• Title/Summary/Keyword: raw material for replacement

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Development of Urethane Foams for Planting Media from Woodwastes (목질폐재를 이용한 식물식재용 우레탄폼의 개발)

  • Cho, Nam-Seok;Seo, Won-Sung;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.4
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    • pp.43-49
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    • 1998
  • The availability of large quantities of waste woods provides an impetus for investigating woody biomass potential uses. Polyurethane (PU) foams are prepared with reacting isocyanates and polyols, and are used. in various industry fields. Thus, lignocellulosic waste raw-materials are proposed as replacement for synthetic polyol to PU foam formulation. In this study PU foams were manufactured from liquefied woods, methanediisocyanate(MDI), catalyst, foaming stabilizer, and viscosity aids. The polyol content, isocyanate.hydroxyl group (NCO/OH) ratio, and water content were varied to evaluate their effects on the foaming and water absorption of the PU foams. Less than 400 Molecular weight. of polyethylene glycol(PEG) and 1 to 3 solvent to woody raw-material ratio were desirable for liquefying woody materials. Liquefying rate was increased with more than 3 % addition of inorganic and organic catalysts and raising reaction temperature more than $150^{\circ}C$. Addition of starch enhanced liquefying of woody materials. Fourty percents of starch resulted in about 90% liquefying rates. Foaming rates were increased with increasing moisture contents of liquefied wood. Moisture contents of 0.6% resulted in 5 time-foaming rates, and seven percents of moisture contents more than 30 time-foaming rates. But, an increase in water content may result in a decrease in cross-links between wood polyol and isocyanate, because the NCO/OH ratio is constant. Increasing moisture contents have significantly decreased density of PU foams. The optimum water content should be about 2.5% or less in this adopted condition.

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Study on Compound Humidifier Employing UV-LED using Environmental Life Cycle Assessment (환경전과정평가에 기반한 UV-LED 를 사용한 복합식 가습기에 관한 연구)

  • Choi, Won-Sik;Park, Si-Hyun;Lee, Si-Wang;Jung, Young-Mi;Yi, Hwa-Cho
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.9
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    • pp.931-937
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    • 2012
  • In this study, we assessed environmental impacts of compound humidifiers using environmental life cycle assessment and presented the ways to improvements in energy consumption of them. We found eco-design parameters and $CO_2$-eq emissions in each stage of raw material acquisition, manufacturing, transportation, use and disuse in life cycle of the compound humidifiers. The highest $CO_2$ emission is found to be in the stage of use among all stages of life cycle, which is mainly due to power consumption in thermal heating of heating coil for sterilization during humidification. The power consumption and $CO_2$ emission in the stage of use can be reduced to 1/4 and 1/3 at the highest estimate through improvement of sterilization method, respectively. We suggested the replacement of conventional thermal heating coil by ultra violet light-emitting diodes (UV-LED) for sterilization and then presented the experimental results on the sterilization effects of UV-LEDs.

Cultivation of Oyster Mushrooms Using the Garlic Peel as an Agricultural by-product (마늘껍질을 이용한 느타리버섯의 인공재배)

  • Lee, Sang-Sun;Kim, Soon-Keun;Lee, Tae-Soo;Lee, Min-Woong
    • The Korean Journal of Mycology
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    • v.25 no.4 s.83
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    • pp.268-275
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    • 1997
  • High prices of raw materials used as media for the mushroom cultivation increased the cost of commercial production of oyster mushroom (Pleurotus ostreatus). In this study, garlic peels (Allium sativum f. pekinese) as an agricultural by-product were investigated to replace the saw dust for the bottle cultivation of oyster mushroom. Mycelial growth of oyster mushroom were examined by the extracts made from the sawdust, rice bran and garlic peels. The mycelial growth was very poor in the agar media containing the extracts of sawdust or garlic peels, but was good when those of the rice bran were added. In the polypropylene bottle experiment, the sawdust medium which ammended with minerals vitamin was essential for the production of the mushroom fruitbodies. The rice bran was considered to stimulate the mycelial growth, but not the development of basidiocarps. The garlic peel was not a factor to stimulate the production of mushroom fruitbodies, but a raw material ammended with the rice bran produced much amounts of mushroom. In this work, garlic peels ($10{\sim}70%$ v/v) added to the mixture of sawdust and rice bran (4 : 1, v/v) was considered to help the productions of mushroom fruitbodies. Based on the result, the replacement of expensive saw dust with inexpensive garlic peels was a good example to reduce production cost of the bottle cultivation of mushroom.

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Characteristics of Opal Glass by Calcium Phosphate Opacifier for a LED Light Diffuser (Calcium Phosphate 유백제 투입량에 따른 LED Diffuser용 유백유리의 특성)

  • Ku, Hyun-Woo;Lim, Tae-Young;Hwang, Jonghee;Kim, Jin-Ho;Lee, Mi-Jai;Shin, Dong Wook
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.75-81
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    • 2013
  • We fabricated translucent opal glass to replace the polycarbonate diffuser in LED lighting systems in order to solve the durability problem. Batch materials of opal glass with a composition of calcium phosphate were created and melted at $1550^{\circ}C$, and the effect of opaqueness was identified by an addition of 1~7% calcium phosphate as an opacifier raw material. As a result, translucent opal glass was obtained by the melting of the mixed batch materials with a composition of more than 5% calcium phosphate glass at $1550^{\circ}C$ for 2 hrs, which had excellent optical properties for the diffuser of a LED lighting system with no dazzling from direct light by a high haze value exceeding 90% and a low parallel transmittance value of about 5%. For the thermal properties, the thermal expansion coefficient was found to be $5.6{\sim}5.9{\times}10^{-6}/^{\circ}C$ and the softening point was $874{\sim}884^{\circ}C$. In addition, good thermal properties such as good thermal shock resistance and feasibility for use with a general manufacturing process during the forming of glass tubes and bulbs were noted. Therefore, it is concluded that this translucent opal glass can be used as a glass diffuser material for LED lighting due to its high heat resistance and high durability as a replacement for a polycarbonate diffuser.

An Analysis of the Shear Strength of Reinforced Concrete Beams with Recycled Coarse Aggregates (순환굵은골재 철근 콘크리트 보의 전단강도 분석)

  • Ji, Sang-Kyu;Yun, Hyun-Do;Song, Seon-Hwa;Choi, Ki-Sun;You, Young-Chan;Kim, Keung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.851-854
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    • 2008
  • Using the recycled aggregate not only saves landfill space but also reduces the demand for extraction of natural raw material for new construction activity. However few investigations have been carried out to study the shear behaviors of RC beams with recycled aggregates such as low absorption of recycled aggregate and full-scale specimens. In this study, six reinforced concrete beams were tested to evaluate the effects of shear strength, and shear behavior on the replacement level (0, 30, 60, and 100%) of recycled coarse aggregate and different amounts of shear reinforcement. The results showed that the beams with recycled coarse aggregates present the similar shear strength and deflections as the beam with natural aggregate on an equal amount of shear reinforcement. the reinforced concrete beams with recycled coarse aggregates present the Influence of shear span-to-depth ratio, effective depth, tension reinforcement ratio and compressive strength as the beams with natural aggregate. Shear strength were compared with the provisions in current code (KCI2007) and the equation proposed by Zsutty. The KCI equations were conservative and subsequently can be used for the shear design of recycled aggregate concrete beam.

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A Study on the Synthesis Behavior of Lithium Hydroxide by Type of Precipitant for Lithium Sulfate Recovered from Waste LIB (폐리튬이차전지에서 회수된 황산리튬 전구체로부터 침전제 종류별 수산화리튬 제조 거동 연구)

  • Joo, Soyeong;Kim, Dae-Guen;Byun, Suk-Hyun;Kim, Yong Hwan;Shim, Hyun-Woo
    • Resources Recycling
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    • v.30 no.1
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    • pp.44-52
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    • 2021
  • This study investigated the effect of the type of alkaline precipitant used on the synthesis of lithium hydroxide by examining the behavior of lithium hydroxide produced using lithium sulfate recovered from a waste lithium secondary battery as a raw material. The double-replacement reaction (DRR) process was used to remove the impurities contained in the lithium salt precursor of lithium sulfate and to improve the efficiency of the synthesis of lithium hydroxide. The experiment was conducted by control the molar ratio of the precursor ([Li]/[OH]), the reaction temperature, and the composition of the alkaline precipitant (KOH, Ca(OH)2, Ba(OH)2) used for the production of highly-crystalline lithium hydroxide. A secondary solid-liquid separation was performed following the reaction to remove the impurities generated, and the purified aqueous solution of lithium hydroxide was evaporated to remove the moisture and obtain the product as a powder. The crystallinity and synthesis behavior of the product were examined.

Medium composition for Flammulina velutipes bottle cultivation utilizing cassava stem chips (카사바줄기칩을 활용한 팽이버섯 병재배용 배지의 조성)

  • Cheong, Jong-Chun;Lee, Chan-Jung;Moon, Ji-Won
    • Journal of Mushroom
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    • v.14 no.1
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    • pp.14-20
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    • 2016
  • This study was conducted to establish replacement the corncob used in winter mushroom bottle cultivation. Corncob is unstable quality in moisture content or total nitrogen(T-N) content. Fruit body yields according to the ratio of cassava stem chips mixing were compared. After treatment-1 and treatment-2, fruit body yields increased by 8.8% and 5.4% and raw material cost decreased by 7% and 19%. The results showed that cassava stem chips could replace 33% to 67% of corncob for winter mushroom bottle cultivation.

Mechanical Properties and Durability of Concrete in Relation to the Amount of Limestone Use (석회석 혼입량에 따른 콘크리트의 역학적 및 내구특성)

  • Oh, Sungwoo;Shin, Dongcheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.138-144
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    • 2017
  • In order to reduce carbon dioxide emission in construction industry, less amount of cement use can be one of the alternatives to manufacture concrete. One of the non-sintered construction materials are limestone, which is the raw material to manufacture ordinary Portland cement(OPC). A large amount of limestone have already been used as binders such as blended cement in Europe and US. Even European countries were already established the standard of blended cement, where the limestone can be used up to 35 percent. In this study, experimental researches were conducted to investigate the effects of limestone replacement on the mechanical properties and durability of concrete with 15%, 25% and 35% of limestone substitution to use limestone in blended cement. 15 percent use of limestone in blended cement developed equivalent or even higher compressive strengths compared to Plain mixture. Porosity of limestone cement with 15 percent substitution was much lower than Plain mixture. Most durability tests such as concrete carbonation, freeze-thaw cycle and drying shrinkage strains were conducted to evaluate long-term performance, and the test results indicated that 15 percent of limestone use did not significantly influence on the concrete durability compared with plain concrete.

Economic and Environmental Impact of the Bioplastics Industry: A Recursive Dynamic CGE Approach (바이오플라스틱산업의 경제적·환경적 파급효과: 축차동태 연산가능일반균형모형 적용)

  • Son, Wonik;Hong, Jong Ho
    • Environmental and Resource Economics Review
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    • v.30 no.2
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    • pp.269-297
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    • 2021
  • Bioplastics are attracting attention as a substitute for conventional petroleum-based plastics because they are carbon neutral and can be biodegradable. This study estimated economic and environmental impact of regulating the petroleum-based plastics industry and fostering the bioplastics industry using a Recursive Dynamic CGE Model of the Korean Economy. Results show that the regulation of the conventional plastics industry exhibits a positive environmental impact by reducing greenhouse gases and plastic waste and a negative economic impact with a decrease in GDP. Meanwhile, fostering the bioplastics industry with regulation on conventional plastics industry has similar levels of greenhouse gas and waste reduction effects when there is only regulation on the conventional plastics industry. It is also shown that expanding the production of bioplastics industry offsets existing economic losses as a form of increased GDP. If petroleum-based plastics are replaced through the expansion of bioplastics production, it can contribute to the decoupling of greenhouse gas emissions and plastic waste from economic growth.

Properties of quasi-noncombustible ultra-lightweight geopolymer (준불연 초경량 지오폴리머의 물성)

  • Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.3
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    • pp.132-139
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    • 2019
  • EPS (expanded polystyrene) is one of the most used building materials for insulation that is favored by its excellent heat insulation, economical efficiency and lightweight characteristics. However, EPS is vulnerable to the fire and producing large amount of toxic gases in case of fire. Therefore, ultra-lightweight geopolymer which can replace EPS is fabricated by using IGCC (integrated gasification combined cycle) fused slag and Si sludge as raw materials and the possibility of replacement on ultra-lightweight geopolymer for EPS as an insulation building material was evaluated in this study. Ultra-lightweight geopolymer can be fabricated with the pulverized IGCC fused slag having low carbon content and density, compressive strength, thermal conductivity were $0.064g/cm^3$, 0.04 MPa, and 0.072 W/mK, respectively. The thermal conductivity of ultra-lightweight geopolymer is 1.5~2.0 times higher than that of EPS suggested in the KS M 3808; however, the thermal conductivity value of geopolymer is meaningful and competitive to that of EPS in the market. Therefore, ultralightweight geopolymer can be applicable to the building material for thermal insulation purpose and have an enough possibility to replace EPS in the future because it is not only much safer than EPS in case of fire but also it can be fabricate by using waste materials from the industry.