문집
    • /
    • pp.50-53
    • /
    • 1992
  • The damages due to alkali-aggregate reaction between the reactive silicia constituents of the aggregate and the alkalies in cement have been frequently reported since 1923 in America . Recently alkali-aggregate reaction, especially alkali-silica reaction, can be found all over the area using crushed stones. The first research, in 1990, was performed to identify the alkali-silica reactivity of 18 sets of crushed stones used in domestic ready-mixed concrete plant as coarse aggregates by 4 petrollgical, chemical and mortar bar method, And the study was continued with 10 sets of crushed stones in this research. It was found that all the aggregates used in this study are innocuous at alkali-silica reaction.

  • PDF

동제련 슬래그를 골재로 사용한 반응성 분말 콘크리트(RPC)의 강도 특성에 관한 실험적 연구 (An Experimental Study on the Strength Properties of Reactive Powder Concrete Using copper slag aggregate)

  • 박민수;이승훈;김영수
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2014년도 춘계 학술논문 발표대회
    • /
    • pp.278-279
    • /
    • 2014
  • This study was performed an evaluation of mechanical properties of reactive powder concrete using copper slag. So, various RPC containing copper slag were made by replacement ratio of copper slag and different the curing condition and their mechanical properties were investigated. From the experimental results, slump flow using copper slag tends to increase with replacement ratio. And also, 30% of copper slag with quartz sand was found to have a compressive strength superior to that of plain.

  • PDF

콘크리트 장기 안정성을 위한 골재의 선택 (Selection of Suitable Aggregates for Long-term Stability of Concrete)

  • 양동윤;이동영
    • 자원환경지질
    • /
    • 제28권5호
    • /
    • pp.519-525
    • /
    • 1995
  • Recently, there have been several cases of serious accidents on concrete structure resulting from rapid deterioration of concrete strength. On the view point of long term stability of concrete, deterioration of concrete strength is mostly due to chemical reaction between alkali and reactive aggregates (alkali-aggreagte reaction; AAR) in concrete rather than a problem of execution. For long-term stability of concrete, concrete aggregates must be carefully selected. Some of rocks used for concrete aggregates contain deleterious minerals reactive to alkali components in concrete. Most of AAR result from chemical reaction between alkali components and reactive silica minerals in aggregates (so called alkali-silica reaction; ASR). The silica minerals are as follows; quartz with seriously distorted lattice structure, volcanic glass, chalcedony, opal, cristobalite, tridymite, etc. ASR may cause expansion and cracks, further collapse in concrete structure, in a few years. In case of crushed aggregates, only a part of rock mass without reactive minerals must be produced in aggregates mine after thorough examination of the distribution of rocks with reactive minerals. In case of natural aggregates, the total content of reactive minerals must be calculated, if, the content is more than 20%, the rate should be lower by mixing other non-reactive crushed- or natural aggregates. If it is obliged to use concrete aggregates all containing deleterious minerals in a discrete area, they must be used with low alkali cement Even if it is low quality in the chemical properties, aggregates with suitable range in the physical properties can be utilized as the aggregate of other purposes.

  • PDF

Effect of perlite powder on properties of structural lightweight concrete with perlite aggregate

  • Yan, Gongxing;Al-Mulali, Mohammed Zuhear;Madadi, Amirhossein;Albaijan, Ibrahim;Ali, H. Elhosiny;Algarni, H.;Le, Binh Nguyen;Assilzadeh, Hamid
    • Structural Engineering and Mechanics
    • /
    • 제84권3호
    • /
    • pp.393-411
    • /
    • 2022
  • A high-performance reactive powder concrete (RPC) has been readied alongside river sand, with 1.25 mm particle size when under the condition of 80C steam curing. As a heat and sound insulation, expanded perlite aggregate (EPA) provides economic advantages in building. Concrete containing EPA is examined in terms of cement types (CEM II 32.5R and CEM I 42.5R), doses (0, 2%, 4% and 6%) as well as replacement rates in this research study. The compressive and density of concrete were used in the testing. At the end of the 28-day period, destructive and nondestructive tests were performed on cube specimens of 150 mm150 mm150 mm. The concrete density is not decreased with the addition of more perlite (from 45 to 60 percent), since the enlarged perlite has a very low barrier to crushing. To get a homogenous and fluid concrete mix, longer mixing times for all the mix components are necessary due to the higher amount of perlite. As a result, it is not suggested to use greater volumes of this aggregate in RPC. In the presence of de-icing salt, the lightweight RPC exhibits excellent freeze-thaw resistance (mass is less than 0.2 kg/m2). The addition of perlite strengthens the aggregate-matrix contact, but there is no apparent ITZ. An increased compressive strength was seen in concretes containing expanded perlite powder and steel fibers with good performance.

쇄석 골재의 알칼리-실리카 반응에 관한 실험적 연구 (An Experimental Study on the Alkali-Silica Reaction of Crushed Stones)

  • 윤재환;정재동;이영수
    • 콘크리트학회지
    • /
    • 제6권2호
    • /
    • pp.108-117
    • /
    • 1994
  • 국내에서는 아직 알칼리-골재 반응으로 인한 피해가 보고되지는 않았지만, 해사와 쇄석의 사용이 증가하고 있어 이에 대한 연구가 시급히 진행되어야 할 것으로 사료되어, 화학법(KS F 2545, ASTMC 289)과 모르터바법(KS F 2546, ASTM C 227)을 중심으로 실험을 행하여 국내산 쇄석1종과 국외산 쇄석 1종이 유해로 판정되었으며, 첨가알칼리성량 및 종류를 달리하여 실시한 모르터바법 시험결과 첨가 알카리로 NaCl사용시 가장 높은 팽창을 하였다. 또한, 모르터바의 표면 및 내부의 반응생성물을 SEM에 의한 관찰과 EDXA에 의한 성분분석을 실시하여 알칼리와 실리카성분으로 이루어진 알칼리 실리케이트 겔임이 판명되어 국내에서 알칼리 반응성을 나타내는 골재의 존재가 처음으로 확인되었다.

국내 쇄석 골재의 알카리-실리카 반응성 판정에 관한 실험적 연구 (1) (An Experimental Study on the Identification of Alkali-Silica Reactivity of Crushed Stones (1))

  • 이양수;노재호;정재동
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 1991년도 봄 학술발표회 논문집
    • /
    • pp.93-98
    • /
    • 1991
  • The damages due to alkali-aggragate reaction between the reactive silica constituents of the aggregate and the alkalies in cement have been frequently reported since 1923 in America. Recently, alkali-aggregate reaction, especially alkali-silica reaction, can be found all over the area using crushed stones. This research was performed to indentify the alkali-silica reactivity of 18 sets of crushed stones being used currently in domestic reacy-mixed concrete plant as coarse aggregates by petrollogical, chemical and mortar bar method. It is found that all the aggregates used in this study are innocuous at alkali-silica reaction. Further study will be carried out with some aggregates in more severe conditions.

  • PDF

알칼리 활성 고로슬래그 미분말 모르터의 알칼리-실리카 반응에 관한 실험적 연구 (An Experimental Study on Alkali-Silica Reaction of Alkali-Activated Ground Granulated Blast Furnace Slag Mortars)

  • 김영수;문동일;이동운
    • 한국건축시공학회지
    • /
    • 제11권4호
    • /
    • pp.345-352
    • /
    • 2011
  • 연구의 목적은 반응성 골재를 함유한 알칼리 활성화 고로슬래그 미분말의 알칼리-골재반응으로 인한 팽창을 조사하기 위한 것이다. 또한 이 연구는 현재 존재하고 있는 반응성 골재와 알칼리 재료들의 거동과 관련하여 특별히 관여 되어 지고 있다. 실험 방법은 EDS, SEM을 통하여 알칼리-실리카 반응 생성물의 구성이나 미세구조를 관찰하였으며 알칼리-실리카 반응에 의한 모르터 바의 팽창정도를 측정하였다. 실험 결과에 따르면 알칼리-활성화된 모르터는 알칼리 실리카 반응 때문에 팽창이 되었지만 14일 재령에서 0.1%의 팽창률을 나타내어 알칼리-실리카반응에 대하여 안전한 것으로 나타났다. 그리고 촉진 실험 후 SEM과 BEM분석한 결과 골재 주변과 시멘트 페이스트에 알칼리-실리카 겔 및 띠 모양의 생성물이 나타난 것을 볼 수 있었다. EDX에 따르면 반응생성물이 알칼리 활성화 고로슬래그를 사용하였을 경우 현격히 감소한 것을 볼 수 있다. 추가적으로 광물학적 혼화재료의 대체 재료로써 콘크리트 내구성의 특성을 보증하기 위하여 알칼리 활성화 고로슬래그의 품질을 향상시키는 연구가 필요하다.

지오폴리머 모르타르의 알칼리-실리카반응에 관한 연구 (A Study on the Alkali-Silica Reaction of Geopolymer Mortar)

  • 김성훈;김영수
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2015년도 추계 학술논문 발표대회
    • /
    • pp.7-8
    • /
    • 2015
  • The purpose of this study is to investigate the expansion of alkali-activated geopolymer mortar containing reactive aggregate due to alkali-silica reaction. In addition, this study is particularly concerned with the behavior of these alkaline materials in the presence of reactive aggregates. The test method included expansion measurement of the mortar bar specimens and geopolymer compressive strength test. Major results that alkali-activated geopolymer mortars showed expansion due to the alkali-silica reaction. geopolymer mortars is safety for the expansion exhibited less than 0.2% at 14 day.

  • PDF

메타카올린 치환에 따른 알칼리-실리카 반응 팽창 저감효과 (The Effect of Meta-Kaolin Replacement on Alkali-Silica Reaction)

  • 전쌍순;이효민;진치섭;황진연
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
    • /
    • pp.360-363
    • /
    • 2004
  • The effectiveness of Meta-Kaolin to prevent detrimental expansion due to alkali-silica reaction was investigated through the ASTM C 1260 method. Reactive aggregate used is a metamorphic rock. The replacement proportions of portland cement by Meta-Kaolin were 0, 5, 10, 15, 25 and 35 percent, respectively. The results indicate that 25 percent replacement of portland cement by Meta-Kaolin seems to be most effective to reduce alkali-silica reaction expansion under this experimental conditions.

  • PDF