• International Journal of Concrete Structures and Materials
• /
• 제8권3호
• /
• pp.213-228
• /
• 2014

Alkali-activated binder (AAB) is recently being considered as a sustainable alternative to portland cement (PC) due to its low carbon dioxide emission and diversion of industrial wastes and by-products such as fly ash and slag from landfills. In order to comprehend the behavior of AAB, detailed knowledge on relations between microstructure and mechanical properties are important. To address the issue, a new approach to characterize hardened pastes of AAB containing fly ash as well as those containing fly ash and slag was adopted using scanning electron microscopy (SEM) and energy dispersive X-ray spectra microanalyses. The volume stoichiometries of the alkali activation reactions were used to estimate the quantities of the sodium aluminosilicate (N-A-S-H) and calcium silicate hydrate (CSH) produced by these reactions. The 3D plots of Si/Al, Na/Al and Ca/Si atom ratios given by the microanalyses were compared with the estimated quantities of CSH(S) to successfully determine the unique chemical compositions of the N-A-S-H and CSH(S) for ten different AAB at three different curing temperatures using a constrained nonlinear least squares optimization formulation by general algebraic modeling system. The results show that the theoretical and experimental quantities of N-A-S-H and CSH(S) were in close agreement with each other. The $R^2$ values were 0.99 for both alkali-activated fly ash and alkali-activated slag binders.

• Journal of Microbiology and Biotechnology
• /
• 제26권8호
• /
• pp.1428-1438
• /
• 2016

In the present work, Arthrobacter sp. 25, a lead-tolerant bacterium, was assayed to remove lead(II) from aqueous solution. The biosorption process was optimized by response surface methodology (RSM) based on the Box-Behnken design. The relationships between dependent and independent variables were quantitatively determined by second-order polynomial equation and 3D response surface plots. The biosorption mechanism was explored by characterization of the biosorbent before and after biosorption using atomic force microscopy (AFM), scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The results showed that the maximum adsorption capacity of 9.6 mg/g was obtained at the initial lead ion concentration of 108.79 mg/l, pH value of 5.75, and biosorbent dosage of 9.9 g/l (fresh weight), which was close to the theoretically expected value of 9.88 mg/g. Arthrobacter sp. 25 is an ellipsoidal-shaped bacterium covered with extracellular polymeric substances. The biosorption mechanism involved physical adsorption and microprecipitation as well as ion exchange, and functional groups such as phosphoryl, hydroxyl, amino, amide, carbonyl, and phosphate groups played vital roles in adsorption. The results indicate that Arthrobacter sp. 25 may be potentially used as a biosorbent for low-concentration lead(II) removal from wastewater.

• 한국방사선학회논문지
• /
• 제12권7호
• /
• pp.895-908
• /
• 2018

의료방사선의 관리에서 가장 중요한 사항은 진료의 적정성을 확보하면서 방사선위해를 최소화하는 것이다. 국제원자력기구는 진단방사선 분야의 선량 감소 방법에 대한 지침서를 만들어 환자피폭선량을 측정하여 각 국가에 사용하도록 권고하고 있다. 또한 국내에서도 우리나라의 실정에 맞게 각 촬영마다 환자 피폭 선량값을 연구하여 진단참고준위를 제시하였다.환자가 질병 때문에 방사선 진료를 받는 것은 방사선 때문에 일어날 수 있는 위해보다 그것으로 얻어지는 이익이 크기 때문이다. 병실 이동검사와 같이 자신의 질병과 무관하게 방사선에 노출되는 환자 및 보호자들의 피폭을 줄이기 위해서는 환자, 방사선사, 의사 및 의료기관의 노력이 가장 중요하다.이에 본 연구에서는 개선방안의 일환으로 MG로 병실의 이동 검사에 대한 문제점을 제시하고 이 문제점을 근거로 하여 산란선으로 예상되는 공간선량률을 분석하였다. MG에 자체 개발한 방어벽을 설치하여 방어벽 설치 전후의 공간선량률을 측정하여 그 감소율을 분석하였다. 최종적으로 이 자료들을 종합하여 MG에 방어벽을 부착하여 방사선사의 병실이동에 대한 부담감의 최소화, 병실 이동검사로 인한 방사선사, 환자 및 보호자를 방사선 노출로부터 보호하고, 검사로 인한 주위 환자 및 보호자의 불편을 최소화하는데 의의가 있다. 이와 같은 개선안에 대해 보다 효율적인 시행을 위하여 MG에 대한 새로운 법 제도가 마련되면, 향후 예상되는 비용, 인력, 고객만족도 및 더욱 더 안정적인 피폭감소방안이 정착될 것이라 사료된다.

• 한국방사선학회논문지
• /
• 제8권7호
• /
• pp.429-433
• /
• 2014

본 연구에서는 입자 침전법으로 제작된 HgO와 PbO 기반 영상 센서의 유방촬영 영역에서의 적용 가능성을 조사하였다. 이를 위하여, 다양한 두께에 따른 HgO와 PbO 필름의 물리적 특성과 x선에 대한 양자 효율을 측정하였으며, 몬테카를로 시뮬레이션 결과와 비교 평가하였다. 또한, 입자 침강법을 이용하여 인듐 주석 산화물로 코팅 된 투명 유리기판 위에 대면적 다결정 박막을 제작하였다. 본 연구에서는 단결정의 효율과 비슷한 양자 효율을 얻기 위하여 필름의 두께와 제작 조건을 변화시켜 최적화 하였다. 본 연구의 결과를 기반으로 차후 대면적 a-Si:H 패널에 적합한 대면적 필름의 제작 기술과 최적화 연구가 가능할 것으로 판단된다.

• 한국소음진동공학회논문집
• /
• 제26권1호
• /
• pp.89-96
• /
• 2016

TDOA(time delay of arrival) position estimate from acoustic measurement of artillery shell impact is studied in order to develop a targeting evaluation system. Impact position is calculated from the intersections of hyperbolic estimates based on the least square Taylor series method. The mathematical process of Taylor series estimation is known to be robust. However, the concern lays with the accuracy because it is sensitive to the bias caused by the randomness of measurement situation. The measurement error typically occurs from the distortion of waveform, change of travelling path, and sensor position error. For outdoor measurement, a consideration should be made on the atmospheric condition such as temperature and wind which can possibly change the trajectories of rays of sound. It produces wrong propagation time events accordingly. Ray tracing and optimization techniques are introduced in this study to minimize the bias induced by the ray of sound. The numerical simulation shows that the atmospheric correction improves the estimation accuracy.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
• /
• pp.330-330
• /
• 2007

Polycrystalline mercuric iodide $HgI_2$) films are being developed as a new detector technology for digital x-ray imaging. The $HgI_2$ is generally vacuum deposited by physical vapor deposition (PVD) process. But the PVD thick deposition has been caused any instability in the biasing due to any defects or cracks. In this work we present a new particle-in-binder (PIB) methodologies used for the $HgI_2$ thick films. These growth techniques can be easily extended to produce much larger film areas. This paper, for the first time, presents results and comparison of polycrystalline $HgI_2$ films derived by various PIB methods. We investigated the structural and morphological properties of the films using X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The films were characterized with respect to their electrical properties and in response to x-ray photons. Physical and electrical results were also compared between conventional polycrystalline PVD and our detectors. Leakage current as low as $350\;pA/cm^2$ at the bias voltage of ~ 200 V has been observed. And high sensitivity and good linearity in the response to x-rays was obtained in the film derived by PIB sedimentation method. Our future efforts will concentrate on optimization of film growth techniques for uniform large area deposition on image readout arrays.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
• /
• pp.176-176
• /
• 2007

Flat-panel direct conversion detectors used in compound substance of semiconductor are being studied for digital x-ray imaging. Recently, such detectors are deposited by physical vapor deposition(PVD) generally. But, most of materials (HgI2, PbI2, TlBr, PbO) deposited by PVD have shown difficult fabrication and instability for large area x-ray imaging. Consequently, in this paper, we propose applicable potentialities for screen printing method that is coated on a substrate easily. It is compared to electrical properties among semiconductors such as $HgI_2$, $PbI_2$, PbO, HgBrI, InI, and $TlPbI_3$ under investigation for direct conversion detectors. Each film detector consists of an ~25 to $35\;{\mu}m$ thick layer of semiconductor and was coated onto the substrate. Substrates of $2cm{\times}2cm$ have been used to evaluate performance of semiconductor radiation detectors. Dark current, sensitivity and physics properties were measured. Leakage current of $HgI_2$ as low as $9pA/mm^2$ at the operation bias voltage of ${\sim}1V/{\mu}m$ was observed. Such a value is not better than PVD process, but it is easy to be fabricated in high quality for large area x-ray Imaging. Our future efforts will concentrate on optimization of growth of film thickness that is coated onto a-Si TFT array.

• 대한의용생체공학회:의공학회지
• /
• 제25권4호
• /
• pp.253-259
• /
• 2004

본 연구에서는 디지털 X-선 영상시스템의 최적화 설계를 위하여 몬테카를로 방법을 이용한 영상모의실험용 코드를 visual $C^{++}$ 프로그래밍 언어를 사용하여 개발하였다. 디지털 X-선 영상시스템으로 Gd$_2$O$_2$S(Tb) 섬광체 및 광센서 어레이를 고려하였으며, 일반적인 실험 환경을 모사하기 위해 2차원 평행 그리드를 포함시켰다. X-선과 피사체, 그리드 및 섬광체와의 반응, 그리고 섬광체에서 발생된 빛의 거동 및 광센서 어레이에서의 수집을 몬테카를로 방법을 이용하여 모사하였다. Gd$_2$O$_2$S(Tb) 섬광체의 두께는 66$\mu\textrm{m}$로 설정하였으며, 광센서 어레이의 픽셀 피치는 48$\mu\textrm{m}$ 그리고 픽셀의 포맷은 256${\times}$256으로 가정하였다. 다양한 모의실험조건에서 X-선 영상을 획득한 후 객관적인 영상시스템의 성능평가 지표인 SNR(signal-to-noise ratio), MTF(modulation transfer function), NPS(noise power spectrum), DQE(detective quantum efficiency) 등을 계산하였으며, 이를 통해 화질을 평가하였다. 본 연구에서 개발된 영상모의실험 코드는 다양한 디지털 X-선 영상시스템에 대해 여러 설계변수들에 대한 성능을 예측함으로써 영상시스템 최적설계에 활용될 수 있다.

• 대한기계학회논문집A
• /
• 제26권9호
• /
• pp.1923-1930
• /
• 2002

In this paper, we present modeling and simulation of microlens formation by means of a deep X-ray lithography followed by a thermal treatment of a PMMA (Polymethylmethacrylate) sheet. According to this modeling, X-ray irradiation causes the decrease of molecular weight of PMMA, which in turn decreases the glass transition temperature and consequently causes a net volume increase during the thermal cycle resulting in a swollen microlens. In this modeling, the free volume theory including the relaxation process during the cooling process was considered. The simulation results indicate that the modeling in this study is able to predict the fabricated microlens shapes and the variation pattern of the maximum heights of microlens which depends on the conditions of the thermal treatment. The prediction model could be applied to optimization of microlens fabrication process and to designing a micro mold insert for micromolding processes.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2008년도 춘계학술대회논문집
• /
• pp.934-938
• /
• 2008

To customize individual characteristics of HRTF, a spherical model has been used for structural modeling technique. A pseudo-code of prolate spheroidal HRTF caused by incident acoustic point source is already developed, and it can be used a head shadow filter for structural modeling of HRTF. In this research, to see the necessity and efficiency of spheroidal head modeling, ITD optimization is performed on CIPIC HRTF database. From given cost function, ITD-optimized spheroidal head model, whose ITD information is the most matched version of measured ITD information, is found by varying head parameters subject by subject. By comparing results of ITD-optimized spheroids and ITD-optimized spheres, we concluded that a spherical head model is more efficient way of generating head shadow effect than a spheroidal head model does.