• Title/Summary/Keyword: reaction time

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A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas (고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구)

  • Lee, Han Min;Yun, Jae Geun;Hong, Jung Goo
    • Journal of ILASS-Korea
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    • v.25 no.3
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    • pp.132-138
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    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.

Immunobiological Studies in Mice Treated with Chemical Carcinogen, 3-Methylcholanthrene: I. Footpad Swelling Reaction and Antibody Titer in Serum (발암제(發癌劑) 3-Methylcholanthrene 투여(投與) 마우스에 대(對)한 면역생물학적(免疫生物學的) 연구(硏究): I. 족척종창반응(足蹠腫脹反應) 및 혈중항체가(血中抗體價))

  • Song, Hee-jong;Kim, Jong-myeon
    • Korean Journal of Veterinary Research
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    • v.26 no.1
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    • pp.109-115
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    • 1986
  • Experiments were performed on mice to investigate the effects of a polycyclic aromatic hydrocarbon, 3-methylcholanthrene (MCA) on Arthus reaction, delayed-type hypersensitivity (DTH) and antibody production to sheep red blood cells (SRBC). Mice were sensitized iv with 0.1ml of 1% SRBC suspension were treated with a single ip injection of olive oil alone or with different doses of MCA in oil (0.5~50mg/Kg) at various time before (-) or after (+) sensitization (day 0) and were challenged at 4 days after SRBC. Arthus reaction was measured at 3 hours after challenge and other responses at 24 hours. Treatment with MCA inhibited Arthus reaction and DTH to SRBC, measured by footpad swelling reaction, and this immunosuppressing effect was dependent on the dose and time of MCA treatment in relation to SRBC sensitization. Humoral immune responses as measured by serum hemagglutinin-and hemolysin-titers to SRBC were significantly depressed when MCA was injected before or at the same time of sensitization. However, the response was slightly depressed when injected after SRBC. These results indicate that MCA suppress the function of the cells involved in immune responses.

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Wetting Characteristics and Interfacial Reaction at $Al/Al_2O_3$ Interface ($Al/Al_2O_3$ 계면의 젖음특성 및 계면반응)

  • 권순용;정대영;최시경;구형회;이종수
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.815-822
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    • 1994
  • Sessile drop studies of molten Al on single crystal sapphire substrate were conducted to understand the wetting behavior and interfacial reaction at Al/Al2O3 interface. To investigate the wetting mechanism, the variation in contact angle was determined with time. The contact angle obtained in this study decreased exponentially with time. This result means that the driving force for wetting is the reduction in interfacial energy between liquid Al and sapphire caused by the interfacial reaction. The closer examination revealed that the reaction was the dissolution of sapphire by molten Al. Ti has been frequently used to improve wetting on ceramic materials. Therefore, the influence of Ti content on the wetting behaviour was investigated in this work. The equilibrium wetting angles of pure Al, Al-0.3 wt%Ti, and Al-1.0 wt%Ti at 100$0^{\circ}C$ were 63$^{\circ}$, 59$^{\circ}$, and 54$^{\circ}$respectively. The difference is considered as the result of the change in interfacial energy caused by the reaction between Ti and sapphire and the interfacial reaction formed the reaction products of varying stoichiometry (TiO, Ti2O3, TiO2 etc.).

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Development of Biodiesel Production Equipment from Animal Fats and Consideration for Reaction Condition of Animal Biodiesel (동물성 유지를 원료로 한 바이오 디젤 제조 장치 개발 및 바이오 디젤의 반응조건 고찰)

  • Kim, Yong Hun;Cho, Young Hak
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.1
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    • pp.119-124
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    • 2013
  • In this paper, we analysed fatty acid methyl ester contents in the biodiesel which is produced from the newly developed biodiesel production equipment. The lard oil was used as the raw material through various experimental conditions. Thirty one experiments were conducted, which were based on the experimental conditions that designed by central composite design method. The effects of four independent variables, including reaction temperature, reaction time, oil to methanol molar ratio, and catalytic amount, were investigated at five levels using central composite design (CCD). Fatty acid methyl ester content was chosen dependent variable. Although the results of analysis of the surface with an irregular surface geometry showed that the biodiesel was partially impure after the reaction due to the natural characteristics of the lard oil as the raw material, we could confirm the relationship between them from the facts that the production amount of fatty acid methyl ester changes according to reaction temperature, reaction time, oil to methanol molar ratio, and catalytic amount.

Reaction Kinetics and Morphological Changes at Polymer-polymer Interface measured by Rheological Properties (유변학적 성질 측정으로 측정한 고분자 계면에서의 반응 kinetics와 morphology 변화)

  • Kim, Hwang-Yong;Unyong Jeong;Kim, Jin-Kon
    • Proceedings of the Korean Society of Rheology Conference
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    • 2002.05a
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    • pp.25-27
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    • 2002
  • In this study we investigated the reaction kinetics by a convenient but useful method-rheology to characterize the interface between two immiscible blends with a Reactive compatibilizer. Also, we made an attempt to correlate changes of interface roughness with rheological properties. The blend systems employed in this study was mono-carboxylated polystyrene (PS-mCOOH) and an poly(methyl methacrylate-ran-glycidylmethacrylate) (PMMA-GMA). PS-mCOOH was synthesized by an anionic polymerization and PMMA-GMA by a free radical polymerization. We prepared two plates of each polymer using compression molding with a smooth surface molder, then put one upon another. As soon as these two plates welds together inside a rheometer under nitrogen environment, the torque and moduli were obtained with reaction time at different temperatures. Through the analysis of this modulus change with reaction time, we estimated interfacial reaction and roughening. The increment of modulus in initial state can be correlated to the extent of reaction. We obtained the reaction kinetic constant by fitting appropriate kinetic equation into experimental data. We also showed that increment of modulus in later state was due to by roughened interface.

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Comparison of quantitative detection of periodontal pathogens before and after scaling by real-time polymerase chain reaction

  • Kim, Young-Sun;Lee, Jung-Hwa;Lee, Young-Eun
    • Journal of Korean society of Dental Hygiene
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    • v.15 no.6
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    • pp.1063-1071
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    • 2015
  • Objectives: The purpose of the study is to investigate the quantitative detection of periodontal pathogens before and after scaling by real-time polymerase chain reaction. Methods: Participants were voluntarily recruited at D university, and saliva samples were extracted before and after scaling. Multiple real-time polymerase chain reactions were used to analyze characteristics and the amount of nine kinds of periodontal pathogens; Aggregatibacter actinomycetemcomitans, Porphyromonas gingivalis, Tannerella forsythia, Treponema denticola, Prevotella intermedia, Fusobacterium nucleatum, Parvimonas micra, Campylobacter rectus, and Eikenella corrodens. Results: After scaling, most periodontal pathogens except Eikenella corrodens were significantly decreased in all subjects(p<0.05). In addition, the percentage of microorganisms associated with disease, the microorganism risk index of periodontitis and the prevalence of red complex, orange complex, and Aggregatibacter actinomycetemcomitans was also significantly reduced after scaling(p<0.05). Conclusions: Scaling decreased in the amount of major periodontal pathogens and periodontitis prevalence rate.

Reaction Dynamics of Continuous Time Random Walker in Heterogeneous Environment

  • Seong, Jae-Yeong
    • Journal of the Korean Chemical Society
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    • v.50 no.4
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    • pp.277-280
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    • 2006
  • We report an exact relation between the survival probability, the revisit time distribution, and the reaction-free propagator of the continuous time random walker. The relation holds even for such a general case where the random walker has a distinct jump dynamics at each lattice site, which may be dependent also on the direction of the jump. The application range of the obtained relation is not limited to the nearest neighbor hopping in the bulk lattice either. The result is applicable to a higher dimensional system with the spherical symmetry as well as it is to the one-dimensional system.

Faster Detection of Step Initiation for the Lower Limb Exoskeleton with Vertical GRF Events

  • Cha, Dowan;Kang, Daewon;Kim, Kab Il;Kim, Kyung-Soo;Lee, Bum-Joo;Kim, Soohyun
    • Journal of Electrical Engineering and Technology
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    • v.9 no.2
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    • pp.733-738
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    • 2014
  • We propose a new approach called as a peak time approach for faster detection of step initiation for the lower limb exoskeleton. As faster detection of step initiation is an important criterion in evaluating the lower limb exoskeleton, many studies have investigated approaches to detect step initiation faster, including using electromyography, the center of pressure, the heel-off time and the toe-off time. In this study, we will utilize vertical ground reaction force events to detect step initiation, and compare our approach with prior approaches. Additionally, we will predict the first step's heel strike time with vertical ground reaction force events from multiple regression equations to support our approach. The lower limb exoskeleton should assist the operator's movement much faster and more reliably with our approach.

Effects of Clubhead Velocity on GRF Magnitude and Time during 7-iron Swing (골프스윙 시 지면반력 크기와 시간 차이가 클럽헤드 속도에 미치는 영향)

  • Woo, Byung Hoon
    • Korean Journal of Applied Biomechanics
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    • v.30 no.1
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    • pp.27-35
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    • 2020
  • Objective: The purpose of this study was to investigate the influence of clubhead velocity through regression analysis on the magnitude and time difference of the forward-backward, mediolateral, and vertical ground reaction peak forces generated by force plate during golf swing. Method: 16 subjects (age: 20.5±4.2 yrs, height: 176.0±5.4 cm, weight: 77.8±5.9 kg, handy: 2.4±1.7) who is elite golf player in high school and university, participated in this study. The study method adopted three-dimensional analysis with 8 cameras and ground reaction force measurement with two force plate. The analysis variables were clubhead velocity, and ground reaction analysis variables set four events in each graph based on the peak forces commonly generated in Fx, Fy, and Fz graphs of the ground reaction data during the golf swing. Results: As a result of analyzing the influence of ground reaction magnitude difference on clubhead velocity, the influence on clubhead velocity was ym4, zm1, xm4, zm2. The larger ym4, xm4, zm1, the fasterthe clubhead velocity, but the smallerthe zm2, the faster the clubhead velocity. And in time difference, the influence on the clubhead velocity was in the order of xt4, zt1, zt3. The shorter xt4, zt1, zt3 showed faster clubhead velocity. Conclusion: The leftfoot played a leading role in increasing the velocity of the clubhead. Although the result was caused by the interaction of the right foot and the left foot during the swing, the role of the left foot is relatively large.