• 제목/요약/키워드: re-dissolution

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지하 처분장에서의 방사성폐기물 고화체의 용출 및 용해에 대한 수학적 모형 분석 (Mathematical Modeling for Leaching and dissolution of Solidified Radioactive Waste in a Geologic Reposiory)

  • Kim, Chang-Lak;Park, Kwang-Sub;Cho, Chan-Hee;Kim, Jhinwung;Suh, In-Suk
    • Nuclear Engineering and Technology
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    • 제20권2호
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    • pp.120-131
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    • 1988
  • 지중매몰된 방사성핵종들이 지하수계를 통해 이동을 하는 Source를 수학적으로 표시하는 Source Term 모형이 필요하다. 물질전달식 또는 측정식에 근거한 여러 Source Term 모형을 비교 분석하였다. 일반적으로 용출 또는 용해에는 (1) 화학반응, (2) 확산 등에 의한 물질이동의 두 가지 작용이 관여한다. 화학반응은 고화체가 지하수에 노출된 후 초기의 짧은 기간 동안에만 용해율을 조절한다. 외부로의 물질전달율이 지하 처분장에서 방사성폐기물 고화체로부터의 장기간에 걸친 핵종유출율을 조절하는 역할을 한다. 물질전단 이론을 적용 할 때는, 필요로 하는 물질이동 현상을 기술할 수 있는 식을 선택해야 한다. 적절히 사용했을 경우, 물질전달 이론에 입각한 Source Term 모형은 핵종유출율의 신뢰할 만한 예측을 위한 귀중한 도구이다.

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Improved Uniformity in Resistive Switching Characteristics of GeSe Thin Film by Ag Nanocrystals

  • Park, Ye-Na;Shin, Tae-Jun;Lee, Hyun-Jin;Lee, Ji-Soo;Jeong, Yong-Ki;Ahn, So-Hyun;Lee, On-You;Kim, Jang-Han;Nam, Ki-Hyun;Chung, Hong-Bay
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.237.2-237.2
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    • 2013
  • ReRAM cell, also known as conductive bridging RAM (CBRAM), is a resistive switching memory based on non-volatile formation and dissolution of conductive filament in a solid electrolyte [1,2]. Especially, Chalcogenide-based ReRAM have become a promising candidate due to the simple structure, high density and low power operation than other types of ReRAM but the uniformity of switching parameter is undesirable. It is because diffusion of ions from anode to cathode in solid electrolyte layer is random [3]. That is to say, the formation of conductive filament is not go through the same paths in each switching cycle which is one of the major obstacles for performance improvement of ReRAM devices. Therefore, to control of nonuniform conductive filament formation is a key point to achieve a high performance ReRAM. In this paper, we demonstrated the enhanced repeatable bipolar resistive switching memory characteristics by spreading the Ag nanocrystals (Ag NCs) on amorphous GeSe layer compared to the conventional Ag/GeSe/Pt structure without Ag NCs. The Ag NCs and Ag top electrode act as a metal supply source of our devices. Excellent resistive switching memory characteristics were obtained and improvement of voltage distribution was achieved from the Al/Ag NCs/GeSe/Pt structure. At the same time, a stable DC endurance (>100 cycles) and an excellent data retention (>104 sec) properties was found from the Al/Ag NCs/GeSe/ Pt structured ReRAMs.

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모의 FP-$(Na_2CO_3-NaHCO_3)-H_2O_2$ 용액으로부터 NaTPB 및 TPPCl에 의한 Cs 및 Re(/Tc)의 침전 거동 (Precipitation behaviors of Cs and Re(/Tc) by NaTPB and TPPCl from a simulated fission products-$(Na_2CO_3-NaHCO_3)-H_2O_2$ solution)

  • 이일희;임재관;정동용;양한범;김광욱
    • 방사성폐기물학회지
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    • 제8권2호
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    • pp.115-122
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    • 2010
  • 본 연구는 $H_2O_2$가 함유된 ($Na_2CO_3-NaHCO_3$) 혼합 탄산염 계에서 사용후핵연료를 산화용해할 시 U과 함께 공용해 되는 Cs, Te, Tc, Mo 등의 핵분열생성물로부터 Cs과 Tc의 선택적 침전 제거 거동을 규명하였다. Cs과 Tc은 각각 장수명 핵종으로 지하에서의 빠른 핵종 이동성과 고방열성 등으로 최종 처분 시 처분 환경을 저해하는 핵종으로 처분 안전성 제고 측면에서 이들의 제거는 중요한 과제 중의 하나이다. Cs과 Re (Tc 대용원소)의 선택적 침전제로는 각각 NaTPB, TPPCl를 선정하였으며, NaTPB에의한 Cs 침전 및 TPPCl에 의한 Re 침전 모두 5분 이내로 매우 빠르게 이루어졌으며, 온도를 $50^{\circ}C$, 교반속도를 1000 rpm 까지 증가시켜도 이들의 침전 속도에는 별 영향이 없었다. NaTPB 침전 및 TPPCl 침전에 있어 가장 중요한 요인은 침전 용액의 pH 이며, 특히 TPPCl에 의한 Re의 선택적 침전의 경우 낮은 pH 에서 Mo가 Re과 공침되므로 pH 9 이상에서 수행하는 것이 효과적이다. 그리고 [NaTPB]/[Cs] 및 [TPPCl]/[Re]의 몰 농도 비 1 이상에서 Cs 및 Re을 각각 99% 이상 선택적으로 침전 제거할 수 있었다.

Ion Exchange Recovery of Rhenium and Its Determination in Aqueous Solutions by Diffuse Reflection Spectroscopy

  • Kalyakina, O.P.;Kononova, O.N.;Kachin, S.V.;Kholmogorov, A.G.
    • Bulletin of the Korean Chemical Society
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    • 제25권1호
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    • pp.79-84
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    • 2004
  • The existing technological schemes for processing rhenium-containing raw materials involve the recovery of Re from solutions, which can be effectively achieved by anion exchange method. The application of anion exchange also allows to study rhenium state in aqueous solutions and to develop analytical control methods. The present work is focused on investigation of ion exchange equilibrium in the analytical system Re(VII)-HCl-$SnCl_2$-KSCN-anion exchanger by means of sorption-desorption method as well as by electron, IR- and diffuse reflection spectroscopy. It was shown that rhenium can be quantitatively recovered from this system. It is proposed to use the sorption-spectroscopic method for Re(VII) determination in aqueous solutions. The calibration curve is linear in the concentration range of 0.5-20.0 mg/L (sample volume is 25.0 mL) and the detection limit is 0.05 mg/L. The presence of Mo(VI), Cu(II), Fe(II, III), Ni(II), Zn(II) as well as $K^+,\;Na^+$ do not hinder the solid-phase determination of rhenium. Rhenium (VII) determination by diffuse reflection spectroscopy was carried out in model solutions as well as in samples of river-derived water and in solutions obtained after the dissolution of spent catalysts.

Development of a Virus Concentration Method and its Application for the Detection of Noroviruses in Drinking Water in China

  • Liu, Junyi;Wu, Qingping;Kou, Xiaoxia
    • Journal of Microbiology
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    • 제45권1호
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    • pp.48-52
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    • 2007
  • A new procedure for the concentration of nonoviruses from water samples has been developed. This procedure (calcium flocculation-citrate dissolution method) uses the following steps: virus flocculation formed by treatment with 1 M $CaCl_2$ and 1 M $Na_2HPO_4$, virus release by sodium citrate dissolution (0.3 M Na citrate, pH 3.5), and virus re-concentration by ultrafiltration. When reverse transcription (RT)-PCR was performed after the procedure, the overall detection sensitivity for seeded noroviruses in a one liter drinking water sample was as low as 1 RT-PCR unit, which is equal to a $10^{-6}$ dilution of the virus sample. This approach showed at least a 5-fold-higher sensitivity than the current method with its three steps of adsorption-elution-concentration. The newly developed procedure was used to test different brands of bottled drinking water from China for putative contamination with noroviruses. A total of 144 samples were analyzed; all of the samples were negative for norovirus specific nucleic acids.

Living for the Children: Immigrant Korean Mothers' Re-creation of Family after Marital Dissolution

  • Oh, Seieun
    • 성인간호학회지
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    • 제26권4호
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    • pp.479-487
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    • 2014
  • Purpose: This study was a grounded theory research aimed at generating a substantive theory that accounts for the explanatory social processes in which immigrant Korean single-mother families were engaged in the United States. Methods: In-depth interviews were conducted with 15 immigrant Korean single mothers who were living with children under 18 years of age at the time of the interviews. Data collection guided by theoretical sampling and concurrent constant comparative analysis of the transcribed data was conducted to identify the core social process. Results: The emerged core social process was "living for the children," which represented the driving process by which these women made transition to their new lives as single-mother families. The major task throughout the entire transition was re-creating their families. The women's transition involved practical and psychological transitions. The practical transition involved three stages: assuring family survival, struggling between the father role and the mother role, and stabilizing. The psychological transition involved becoming strong and settling in with a new supportive network. Conclusion: Study results added to the literature by elaborating the women's emphasis on maternal identity and the resilience-provoking nature of the women's transitions.

리트벨트 작품의 공간표현 형식에 관한 연구 - 몽드리앙 작품과의 비교를 중심으로 - (A Study on the form of spatial expression shown in Rietveld's works - Focused on comparing with Mondrian's works -)

  • 박영경
    • 한국실내디자인학회논문집
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    • 제40호
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    • pp.68-75
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    • 2003
  • The purpose of this study is to find out the expression style of space in Rietveld's early works in comparison with Mondrian's paintings. Through investigating the development of their works and analyzing the composition and disposition type of elements such as point, line, plane, color in the selected works, we can draw the following conclusions. .First, Rietveld pursues the dissolution of traditional volume and the de-composition of elements as Mondrian does. Second, the painterly property of plane is emphasized by the projection of separately floating elements on the picture plane. Third, the separating the layer of lines from the layer of planes and the re-combination of these two layers present the superimpositional image of three-dimensional objects. This leads into new conception of architectural space and develops the transparency and the extension of plan in modem architecture.

$CO_2$ 레이저빔을 이용한 예민화된 Alloy 600의 급속응고 미세구조 연구 (Study on microstructure of sensitized Alloy 600 rapidly solidified by a $CO_2$ laser beam)

  • 임연수;서정훈;국일현;김정수
    • 한국레이저가공학회지
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    • 제1권1호
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    • pp.18-23
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    • 1998
  • A Study on microstructural changes of sensitized Alloy 600 which was rapidly solidified by a $CO_2$ laser beam was conducted using microscopic equipments such as SEM and TEM. Dissolution of Cr-rich carbides and resultant Cr recovery on the grain boundaries occurred in the heat affected zone (HZA). The microstructure of the laser melted zone (LMZ) having epitaxially solidified from the HAZ was mainly celluar-dendritic with the 〈100〉 crystallographic direction of growth. The Cr concentration was observed to increase along the cell bondaries, and tiny particles were distributed along the cell walls with tangled dislocations around them. Cr-rich carbides had been completely melted by the high density of a laser beam, and were not re-precipitated during the matrix solidification due to a fast cooling rate in the LMZ.

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Synthesis of amorphous calcium carbonate by gas-liquid reaction and its crystallization

  • Ahn Ji-Whan;Kim Hyung-Seok;Park Jin-Koo;Kim Ka-Yeon;Yim Going;Joo Sung-Min
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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    • pp.654-657
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    • 2003
  • We obtained amorphous calcium carbonate through the carbonation reaction of $Ca(OH)_2$, and through this reaction, observed changes in particle shape and phase by electric conductivity, XRD and TEM analysis. According to the result of the analysis, in the first declining stage of electric conductivity, amorphous calcium carbonate that has formed is coated on the surface of $Ca(OH)_2$ and obstructs its dissolution, and in the first recovery stage of electric conductivity, amorphous calcium carbonate is dissolved and re-precipitated and forms chains of fine calcite particles linearly joined. In the second decline of conductivity, viscosity increases due to the growth of chains of calcite particles, and finally the calcite particles are dissolved and separated into colloidal crystalline calcite, thereby increasing electric conductivity again.

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Bioactivity of Calcium Phosphate Ceramic Coatings on Metallic Implants

  • Kim, Cheol-Sang;Ducheyne, P.
    • 대한의용생체공학회:의공학회지
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    • 제11권1호
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    • pp.5-12
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    • 1990
  • Calcium phosphate ceramics have been applied intensively to orthopaedic and dental implants by virtue of their osteoconductive nature. In an attempt to enhance the bone implant intergrity and Eta utility, these ceramics are deposited onto the porous surface of metallic implants. The coating procedure and the ensuing phase transformations of the ceramic alter the mechanical properties and surface chemistry of the ceramic layers as well as those of the substrate. These structural and compositional differences are directly related to the interaction mechanisms at the surface-active ceramicbone interface. Material and processing induced influences on dissolution, electrokinetic behavior, ceramic-metallic substrate interface and boRe growth enhancement are presented.

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