• Mass Spectrometry Letters
• /
• 제8권1호
• /
• pp.1-7
• /
• 2017

Studies performed on heterogeneous reactions of hydroxyl radicals (OH) in aerosol materials of tropospheric interest are presented, focusing on the chemical ionization mass spectrometric approach. Kinetic investigations of these reactions reduced deviation in the estimation of OH concentration in the troposphere by atmospheric modeling from field measurements. Recently, OH uptake was investigated under wet conditions to acquire kinetic information under more realistic conditions representative of the troposphere. The information on the mechanism and kinetics of OH uptake by tropospheric aerosol materials will contribute to the updating of atmospheric models, allowing a better understanding of the troposphere.

• 품질경영학회지
• /
• 제21권2호
• /
• pp.242-253
• /
• 1993

The interpretation of the reaction mechanism is significant to produce the high quality welds and understand the welding processes. This investigation is important for the design of welding consumables and the selection of welding process parameters to develop the high quality welds. The objective of this study is to investigate the effect of electrochemical reactions on the transfer of alloy elements between slag and weld metal during submerged arc welding During submerged arc welding weld metal composition is shown to be controlled by two reaction mechanisms in four reaction zones. The responsible reaction mechanisms are thermochemical and electrochemical reactions. The possible reaction sites are the melted electrode tip, the detached droplet, the hot weld pool immediately below the moving electrode, and the cooling and solidifying weld pool behind the moving electrode. The possible reactions in submerged arc welding at different zones of the process is schematically shown in Figure 1.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
• /
• pp.19-22
• /
• 2004

Two-dimensional modeling studies using TOUGHREACT were conducted to investigate the coupling between flow and transport developed as a consequence of differences in density, dissolution/ precipitation, and medium heterogeneity. The model includes equilibrium reactions for aqueous species, kinetic reactions between tile solid phases and aqueous constituents, and full coupling of porosity and permeability changes resulting from precipitation and dissolution reactions in porous media. Generally, the evolutions in the concentrations of the aqueous phase are intimately related to the reaction-front dynamics. Plugging of the medium contributed to significant transients in patterns of flow and mass transport.

• Journal of Microbiology
• /
• 제40권1호
• /
• pp.51-54
• /
• 2002

Heavy metal adsorptions of four streptomycetes were compared with each other, Among the test strains, Streptomyces viridochromogenes showed the most efficient metal binding activity, which was carried out by cell wall as well as freeze-dried mycelium. An order of adsorption potential (zinc > copper > lead > cadmium) was observed in single metal reactions, whereas this adsorption order was disturbed in mixed-metal reactions. The metal adsorption reactions were very fast, pH dependent and culture age-independen, suggestive of a physico-chemical reaction between cell wall components and heavy metal ions. The metal tolerant stains presented the weakest adsorbing activity, indicating that the metal biosorption was not the basis of the metal tolerance.

• 한국근적외분광분석학회:학술대회논문집
• /
• 한국근적외분광분석학회 2001년도 NIR-2001
• /
• pp.1282-1282
• /
• 2001

Near Infrared (NIR) spectra has long been used in industry to monitor rates of reactions via calculation of analyte concentrations. However, the kinetic information is inherent in the data through spectral ratios. Two-dimensional correlation spectroscopy (2D-COS) is a spectral method that is based on changes (e.g. concentration) in time and is therefore uniquely suited for reaction monitoring. This method is especially useful in the understanding of how the reaction(s) proceeds. We will show the application of 2D-COS to synthetic kinetic data from different reaction orders to illustrate the method. We will then show application to real reactions of various orders. Finally, we will illustrate how 2D-COS will be of specific interest to developing optimized industrial reactions.

• 한국조명전기설비학회:학술대회논문집
• /
• 한국조명전기설비학회 2004년도 학술대회 논문집
• /
• pp.131-135
• /
• 2004

The molecules of the substance absorbing a light obtains the radiant energy to the wavelength of the light to make thermal reactions or photochemical reactions. Specially, thermal reactions by infrared radiation brings about physical damage by temperature rise process or temperature drop process of the material. In this study, a measuring system was set up to measure the temperature rise and temperature drop of each sample by infrared radiation from light source. And a physical demage of samples by infrared radiation were measured using the measuring system.

• Toxicological Research
• /
• 제17권
• /
• pp.211-216
• /
• 2001

Drugs can have various adverse effects on the immune system including unintended immun-osuppression, induction of both drug-specific immune responses (including drug allergies) and non-specific immunostimulation (including autoimmune reactions), and direct activation of effector mechanisms (such as histamine release). As a practical matter, the Center for Drug Evaluation (CDER) relies on standard non-clinical toxicology studies to detect unintended immunosuppression. Specific assays using guinea pigs and mice are available to identify drugs that can induce immune-mediated dermal hypersensitivity reactions. Respiratory and systemic hypersensitivity and autoimmune reactions are more difficult to model in non-clinical studies. Unintended nonspecific immunstimulation can be detected in animal studies. CDER is currently developing specific guidance for evaluating potential drug immunotoxicity.

• 한국응용과학기술학회지
• /
• 제17권2호
• /
• pp.89-93
• /
• 2000

The oxidation of methane was carried out in six different configurations of plasma reactors in order to study the radical reactions inside and outside of the plasma zone and to explore the method to control them. Various radicals and reactive molecules, such as CH, $CH_{2}$, $CH_{3}$, H, and O(from $O_{2}$) were generated in the plasma. A variety of products were produced through many competing reaction pathways. Among them. partial oxidation products were usually not favored, because the intermediates leading to the partial oxidation products could be oxidized further to carbon dioxides easily. It is important to control the free radical reactions in the plasma reactor by controlling the experimental conditions so that the reactions leading to the desired products are the major pathways.

• 한국우주과학회:학술대회논문집(한국우주과학회보)
• /
• 한국우주과학회 2008년도 한국우주과학회보 제17권2호
• /
• pp.22.3-22.3
• /
• 2008

We present the results of the investigations of high dispersion spectra of two stars. These are the eclipsing binary RR Lyn, and $\rho$ Pup - the prototype of the group of pulsating variables. The spectra were obtained at 1.8 m Bohyuunsan observatory telescope, and 8.2 m VLT. We found the chemical composition. The both components of RR Lyn are Am stars (metallic line stars), but the abundance patterns of the components are not similar - the iron abundance and the abundances of other elements are surely different. For few elements the differences exceeds 1 dex. We found the abundances of 56 chemical elements in the atmosphere of $\rho$ Pup. This is one of the best stellar abundance patterns. It permits to investigate the role of the charge-exchange reactions in stellar atmospheres. These reactions can produce the abundance anomalies in the atmospheres of B-F type stars. These reactions can be one of the sources of galactic cosmic rays, and the reason of the braked rotation of A-F type chemically peculiar stars.

• 융복합기술연구소 논문집
• /
• 제2권2호
• /
• pp.30-34
• /
• 2012

The SI thermochemical cycle process accomplishes water splitting through distinctive three chemical reactions. We focused on thermodynamic models applicable to the process. Recently, remarkable models based on the assumed ionic species have been developed to describe highly nonideal behavior on the liquid phase reactions. ElecNRTL models with ionic reactions were proposed in order to provide reliable process simulation results for phase equilibrium calculations in Section II and III. In this study, the current thermodynamic models of SI thermochemical cycle process were briefly described and the calculation results of the applied ElecNRTL models for phase equilibrium calculations were illustrated for binary systems.