• Journal of Environmental Science International
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• v.22 no.3
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• pp.331-339
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• 2013

Efforts were made to determine the activation energy and the reaction order by adopting Kissinger and Flynn-Wall-Ozawa analysis methods. All the data were acquired from TGA thermograms for the mixed fuels with different temperature heating rates. It could be known that both the coal and the mixed fuels decomposed thermally at temperature ranges of $300{\sim}700^{\circ}C$. The temperature at the maximum reaction rate, Tp, could be determined by DTG method, which could be obtained by differentiation of TGA thermogram. Kissinger analysis showed the linear relationship with experimental data, showing the activation energy of $319.64{\pm}4$ kJ/mol. From Flynn-Wall-Ozawa analysis, it was shown that the activation energies and the reaction orders did not undergo any significant changes with both the conversions and the heating rates. It was considered from this facts that the combustion mechanism of the mixed fuels could not be affected by the extent of conversion and heating rate. In the present study, the activation energies showed different values according to the different analysis methods. The difference might be originated from the inconsistency of the mathematical data treatment method. In other words, while the activation energies obtained from the Kissinger method indicated the average values for overall reaction, that from Flynn-Wall-Ozawa method showed the average values for the each conversion around Tp.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.3
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• pp.357-366
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• 2008

In this study, the analytical performance of trimethylamine (TMA) were investigated with respect to headspace-solid phase microextraction (HS-SPME) method. In order to induce the elution of aqueous TMA to headspace, NaOH was added as a decomposition reagent to aqueous TMA standard. By controlling the combination of three major variables for TMA extraction, the extent of extraction was compared between the two contrasting conditions for each variable (i.e., reaction time (long (L) vs short (S)), exposure temperature (30 vs $50^{\circ}C$), and exposure time (10 vs 30 min)). The results of this comparative analysis showed that the extraction efficiency for all eight types of HS-SPME combinations decreased on the order: L-30-30>L-50-10>L-30-10>L-50-30>S-30-30>S-50-30>S-50-10>S-30-10. The effect of reaction time appeared to exert significant influences on the relative recovery rate of HS-SPME at 90% confidence level. However, the effects of exposure temperature or exposure time were not so significant as reaction time. When the recovery rate of HS-SPME is compared against the direct injection of liquid standard into GC injector, it recorded as 2%. According to this comparative study, the reaction conditions for HS-SPME application can exert significant influences on the analysis of TMA.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.10
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• pp.1406-1418
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• 2002

The direct simulation Monte Carlo(DSMC) method is employed to calculate the etch rate on Al wafer. The etchant is assumed to be Cl$_2$. The etching process of an Al wafer in a helicon plasma etcher is examined by simulating molecular collisions of reactant and product. The flow field inside a plasma etch reactor is also simulated by the DSMC method fur a chlorine feed gas flow. The surface reaction on the Al wafer is simply modelled by one-step reaction: 3C1$_2$+2Allongrightarrow1 2AIC1$_3$. The gas flow inside the reactor is compared for six different nozzle locations. It is found that the flow field inside the reactor is affected by the nozzle locations. The Cl$_2$ number density on the wafer decreases as the nozzle location moves toward the side of the reactor. Also, the present numerical results show that the nozzle location 1, which is at the top of the reactor chamber, produces a higher etch rate.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.1
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• pp.76-83
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• 2000

This research is about wastewater containing non-biodegradable TDI(Toluene Diisocyanate) that is treated by the activated carbon adsorption method. In the case of the Fenton oxidation process being applied to the existing process, optimal pH, reaction time, chemical dosing amount, removal rate, and cost were investigated. A pilot plant test was applied after finding optimal conditions with lab experiments. The optimal conditions were pH 3~5(COD removal rate 84~88%) and reaction time 30min~1hr. In higher $H_2O_2$ dosing amount, COD removal rate was a little higher. But there was little difference in the removal rate according to $FeSO_4{\cdot}7H_2O$ dosing amount. Treatment cost was economical in the case of the Fenton oxidation process being operated earlier than activated carbon adsorption system. But chemical dosing point, chemical mixing effect, chemical dosing amount, removal rate, and the cost of facility and others must be considered in practical process.

• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.315-319
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• 2018

Fenton reaction is widely used as a out of cell method for evaluating the membrane electrochemical durability of Proton Exchange Fuel Cell (PEMFC). In this study, we investigated the factors affecting the Fenton reaction. In order to estimate the degree of the reaction, it is necessary to analyze the radicals as a product in the Fenton reaction. However, since the radicals are difficult to analyze, the degree of the reaction was measured by analyzing the concentration of hydrogen peroxide. The activation energy was calculated from the rate of hydrogen peroxide change with temperature. The activation energy was 24.9 kJ/mol at 180 min. The Fenton reaction rate was affected by the iron ion concentration. At $80^{\circ}C$, 200 rpm, and $Fe^{2+}$ 80 ppm, the concentration of hydrogen peroxide was decreased more than 20% even for 1 hour, which shows that frequent solution replacement increases the membrane degradation rate.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.6
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• pp.563-569
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• 1999

The numerical simulation method was utilized to investigate the optimal condition for synthesizing ultrafine SiC powders by using $TMS[Si(CH_3)_4]-H_2$ gaseous mixtures in the horizontal reactor. As a result of the theoretical analysis, the conversion percentage of TMS source was increased with increasing reaction temperature, however, which was decreased with increasing H$_2$flow rate. Though the SiC particles concentration synthesized was decreased with increasing the reaction temperature due to the higher collision rate in the gas phase, they were increased with increasing the H$_2$flow rate and TMS concentration. The SiC particle size showed a tendency to become larger as the reaction temperature and the initial TMS concentration were increased and smaller as the H$_2$ flow rate was increased. The variation of experimental particle size with the reaction temperature, H$_2$flow rate and TMS concentration was agreed with the theoretical results.

• Bulletin of the Korean Chemical Society
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• v.16 no.6
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• pp.543-546
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• 1995

The reaction between CH3 radicals and H2 was investigated behind incident shock waves at temperatures between 1308 and 1825 K by following the consumption of CH3 using a time resolved UV absorption method at 213.9 nm. The rate coefficient expression 1.10 X 1013 exp(-7370 K/T) cm3mol-1s-1 for the reaction of CH3 with H2 was derived.

• Nuclear Engineering and Technology
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• v.55 no.7
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• pp.2516-2533
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• 2023

Several practical methods for accelerating the depletion calculation in a GPU-based Monte Carlo (MC) code PRAGMA are presented including the multilevel spectral collapse method and the vectorized Chebyshev rational approximation method (CRAM). Since the generation of microscopic reaction rates for each nuclide needed for the construction of the depletion matrix of the Bateman equation requires either enormous memory access or tremendous physical memory, both of which are quite burdensome on GPUs, a new method called multilevel spectral collapse is proposed which combines two types of spectra to generate microscopic reaction rates: an ultrafine spectrum for an entire fuel pin and coarser spectra for each depletion region. Errors in reaction rates introduced by this method are mitigated by a hybrid usage of direct online reaction rate tallies for several important fissile nuclides. The linear system to appear in the solution process adopting the CRAM is solved by the Gauss-Seidel method which can be easily vectorized on GPUs. With the accelerated depletion methods, only about 10% of MC calculation time is consumed for depletion, so an accurate full core cycle depletion calculation for a commercial power reactor (BEAVRS) can be done in 16 h with 24 consumer-grade GPUs.

• Journal of Industrial Technology
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• v.21 no.B
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• pp.141-147
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• 2001

For the preparation of calcium carbonate particles from aqueous $Ca(OH)_2$ slurry, carbonation reaction of aqueous $Ca(OH)_2$ slurry was carried out by batch method the $CO_2$ into reactor filled with aqueous slurry of $Ca(OH)_2$. The concentration of $Ca(OH)_2$ varies from 1.00 to 7.00wt%, reactor temperature at 20 and $40^{\circ}C$, and reactor pressure from atmospheric pressure to $6.0kg_f/cm^2$. Crystal structure of calcium carbonate was of calcite, the particle size were about $0.05{\sim}2.0{\mu}m$, and the particle shape was cubic and spindle. When reactor temperature was higher, particle size of calcium carbonate was bigger and particle shape was varied, but reaction rate was increased. When reactor pressure was higher, particle size of calcium carbonate was smaller, particle shape was cubic, and reaction rate was increased.

• Journal of Environmental Science International
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• v.17 no.1
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• pp.97-105
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• 2008

This study examined the contaminated soils with an indicator of TPH using SVE (Soil Vapor Extraction) and biological treatments. Their results are as follows. Water content in the polluted soils slowly decreased from 15% during the initial experimental condition to 10% during the final condition. Purification of polluted soils by Bioventing system is likely to hinder the microbial activity due to decrease of water content. Removal rate of TPH in the upper reaction chamber was a half of initial removal rate at the 25th day of the experiment. The removal rate in the lower reaction chamber was 45% with concentration of 995.4 mg/kg. When the Bioventing is used the removal rate at the 14th day of the experiment was 53%, showing 7 day shortenting. Since the Bioventing method control the microbial activity due to dewatering of the polluted soil, SVE method is likely to be preferable to remove in-situ TPH. The reactor that included microbes and nutrients showed somewhat higher removal rate of TPH than the reactor that included nurtients only during experimental period. In general, the concentration showed two times peaks and then decreased, followed by slight variation of the concentration in low concentration levels. Hence, in contrast to SVE treatment, the biological treatment tend to show continuous repetitive peaks of concentration followed by concentration decrease.