• Title/Summary/Keyword: reaction zone thickness

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Reaction Zone Thickness of Turbulent Premixed Flame

  • Yamamoto, Kazuhiro;Nishizawa, Yasuki;Onuma, Yoshiaki
    • Journal of the Korean Society of Combustion
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    • v.6 no.2
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    • pp.36-42
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    • 2001
  • Usually, we use the flame thickness and turbulence scale to classify the flame structure on a phase diagram of turbulent combustion. The flame structure in turbulence is still in debate, and many studies have been done. Since the flame motion is rapid and its reaction zone thickness is very thin, it is difficult to estimate the flame thickness. Here, we propose a new approach to determine the reaction zone thickness based on ion current signals obtained by an electrostatic probe, which has enough time and space resolution to detect flame fluctuation. Since the signal depends on the flow condition and flame curvature, it may be difficult to analyze directly these signals and examine the flame characteristics. However, ion concentration is high only in the region where hydrocarbon-oxygen reactions occur, and we can specify the reaction zone. Based on the reaction zone existing, we estimate the reaction zone thickness. We obtain the thickness of flames both in the cyclone-jet combustor and on a Bunsen burner, compared with theoretically predicted value, the Zeldovich thickness. Results show that the experimentally obtained thickness is almost the same as the Zeldovich thickness. It is concluded that this approach can be used to obtain the local flame structure for modeling turbulent combustion.

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Influence of Changing Combustor Pressure on Combustion Characteristics and Reaction Zone in the Partially Premixed Flame with $CH_4$, $C_2H_4$ and $C_3H_8$ (부분 예혼합 화염에서 연소실 압력이 연료별($CH_4$, $C_2H_4$, $C_3H_8$) 연소특성과 반응영역에 미치는 영향)

  • Son, Je-Ha;Kim, Jong-Ryul;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of the Korean Society of Combustion
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    • v.16 no.3
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    • pp.33-40
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    • 2011
  • Combustion experiments were conducted at three different fuels ($CH_4$, $C_2H_4$ and $C_3H_8$) to investigate the effects of combustor pressure (30 ~ -30 kPa) on combustion charateristics and reaction zone structure. Regardless of the fuels, emission index of CO (EICO) increased with decreasing combustor pressure, and EICO of $C_2H_4$ was mostly affected by changing combustor pressure at subatmospheric pressure. In order to observe reaction zone, $OH^*$, $CH^*$ and ${C_2}^*$ chemiluminescence intensity were measured. The sequence of the chemiluminescence intensity peak position was affected by chemical characteristics of fuels rather than changing combustor pressure. The emission zone thickness of $C_2H_4$ and $C_3H_8$, defined by the full width at half maximum (FWHM) of $CH^*$ intensity profile, were increased with decreasing combustor pressure. however, the thickness of $C_2H_4$ exhibited the opposite tendency due to the characteristics of the fuel as the bond structure.

An experimental study on microstructure of doubled jet burner flame (이중분류버너화염의 미세구조에 관한 실험적 연구)

  • Jang, In-Gap;Choe, Gyeong-Min;Choe, Byeong-Ryun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.7
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    • pp.2337-2346
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    • 1996
  • One of the most useful method for increasing combustion loading of premixed flame is to strengthen the turbulent intensity of unburned mixture. It produces an important information to a design of efficient combustion equipment that analysing microstructure of strong turbulence premixed flame. The flame structure and characteristics are depend on the turbulence of unburned mixture. Therefore, to strengthen the turbulent intensity of unburned mixture make flame scale small and accomplish efficient combustion. We measured the velocity of local flame front movements, local eddy radius and local reaction zone thickness quantitatively with increasing turbulent intensity of unburned mixture. We researched the microstructure of flame using ion currents that react sensitively in the reaction zone. Consequently, the velocity of local flame front movements is depend on the velocity of unburned mixture and local eddy scale is to be small with increasing turbulent intensity. But there is no change in local reaction zone thickness with turbulence.

Studies on the Kinetics for the Formation Reaction $Ti_3AI$ by SHS (Self-propagating High-temperatuer Synthesis) Method (자체반응열 고온합성법에 의한 $Ti_3AI$ 생상반응의 동력학적 연구)

  • 전광식
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.569-574
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    • 1998
  • The thickness of flame zone reaction rate and apparent activation energy in the formation reaction of $Ti_3AI$ intermetallic compound were investigated using SHS method which sustains the reaction spontaneously and utilizes the heat generated by thye exothermic reaction itself. In this reaction the thickness of flame zone was 1.4 mm and the reaction rate was $0.4g/\textrm{cm}^2{\cdot}sec$. Also the apparent activation energy calculated using from the experimental data obtained by controlling the realtive green density was 40kJ/mol.

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The Effect of Casting Conditions on the Fluidity during Lost Foam Casting of Al Alloy (알루미늄 합금의 소실모형주조 시 유동도에 미치는 주조 조건의 영향)

  • Shin, Seung-Ryoul;Han, Sang-Won;Lee, Kyong-Whoan;Lee, Zin-Hyoung
    • Journal of Korea Foundry Society
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    • v.24 no.1
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    • pp.34-39
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    • 2004
  • The effects of casting condition and hot melt glue during Lost Foam Casting were investigated on the fluidity of Al alloy melt. The fluidity increased linearly with increasing pouring temperature in thick castings but non-linearly in thin casting due to the difference in main heat flow direction. The metal flow velocity was in range of $0.5{\sim}2.7$ cm/s in no evacuation condition and the minimum value of it was measured after the melt flow through the hot melt barrier. The mold evacuation improved the metal flow velocity by around $0.5{\sim}1$ cm/s. And the reaction zone layer thickness was about 1 cm in no-evacuation conditions but about 0.6 cm in mold evacuation condition of 710 torr due to the easier removal of pyrolsis product of EPS. And hot melt barrier thickness of 0.6 mm increased the reaction zone layer thickness up to about 2.5 cm. The fluidity decreased remarkably with an enlarged thickness of hot melt due to a lot of pyrolysis products.

A Study on the Effects of Reynolds Number and Damkohler Number in the Structure of Premixed Turbulent Flames (예혼합 난류화염구조에 미치는 레이놀즈 수와 담퀠러 수의 영향에 관한 연구)

  • 김준효;안수길
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.4
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    • pp.34-41
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    • 1995
  • The structure of premixed tubulent flames in a constant-volume vessel was investigated using a schlieren method and microprobe method. The schlieren method was used to observe the flame structure qualitatively. The microprobe method, which detects a flamelet by detecting its flame potential signal, was used to investigate the deeper flame structure behind the flame front. The flame potential signal having one to six peaks was obtained in the case of turbulent flames, each of them being regarede as a flamelet existing in the flame zone. Based on this consideration, the flame propagation speed, the thickness of the flame zone, the number of flamelets and the separation distance between adjacent flamelets in the flame zone were measured. Moreover, the thickness of flamelet which could not be attempted in the conventional electrostatic probe method was also investigated. The experimental results of this work suggest the existence of "reactant islands" in the reaction zone, and show that the averaged number of flamelets increases with an increase in the turbulence intensity and/or a decrease in the Damkohler number. The mean thickness of flamelet in the case of turbulent flames was found to be about two times compared to laminar values.ar values.

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Computational Study of Intermetallic Reaction Propagation in Nanoscale Boron/Titanium Metallic Multilayers (보론/티타늄 나노박막다층 내 이종금속간 화학반응 전파특성 해석연구)

  • Kim, Kyoungjin;Park, Joong-Youn
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.3
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    • pp.10-17
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    • 2017
  • The analytical modeling has been established on the self-propagation of intermetallic reaction in the spanwise direction of highly reactive boron and titanium nanoscale multilayers. Assuming that the reaction obeys Arrhenius kinetics, two-dimensional computations are carried out for heat and atomic species diffusion with exothermic reaction model in order to simulate the self-propagation of intermetallic reaction. The effects of bimetallic layer thickness and thickness ratio on the reaction propagation speed are tested and discussed in addition to the assessment of pre-mixing zone effects.

Consideration of reversed Boudouard reaction in solid oxide direct carbon fuel cell (SO-DCFC)

  • Vahc, Zuh Youn;Yi, Sung Chul
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.514-518
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    • 2018
  • The direct carbon fuel cell (DCFC) has attracted researcher's attention recently, due to its high conversion efficiency and its abundant fuel, carbon. A DCFC mathematical model has developed in two-dimensional, lab-scale, and considers Boudouard reaction and carbon monoxide (CO) oxidation. The model simulates the CO production by Boudouard reaction and additional electron production by CO oxidation. The Boudouard equilibrium strongly depends on operating temperature and affects the amount of produced CO and consequentially affects the overall fuel cell performance. Two different operating temperatures (973 K, 1023 K) has been calculated to discover the CO production by Boudouard reaction and overall fuel cell performance. Moreover, anode thickness of the cell has been considered to find out the influence of the Boudouard reaction zone in fuel cell performance. It was found that in high temperature operating DCFC modeling, the Boudouard reaction cannot be neglected and has a vital role in the overall fuel cell performance.

Microstructure and Tensile Strength Property of Arc Brazed DP steel using Cu-Sn Insert Metal (Cu-Sn 삽입금속을 이용한 DP강의 아크 브레이징 접합부의 미세조직과 인장특성)

  • Cho, Wook-Je;Cho, Young-Ho;Yun, Jung-Gil;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.31 no.1
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    • pp.58-64
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    • 2013
  • The following results were obtained, microstructures and tensile properties in arc brazed joints of DP(dual phase) steel using Cu-5.3wt%Sn insert metal was investigated as function of brazing current. 1) The Fusion Zone was composed of ${\alpha}Fe+{\gamma}Cu$ and Cu23Sn2. The reason for the formation of these solid solutions. Despite, Fe & Cu were impossible to solid solution at room temperature. It's melting & reaction to something of insert metal & Base Metal (DP Steel) by Arc. Brazing Process has faster cooling rate then Cast Process, Supersaturated solid solution at room temperature. 2) The increase Hardness of Fusion Zone was directly proportional to the rise of welding current. Because, ${\alpha}Fe+{\gamma}Cu$ phase (higher hardness than the Cu23Sn2.(104.1Hv < 271.9Hv)) Volume fraction was Growth, due to increasing the amount of base metal melting by High current. 3) The results of tensile shear test by Brazing, All specimens happen to fracture in Fusion Zone. On the other hand, when Brazing Current increasing tend to rise tensile load. but it was very small, about 26-30% of the base metal. 4) The result of fracture analysis, The crack initiate at Triple Point for meet to Upper B.M/Under B.M/Fusion Zone. This Crack propagated to Fusion zone. So ruptured by tensile strength. The Reason to in the fusion zone fracture, Fusion zone by Brazing of hardness (strength) was very lower then the base metal (DP steel). In addition the Fusion Zone's thickness in triple point was thin than the base metal's thickness in triple point.

Soild-state reaction in Ti/Ni multilayers

  • ;;;;Y.V.Kudryavtsev;B.Szymanski
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.140-140
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    • 1999
  • Ti/Ni multilayered films (MLF) are ideal for neutron optics particularly in neutron guides and focusing devices. This system also possesses the tendency of amorphization through a solid-state reaction (SSR). This behaviors are closely related to the electronic structures and both magneto-optical (MO) and optical properties of metals depend strongly on their electron energy structures. Mutual inter-diffusion of the Tin and Ni atoms in the MLF caused by a low temperature annealing should decrease the thickness of pure Ni, as well as change the chemical and atomic order in the reactive zone. The application of the MO spectroscopy to the study of SSR in the MLF allows us to obtain an additional information on the changes in the atomic and chemical orders in the interface region. The optical one has no restriction on the magnetic state of the constituent sublayers. Therefore, the changes in magnetic, MO and optical properties of the Ti/Ni MLF due to SSR can be expected. To the best of our knowledge, the MO and optical spectroscopies were not used for this purpose. SSR has been studied in the series of the Ti/Ni MLFs with bilayer periods of 0.65-22.2nm and constant ratio of the Ti to Ni sublayers thickness by using MO and optical spectroscopies as well as an x-ray diffraction. The experimental MO and optical spectra are compared with the computer-simulated spectra, assuming various interface models. The relative changes in the x-ray diffraction spectra and MO properties of the Ti/Ni MLF caused by annealing are bigger for the multilayers with "thick" sublayers, or the SSR with the formation of amorphous alloy takes place mainly in the Ti/Ni multilayers with "thick" sublayers, while in the nominal threshold thickness of the Ni-sublayer for the observation of the equatorial Kerr effect in the as-deposited and annealed Ti/Ni MLFs of about 3.0 and 4.5nm thick is explained by the formation of amorphous alloy during the deposition or the formation of the nonmagnetic alloyed regions between pure components as a result of the SSR. For the case of Ti/Ni MLF the MO approach is more sensitive for the determination of the thickness of the reacted zone, while x-ray diffraction is more useful for structural analyses.structural analyses.

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