• 한국염색가공학회지
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• 제19권2호
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• pp.14-23
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• 2007

This research article explores the use of phthalocyanine reactive dye on nylon substrate. The effect of factors such as pH, temperature, liquor ratio and alkali addition on level of dye exhaustion, fixation and total fixation efficiency. Low pH, high temperature and low liquor ratio were found to be suitable conditions for maximum % exhaustion values. The effect of sulphatoethylsulphone(SES) and vinylsulphone(VS) form of the dyes on level of dye fixation was also discussed. The optimized exhaustion (%E), fixation(%F) and total fixation efficiency were determined. Modification of the dyeing process with alkali addition displayed that dye fixation(%) increased by alkali addition. Vinylsulphone(VS) moiety of the dye was found to be superior to. maximum fixation (%F). Appropriate predictable empirical models, relatively a new approach in dyeing processes, were developed incorporating interactions effects of temperature, pH and liquor ratio for predicting % exhaustion, fixation and total fixation efficiency. The significance of the mathematical model developed was ascertained using microsoft excel regression(solver) analysis module. High correlation coefficient was obtained (R2=0.9895 for % exhaustion, R2=0.9932 for fixation, R2=0.9965 for total fixation efficiency) for the model which shows prominent prediction capacity of the model for my conditions. The predictable polynomial equations developed from tile experimental results were thoroughly analyzed by ANOVA (Analysis of Variance) statistical concepts.

• 한국염색가공학회지
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• 제31권3호
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• pp.127-134
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• 2019

Cotton fabrics were treated with gelatin to improved their dyeability, color strength toward cochineal dye. Gelatin were used as the protein. Gelatin is containing a large number of hydrophilic groups. Pad-dry-cure method was used for the treatment process(10g/L concentration). The scanning electron micrograph showed the gelatin was deposited on the surface of cotton. Pretreated fabrics were mordanted with 10%(owf) alum. Then the fabrics were dyed with cochineal. Compared with original cotton fabric the K/S value with cochineal dyes was significantly improved on gelatin modified cotton. Treating cotton with 10g/L concentration gelatin offered higher cochineal adsorption. The dyeability of pH 4 yielded the highest color strength. In dyebaths of a ratio of ethanol and water such as; 10:0, 9:1, 8:2, 7:3, 6:4, 5:5, 4:6, 3:7, 2:8, 1:9, 0:10, fabrics were dyed. The ratio of ethanol and water had powerful effects on solution polarity. Cochineal dye uptake showed maximum value, when the proportion of ethanol and water was 9:1. Dyeing at increased temperatures and with increased time resulted in higher dye uptake and reddish-purple color(5RP). The washing fastness was 1-2grade, and the fastness to light was 2-3grade.

• 한국의류학회지
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• 제45권6호
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• pp.1035-1051
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• 2021

This study compares the strength properties of Jumchi-Hanjis dyed with 70% and 100% persimmon juice concentrations and undyed Jumchi-Hanjis. The Juumchi-Hanjis were made from Dakjis (mulberry papers), which were mixed with different ratios of fibers from paper mulberries originating in Korea and Thailand, including wood pulp from Canada. Research results showed that tensile, wet tensile, and bursting strengths of Jumchi-Hanjis dyed with 70% concentration were higher than those of undyed Jumchi-Hanjis. However, the tearing strengths of the dyed Jumchi-Hanjis were lower than those of undyed Jumchi-Hanjis. The wet tensile strengths of Jumchi-Hanjis dyed with 100% concentration were higher than those of dyed with 70% concentration. The increase and decrease of tensile, tearing, and bursting strengths depending on persimmon juice dyeing differed as per the mixing ratio of the raw materials of Jumchi-Hanjis. Dyeing with 100% persimmon juice concentration tends to be more useful than 70% to increase the tensile (MD) and wet tensile strengths of Jumchi-Hanjis containing only Korean mulberry fibers (90%) and wood pulp (10%) as raw materials. Dyeing with 100% concentration tends to be less useful than 70% to increase the tensile, tearing and bursting strengths of Jumchi-Hanjis with high proportions (90% or 60%) of mulberry fibers from Thailand.

• 한국염색가공학회지
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• 제27권1호
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• pp.11-17
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• 2015

Recently, super fiber reinforced composite materials are widely used in many industries due to high mechanical properties. In this study, 2 different types of composite materials were manufactured in order to compare their mechanical properties. Carbon and Aramid fibers were used for reinforcement materials and Bisphenol-A type epoxy resin was for matrix. Two kinds of fiber-reinforced materials were manufactured by RIM(Resin Injection Molding) method. Before manufacturing composite materials, the optimal manufacturing and curing process condition were established and the ratio of reinforcement to epoxy resin was discussed. FT-IR analysis was conducted to clarify the structure of epoxy resin. Thermal and mechanical property test were also carried out. The cross-section of composite materials was observed using a scanning electron microscope(SEM).

• 한국염색가공학회지
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• 제24권2호
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• pp.131-137
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• 2012

para-Aramid fibers were treated by low-temperature plasma to improve the adhesion. The surface of para-aramid fibers were treated with gaseous plasma of several discharge power and treatment time in oxygen gas at 1Torr pressure. The treated fibers at low-temperature plasma were taken oxygen-containing functional groups and micro-crator on the surface. The modified fibers were measured by dynamic contact angle analyzer and XPS(X-ray photoelectron spectroscopy). The Interfacial adhesion properties of aramid fabric and polyurethane resin were determined by T-peel test. The surface of aramid fibers were observed by FE-SEM photographs. It was found that surface modification and chemical component ratio of the aramid fibers were improved wettability and adhesion characterization.

• Journal of the Korean Wood Science and Technology
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• 제49권2호
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• pp.134-141
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• 2021

This study was conducted to investigate the potential of the neutral extract (NE) prepared by treating P. radiata bark with aqueous NaHCO3 solution as a natural dyestuff. Silk and cotton fabrics were dyed at four different NE concentrations, 0.5%, 1.0%, 1.5%, and 2.0% o.w.b. (on the weight of bath). The fabric to liquid ratio of 1 : 50, dyeing temperature of 90℃, and dyeing time of 90 min were used as the fixed condition. The appropriate NE dyeing concentration of silk and cotton fabrics was 1.5% o.w.b. Colors of the dyed silk and cotton fabrics were brown and light brown, respectively. From colorfastness assessment, both dyed silk and cotton showed good washing and rubbing fastness, but poor light fastness. NE dyed fabrics exhibited excellent ammonia deodorization property and antibacterial activity against Staphylococcus aureus and Klebsiella pneumoniae. Therefore, NE of P. radiata bark could have the potential for use as a functional brown dyestuff.

• 한국염색가공학회지
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• 제14권6호
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• pp.335-341
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• 2002

The physical properties and the dyeability of the nylon S fibers Prepared by high speed spinning according to godet roller draw ratio form 1.1 to 1.6 were investigated. The strains of nylon 6 fibers were decreased against the increase of the godet roller draw ratio. The stresses of nylon 6 fibers were increased with the increase of the godet roller draw ratio. Birefringences, densities and crystallinities of the nylon 6 fibers were increased with the increase of godet roller draw ratio In DSC diagrams, the $\gamma$ form of crystal became dominant at higher godet roller draw ratio. The dye uptakes of C. 1. Acid Blue 113 on the fibers were decreased against the increase of godet roller draw ratio.

• 한국의류학회지
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• 제41권5호
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• pp.914-928
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• 2017

This research investigated the effect of pH of dyebath and dyeing temperature on the dyeability of indigotin and indirubin on silk as well as the relationship between the amount of indigotin and indirubin detected from the dyed silk through HPLC-DAD analysis and the color of samples measured using a spectro-colorimeter. Indigo standard dye and indirubin standard dye were deliberately mixed by ratios 100:0, 80:20, 60:40, 40:60, 20:80, and 0:100 to dye silk with a different pH of dyebath (7, 11) and different dyeing temperatures ($50^{\circ}C$, $70^{\circ}C$). The amount of indigotin and indirubin pigments in silk was calculated using regression equations obtained from standard calibration curves of indigotin and indirubin. A higher indigotin percent ratio resulted in the higher K/S values and the higher amount of indigotin detected from silk. However, higher indirubin percent ratio in the mixed dye did not relate to the higher indirubin pigment detected in silk. While indirubin showed low or negative contribution to the K/S values, it showed a higher effect on the color of dyed silk. Higher amounts of indirubin in dyed silk resulted in a darker PB color, which led to P color with increases in indirubin content.

• 한국의류학회지
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• 제32권7호
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• pp.1095-1103
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• 2008

The effects of resin finish and dyeabilities of four kinds of Iyocell fabrics that were manufactured by four kinds of pulps were investigated. The dyeabilities of Iyocell fabrics were similar, but differed from cotton fabric. In early stage of 30 minutes, cotton fabric was shown higher dye exhaustion ratio than Iyocell fabrics, however after then cotton fabric did not increase dye exhaustion, Iyocell fabrics increased continuously. At last, the dye exhaustion ratio of Iyocell fabrics were about 75% and that of cotton fabric was 65%. Two kinds of experimental procedures were applied for Iyocell fabrics. One was what the fabrics were treated with resins and washed with cellulase, and then dyed with reactive dyes. The other procedure was the fabrics were dyed with reactive dyes, and then applied the resin treatments and cellulase washing. After fibrillation and washing the undyed Iyocell fabric and the Iyocell fabric that was dyed with C.I.Reactive Red 120, their weight loss ratios were 3.5% and 2.8%, respectively. Dyeing with reactive dyes caused the crosslinking between cellulose and dyes and the crosslinking decreased fibrillation. The weight loss by enzyme washing of Iyocell fabrics decreased by the glyoxal and melamine resin treatments. The reduction of weight loss can be caused by fibrillation decrease. Dyeing and resin treating can be showed the synergic effect on the reduction of fibrillation. The effect of glyoxal resin on the reduction of fibrillation was a little better than that of melamine resin.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2007년도 추계학술발표회
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• pp.121-122
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• 2007