• Korean Journal of Materials Research
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• v.32 no.1
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• pp.23-29
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• 2022

Fly ash is a by-product of coal fired electrical power plants and used as a material for cement and concrete; particularly, imported fly ash is mainly applied for cement production. Main objectives of this article are to replace domestic fly ash with an imported source. To verify the possibility of domestic fly ash as a material for cement from the aspect of chemical composition and physical properties, we manufactured various kinds of cement, such as using only natural raw material, shale, and partial replacement with domestic and imported fly ash. When we used the domestic and imported fly ash, there were no specific problems in terms of clinker synthesis or cement manufacturing in relation to the natural material, shale. In conclusion, domestic fly ash has been confirmed as an alternative raw material for cement because 7 days and 28 days compressive strength values were better than those of reference cement using natural raw material, on top of the process issue.

• Journal of the Korea Institute of Building Construction
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• v.17 no.2
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• pp.183-189
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• 2017

The aim of the research is to provide rheological properties of cement paste with various qualities of coal ash including fly ash, raw ash, and reject ash. Generally, fly ash is the well known supplementrary cementitious materials for concrete and is used to improve various properties. Although fly ash is obtained as a byproduct of fire powder plant, still reject ash is wasted from raw ash. In this research, thus, to provide a fundamental information on using not only fly ash but also raw ash or reject ash for cementitious materials, a rheological properties of cement paste was studied with three different coal ash. This research was conducted from particle conditions of three different coal ashes to rheological properties in cement paste phase. According to the expeirment, reject ash was consisted with large and coagulated particles although fly ash was consisted with a small and spherical shaped particles. based on the particle conditions of various coal ashes, rheological behaviors were tested, and it was shown as the coal ashes improved the fluidity of cement paste. Specifically, depending on the particle distributions of cement paste, it is considered that the viscosity of paste can be controlled.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.33 no.6
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• pp.210-215
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• 2023

Raw mix burnability is an especially crucial factor in cement manufacturing technology, and it depends on the physical, chemical and mineralogical properties of each raw material. In this article, we compared the difference of burnability between the domestic and Japanese fly ash as cement raw materials by using Lafarge and Polysius evaluation method. Regardless of the type or amount of fly ash used, it was found to be more combustible when using fly ash. In both case, burnability improves as the amount of fly ash increases, especially the improvement in bunarbility is remarkable up to 3%. In conclusion, as the amount of fly ash increases within the range allowed by cement quality, burnability of raw materials improves, and thus the fuel cost required for the firing of clinker can also be expected to be reduced.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.6
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• pp.180-188
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• 2020

To replace Japanese coal ash used in the domestic cement production and to recycle large quantities of domestic pond ash, it is essential to develop the technologies for quality control of cement by using the domestic pond ash. Thus, in this study, the feasibility of using the pond ash as a raw material for cement was investigated through chemical composition and microstructure analysis. As a result, most of the domestic pond ash contained slightly more Fe2O3, chloride, and unburned carbon contents than Japanese coal ash. In particular, the contents of chloride were considerably low in the pond ash that was transferred to fresh water or collected from surface of landfill area. However, since circulating fluidized bed boiler coal ash had relatively high SO3 contents causing durability problems of cement, it was not suitable for use as a raw material for cement. Thus, to replace Japanese coal ash with the domestic pond ash, it is necessary to introduce the adjustment of mixture proportion of cement raw materials and the process of removing chloride in the pond ash.

• Journal of the Korean Ceramic Society
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• v.41 no.4
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• pp.323-327
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• 2004

This study has been carried out to use the municipal solid waste sewage sludge ash generated at sewage disposal field as the raw materials of Ordinary Portland Cement (OPC). Limestone, shale, converter slag, and fly ash were used as the main raw materials. After the raw materials were mixed, these were fired at 1,300, 1,350, 1,400, 1,450, and 1,500$^{\circ}C$ for 1 h and cooled rapidly in air. The properties of clinker synthesized were examined with XRD, SEM, and burnability index by polysius method.

• Journal of the Korean Ceramic Society
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• v.52 no.2
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• pp.154-158
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• 2015

This paper investigates the reaction rates of $CO_2$ that stores carbonation through comparing the carbonation behavior between $Ca(OH)_2$ and fly ash with circulating fluidized bed combustion (CFBC) containing a large amount of free CaO. Because fly ash with CFBC contains abundant free CaO, it cannot be used as a raw material for concrete admixtures; hence, its usage is limited. Thus, it has been buried until now. In order to consider its reuse, we conduct carbonation reactions and investigate its rates. X-ray diffraction (XRD), thermogravimetric/differential thermal analysis (TG/DTA), and X-ray fluorescence (XRF) are conducted for the physical and chemical analyses of the raw materials. Furthermore, we use a PH meter and thermometer to verify the carbonization rates. We set the content of the fly ash of CFBC, $Ca(OH)_2$, $CO_2$ flow rate, and water to 100 ~ 400 g, 30 ~ 120 g, 700 cc/min, and 300 ~ 1200 g, respectively, based on the content of the free CaO determined through the TG/DTA analyses. As a result, the carbonization rate of the fly ash with CFBC is the same as that of $Ca(OH)_2$, and it tends to increase linearly. Based on these results, we investigate the carbonization behavior as a function of the free CaO content contained in the raw material.

• Resources Recycling
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• v.5 no.3
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• pp.44-49
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• 1996

One of the most serious problems in utilizing the fly-ash produced from damcstic coal-firing power plants is lhc unburned-carbon mntained m the fly-ash In this shldy, the effects of fruther and collector an the yield,recuvery,unburnedcarbon rejectiou peiccntage,and process efficiency of product (cleaned fly-ash) wcrc examined when convzntional froth flotation was applied to rejcct the unburned-carbon included in the fly-ash of bituminous coal Alsa,the ash analysis for both thc raw and the clcaned fly-ash was conducted to review the change in thc major elements of fly-ash. Experimental results shawcd lhat tlle rcjectlon oI the unburned-cubon of thc raw fly-ash sample is available upto 92.4% using fiath flotalian and that the putity ol the pmdud(c1eancd fly-ash) attains up to 99.4%.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.211-218
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• 2022

Coal ash is being considered as a source of silica and alumina for cement clinker. The purpose of this study was to investigate the effect on cement clinker sintering by confirming the high-temperature microstructural change according to the firing temperature in the cement clinker sintering process of coal ash. In the coal ash used as a raw material for cement clinker, the shape change of the particle surface was confirmed from the sintering tem perature of 950 ℃. The shape of the coal ash disappeared from the sintering temperature higher than 1250 ℃. It was confirmed that the Al and Fe components of the coal ash were converted to the cement interstitial phase at a temperature higher than 1350 ℃. In addition, the clinker using a large amount of coal ash as a raw material showed a low content of Lime and a high content of Belite in the sintering tem perature range of 1150~1200 ℃. From this, it was confirmed that the formation of calcium silicate mineral proceeds more easily at the initial sintering temperature by the application of coal ash.

• Journal of the Korean Ceramic Society
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• v.49 no.2
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• pp.185-190
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• 2012

The purpose of this study was to examine a possibility that fly ash could be used as raw material for carbonation by conducting the experiment on magnetic separation and hydration of fly ash that contained a large amount of CaO composite. Wet magnetic separation experiment was performed to remove the component of magnetic substance that contained fly ash, which aimed at increasing the content of CaO in the non-magnetic domain. The selected fly ash was used for hydration experiment before the TG-DTA, XRF and XRD analyses were made to confirm the Ca component that could be carbonated. Then, the fly ash was turned to a hydrate that was favorable to dissociation of $Ca^{2+}$ ion. As a result, the magnetic separation enabled detecting the content of CaO component by up to 61 wt% in the non-magnetic domain. Since the hydrate was confirmed, it is believed that the fly ash can be used as raw material for carbonation.

• Journal of Ceramic Processing Research
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• v.19 no.6
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• pp.509-513
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• 2018

This study uses fly ash for non-shrinkage grout in order to develop strength of grout and improve its durability. We grind fly ash to the extent of $7,000cm^2/g$ and use ground fly ash and raw fly ash respectively at the proportion of 10%, 20%, 30% instead of OPC and compare the results drawn on the condition of each proportion. As a mixed material of grout, EVA and water-reducing agent is added in order to prevent bleeding and improve segregation resistance, CSA is added with a view to preventing drying shrinkage and improving early strength property. In regard to flow and flow time test for analyzing and evaluating workability, it is revealed that grouts of all mix proportions except raw fly ash 30% mix proportion satisfy all performance criteria. With regard to length change rate, grout with no admixture shows the highest shrinkage rate, but the rate is 0.0005%, extremely insignificant rate. As material age increases, compressive strength of two grouts, that is to say ground fly ash 10% and 20%-used grouts, exceed that of grout with no admixture or show high-level compressive strength.