• Title/Summary/Keyword: re-dissolution

Search Result 56, Processing Time 0.018 seconds

Genesis and Hydrochemistry of $CO_2$-rich Springs from Kyungpook Province, Korea (경북지역 탄산수의 생성기원과 수리화학적 특성)

  • 정찬호
    • Economic and Environmental Geology
    • /
    • v.35 no.2
    • /
    • pp.121-136
    • /
    • 2002
  • The $CO_2$-rich springs in the Kyungpook Province has been found at 16 locations. Most of the $CO_2$-rich springs outflow along either fault zones or the geologic boundary between Mesozoic granites and their adjacent rocks. The $CO_2$-rich water samples show a high $CO_2$ concentration ( $P_{CO2}0.46 to 5.21 atm), weak acidic pHs, wide electrical conductivity values ranging from 422 to 2,280 $\mu\textrm{S}$/cm, and high re content. They are classified into the ca-HC $O_3$ type in chemical composition.$\delta$$^{18}$ O and $\delta$$^2$H data indicate that $CO_2$-rich water is meteoric origin. The $\delta$$^{13}$ C values (-1.5$\textperthousand$ to -6.1$\textperthousand$ PDB) suggest that dissolved $H_2$C $O_3$$^{0}$ C $O_3$- are mainly derived from a deep-seated $CO_2$ and carbonate minerals. The thermodynamic equilibrium state between $CO_2$-rich water and major minerals, and hydrochemical characteristics indicate that major source minerals determining the chemical composition of $CO_2$-rich water are carbonate minerals, plagioclase, K-feldspar and Fe-oxides. Under high $CO_2$ pressure and the weak acidic condition, most of the $CO_2$-rich water samples are thermodynamically in the dissolution state with respect to albite and carbonate minerals.

A Study on the Characteristics and Cleanliness of Fluidic Strip Process of Environment-Friendly Aqueous Stripper (친환경 수계 박리액의 유동박리 공정 특성 및 청정성 연구)

  • Lee, Ki-Seong;Lee, Jaeone;Kim, Young Sung
    • Clean Technology
    • /
    • v.24 no.3
    • /
    • pp.175-182
    • /
    • 2018
  • In this research, we investigated the cleanliness by optimizing the water content of the aqueous stripper in fluidic strip process. The stripping properties of the photoresist with optimized aqueous stripper were compared with the commercial organic stripper. The stripping performance was evaluated by electrical and optical characteristics on the surface of the transparent electrode that compare with stripped the transparent electrode surface and the rare surface before patterning by the photoresist. As a result of the photoresist stripping process of the organic stripper and the aqueous stripper optimized for water content, the aqueous stripper exhibited better electrical and optical characteristics than the organic stripper. In the case of the fluidic strip process with organic stripper, the photoresist dissolves in the stripper solution during stripping which can cause re-adsorption by contamination. Whereas that the aqueous stripper under development seems to decrease the photoresist dissolution in the stripper solution. Because the cyclodextrin contained in the stripper captures organic photoresist into hall of cyclodextrin which stripped through swelling and tearing. The photoresist residue captured by the cyclodextrin can be filtered. After the fluidic stripping process by different chemical stripping mechanism, the cleanliness of the organic stripper and aqueous stripper was compared and analyzed.

A study on Programs for Enhancing Remarried Family Functioning (재혼가정의 가족기능향상프로그램 개발을 위한 시론적 연구)

  • Kim, Yoon-Ok
    • Korean Journal of Social Welfare
    • /
    • v.56 no.2
    • /
    • pp.215-235
    • /
    • 2004
  • A little understood but rapidly growing phenomenon in our society is remarriage. By 2002, 21% of marriage involved the remarriage of one or both partners. Furthermore, the ratio of remarriage of women has outnumbered the ratio of remarriage of men, which is remarkable change compared to the traditional culture putting a taboo on women's remarriage in Korea. The purpose of this study is to construct the perspective and the direction of programs for enhancing the remarriage family functioning. For the purpose, we explore the intrinsic vulnerability to family dissolution of remarriage and ill preparation for remarriage of people. There are unrealistic myths around, lack of informations on, absence of guideline for remarriage family life. Also, we discuss the process of remarriage family development, which leads us to the conclusion that the remarriage shows totally different family structure and family interaction from first marriage nuclear family. Based on discussion mentioned above, several suggestions are provided for developing programs for remarriage family functioning. Above all, the family developmental perspective on remarriage is more useful paradigm rather than deficit-comparison perspective for remarriage family. Also, the programs for remarriage family functioning should challenge the unrealistic myths around remarriage such as the instant love between step-parents and step-children, the re-created nuclear family, etc. Also, several points such as the remarried family developmental stage, the disparity in expectation of man and woman on remarriage, and the tendency to scapegoat a stepmother should be considered in programs for enhancing remarriage family functioning.

  • PDF

Effect of Ultrasound Irradiation during Cementation Process for Recovery of Iridium (이리듐 회수를 위한 시멘테이션 공정 중 초음파 조사의 영향)

  • Kim, Seunghyun;Kim, Young-Jin;Seo, Jun-Hyung;Cho, Jin-Sang;Cho, Kye-Hong;Lee, Jaeryeong
    • Resources Recycling
    • /
    • v.30 no.6
    • /
    • pp.61-67
    • /
    • 2021
  • This work investigated the cementation of iridium from iridium-containing hydrochloric acid leachate. Zinc powder was used as the reducing agent, and the effects of the stoichiometric ratio of Zn/Ir, initial Ir concentration, initial pH, reaction time, and ultrasound irradiation on iridium recovery were investigated. When only the stirrer was used for cementation, the iridium recovery increased with the addition amount of zinc, and the recovery of about 70% at 40 times the stoichiometric ratio of Zn/Ir. In contrast, when employing ultrasonic irradiation with stirring, the recovery of iridium decreased at 20 times or less the stoichiometric amount of zinc. The recovery of iridium increased at 40 times the stoichiometric ratio of Zn/Ir. This result may be due to the ionization of zinc and re-dissolution of iridium during the ultrasound irradiation treatment. When a combination of ultrasonic irradiation and stirring was used for cementation, the iridium recovery increased by more than 27% compared to that when using only the stirrer. It was possible to recover 99% of iridium under the following conditions: reaction time, 60 min; initial pH, 0.01; volume of leachate, 100 mL; 1770 ppm Ir, 40 times the stoichiometric ratio of Zn/Ir.

Geochemical Evolution and Deep Environment of the Geothermal Waters in the Bugok Area: Reconsideration on the Origin of Sulfate-type Geothermal Water (부곡 지열수의 심부환경과 지화학적 진화: 유황형 지열수의 생성과정 재해석)

  • 고용권;윤성택;김천수;배대석;박성숙
    • Economic and Environmental Geology
    • /
    • v.34 no.4
    • /
    • pp.329-343
    • /
    • 2001
  • The deep environment and geochemical evolution of the Bugok geothennal waters, located in the Kyeongnam Province, was re-interpreted based on the hydrochemical and isotopic data published by Yun et al. (1998). The geothermal waters of the Bugok area is geochemically divided into three groups; Geothennal water I, II and III groups. Groups I and II are geochemically similar; high temperature (55.2-77.2$^{\circ}$C) and chemically belonging to Na-S04 types. However, pH and Eh values are a little different each other and Group II water is highly enriched in S04 compared to Group I water. Group III water, occurring from peripheral sites of the central part of the geothennal waters, shows temperature range of 29.3 to 47.0$^{\circ}$C and belongs to $Na-HCO_3-S0_4$ types. The deep environment and geochemical evolution of the Bugok geothennal waters, showing the diversity of geochemistry, can be interpreted as follows; I) Descending to great depth of meteoric waters that originated at high elevation and reacting with sediments and/or granites in depth. The $S0_4$ concentration of the waters has been increased by the dissolution of sulfate minerals in sediments. 2) During the continuous descending, the waters has met with the reduction environment, producing the $H_2S$ gas due to sulfate reduction. The waters has been heated up to 130$^{\circ}$C and the extent of water-rock reaction was increased. At this point, pH of waters are increased, S04 concentration decreased and calcite precipitated, therefore, the waters show the $Na-S0_4$ type. 3) Ascending of the geothennal waters along the flow path of fluids and mixing with less-deeply circulated waters. The $S0_4$ concentration is re-increased due to the oxidation of $H_2S$ gas and/or sulfide minerals in sediments. During continuous ascending, these geothennal waters are mixed with shallow groundwater.

  • PDF

A Study on the Resource Recovery of Fe-Clinker generated in the Recycling Process of Electric Arc Furnace Dust (전기로 제강분진의 재활용과정에서 발생되는 Fe-Clinker의 자원화에 관한 연구)

  • Jae-hong Yoon;Chi-hyun Yoon;Hirofumi Sugimoto;Akio Honjo
    • Resources Recycling
    • /
    • v.32 no.1
    • /
    • pp.50-59
    • /
    • 2023
  • The amount of dust generated during the dissolution of scrap in an electric arc furnace is approximately 1.5% of the scrap metal input, and it is primarily collected in a bag filter. Electric arc furnace dust primarily consists of zinc and ion. The processing of zinc starts with its conversion into pellet form by the addition of a carbon-based reducing agent(coke, anthracite) and limestone (C/S control). These pellets then undergo reduction, volatilization, and re-oxidation in rotary kiln or RHF reactor to recover crude zinc oxide (60%w/w). Next, iron is discharged from the electric arc furnace dust as a solid called Fe clinker (secondary by-product of the Fe-base). Several methods are then used to treat the Fe clinker, which vary depending on the country, including landfilling and recycling (e.g., subbase course material, aggregate for concrete, Fe-source for cement manufacturing). However, landfilling has several drawbacks, including environmental pollution due to leaching, high landfill costs, and wastage of iron resources. To improve Fe recovery in the clinker, we pulverized it into optimal -sized particles and employed specific gravity and magnetic force selection methods to isolate this metal. A carbon-based reducing agent and a binding material were added to the separated coarse powder (>10㎛) to prepare briquette clinker. A small amount (1-3%w/w) of the briquette clinker was charged with the scrap in an electric arc furnace to evaluate its feasibility as an additives (carbonaceous material, heat-generating material, and Fe source).