• 제목/요약/키워드: rate of resistance increase

검색결과 687건 처리시간 0.031초

수종 임플랜트 금속의 내식성에 관한 전기화학적 연구 (AN ELECTROCHEMICAL STUDY ON THE CORROSION RESISTANCE OF THE VARIOUS IMPLANT METALS)

  • 전진영;김영수
    • 대한치과보철학회지
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    • 제31권3호
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    • pp.423-446
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    • 1993
  • Titanium and its alloys are finding increasing use in medical devices and dental implants. The strong selling point of titanium is its resistance to the highly corrosive body fluids in which an implant must survive. This corrosion resistance is due to a tenacious passive oxide or film which exists on the metal's surface and renders it passive. Potentiodynamic polarization measurement is one of the most commonly used electro-chemical methods that have been applied to measure corrosion rates. And the potentiodynamic polarization test supplies detailed information such as open circuit, rupture, and passivation potential. Furthermore, it indicates the passive range and sensitivity to pitting corrosion. This study was designed to compare the corrosion resistance of the commonly used dental implant materials such as CP Ti, Ti-6A1-4V, Co-Cr-Mo alloy, and 316L stainless steel. And the effects of galvanic couples between titanium and the dental alloys were assessed for their useful-ness-as. materials for superstructure. The working electrode is the specimen , the reference electrode is a saturated calomel electrode (SCE), and the counter electrode is made of carbon. In $N_2-saturated$ 0.9% NaCl solutions, the potential scanning was performed starting from -800mV (SCE) and the scan rate was 1 mV/sec. At least three different polarization measurements were carried out for each material on separate specimen. The galvanic corrosion measurements were conducted in the zero-shunt ammeter with an implant supraconstruction surface ratio of 1:1. The contact current density was recorded over a 24-hour period. The results were as follows : 1. In potential-time curve, all specimens became increasingly more noble after immersion in the test solution and reached between -70mV and 50mV (SCE) respectively after 12 hours. 2. The Ti and Ti alloy in the saline solution were most resistant to corrosion. They showed the typical passive behavior which was exhibited over the entire experimental range. Therefore no breakdown potentials were observed. 3. Comparing the rupture potentials, Ti and Ti alloy had the high(:st value (because their break-down potentials were not observed in this study potential range ) followed by Co-Cr-Mo alloy and stainless steel (316L). So , the corrosion resistance of titanium was cecellent, Co-Cr-Mo alloy slightly inferior and stainless steel (316L) much less. 4. The contact current density sinks faster than any other galvanic couple in the case of Ti/gold alloy. 5. Ag-Pd alloy coupled with Ti yielded high current density in the early stage. Furthermore, Ti became anodic. 6. Ti/Ni-Cr alloy showed a relatively high galvanic current and a tendency to increase.

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Efficient Elimination of Tetracycline by Ferrate (VI): Real Water Implications

  • Levia Lalthazuala;Lalhmunsiama Lalhmunsiama;Ngainunsiami Ngainunsiami;Diwakar Tiwari;Seung Mok Lee;Suk Soon Choi
    • 공업화학
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    • 제34권3호
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    • pp.318-325
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    • 2023
  • The detection of antibiotics in treated wastewater is a global concern as it enters water bodies and causes the development of antibiotic resistance genes in humans and marine life. The study specifically aims to explore the potential of ferrate (VI) in eliminating tetracycline (TCL). The degradation of TCL is optimized with parametric studies, viz., the effect of pH and concentration, which provide insights into TCL elimination. The increase in pH (from 7.0 to 10.0) favors the percentage removal of TCL; however, the increase in TCL concentrations from 0.02 to 0.3 mmol/L caused a decrease in percentage TCL removal from 97.4 to 29.1%, respectively, at pH 10.0. The time-dependent elimination of TCL using ferrate (VI) followed pseudosecond-order rate kinetics, and an apparent rate constant (kapp) was found at 1978.8 L2 /mol2 /min. Coexisting ions, i.e., NaNO3, Na2HPO4, NaCl, and oxalic acid, negligibly affect the oxidation of TCL by ferrate (VI). However, EDTA and glycine significantly inhibited the elimination of TCL using ferrate (VI). The mineralization of TCL using ferrate (VI) was favored at higher pH, and it increased from 18.57 to 32.52% when the solution pH increased from pH 7.0 to 10.0. Additionally, the real water samples containing a relatively high level of inorganic carbon spiked with TCL revealed that ferrate (VI) performance in the removal of TCL was unaffected, which further inferred the potential of ferrate (VI) in real implications.

석유 팬 히터의 연소실 주변 열전달 특성 (Heat transfer characteristics around a circular combustion chamber of kerosene fan heater)

  • 김장권
    • 대한기계학회논문집B
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    • 제22권4호
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    • pp.551-561
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    • 1998
  • This paper was studied to understand the characteristics of heat transfer coefficients and surface temperature distributions around a circular combustion chamber within the heat-intercept duct of kerosene fan heater. The experiment was carried out in the heat-intercept duct of kerosene fan heater attached to the blow-down-type subsonic wind tunnel with a test section of 240 mm * 240 mm * 1200 mm. The purpose of this paper was to obtain the basic data related with normal combustion for new design from conventional kerosene fan heater, and to investigate the effect of surface temperature, local and mean heat transfer coefficients versus flow-rate of convection axial fan according to the variations of heat release conditions from kerosene fan heater during normal combustion. Consequently it was found that (i) the revolution of convection axial fan during combustion had a smaller value than that of non-combustion because of the thermal resistance due to the high temperature in the heat-intercept duct, (ii) the pressure ratio P$_{2}$/P$_{1}$ had a comparatively constant value of 0.844 according to the revolution increase of turbo fan and the heating performance of kerosene fan heater had a range of 1,494 ~ 3,852 kcal/hr, (iii) the local heat transfer coefficient around a circular combustion chamber had a comparatively larger scale in the range of 315 deg. < .theta. < 45 deg. than that in the range of 90 deg. < .theta. < 270 deg. as a result of heat transfer difference between front and back of a circular combustion chamber, and (iv) the mean heat transfer coefficient around a circular combustion chamber increased linearly like a H$_{m}$=95.196Q+104.019 in condition of high heat release according to the increase of flow-rate of axial fan.n.

용융염 LiCl 및 LiCl-$Li_2O$에서 내열합금 More 1과 Super 22H의 부식거동 (Corrosion Behavior of Heat-Resistant Alloys of More 1 and Super 22H in Molten Salt of LiCl and LiCl-$Li_2O$)

  • 조수행;박상철;장준선;신영준;박현수
    • 한국재료학회지
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    • 제9권6호
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    • pp.556-563
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    • 1999
  • The corrosion behavior of heat-resistant alloys, More 1 and Super 22H in molten salts of LiCl and $LiCl-Li_2$O was investigated in the temperature range of $650~850^{\circ}C$. In a molten salt of LiCl, a dense protective oxide scale of $LiCrO_2$ was formed, following growth of oxide scale with parabolic kinetics. But in a mixed molten salt of LiCl, a dense protective oxide scale of $LiCrO_2$ was formed, following growth of oxide scale with parabolic kinetics. But in a mixed molten salt of $LiCl-Li_2$O, a porous non-protective scale of Li\ulcorner(Cr, Ni, Fe)\ulcornerO$_2$was formed, following growth of oxide scale with linear kinetics. The corrosion rate increased slowly with the increase of temperature up to $750^{\circ}C$, but above $750^{\circ}C$ rapid increase in corrosion rate observed. The corrosion behavior of Super 22H alloy was similar to that of More 1 alloy, but Super 22H showed higher corrosion resistance than More 1.

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실선 시험에 의한 저층 트롤 어구에 관한 연구-II -어구의 수중 형태에 관하여- (A study on the bottom trawl gear by the trial of a stern trawler-II -On the net shape of a bottom trawl gear-)

  • 조봉곤;고광수
    • 수산해양기술연구
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    • 제36권4호
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    • pp.281-286
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    • 2000
  • 저층트롤 실물 어구를 이용한 해상 실험을 통하여 예망 중인 어구의 망구 형태에 관련되는 전개판의 간격 및 망고 등을 예망 속도별, 끌줄의 길이별로 측정하고, 이론적인 수치 해석 결과와 비교하여 실물어구의 수중 현황을 해석함으로서 어구의 효율적인 운용과 어획효과의 증대를 위한 기초자료를 제공하고자 한다. 수중 현황을 해석한 결과를 요약하면 다음과 같다. 1. 전개판의 전개간격은 예망 속도와 끌줄길이의 증가에 따라 직선적으로 증가하며 끌줄 길이에 의한 증가율이 예망 속도에 의한 증가율보다 현저히 크게 나타났으며, 그 간격의 변화는 57.0∼82.8m로서 후릿줄과 그물목줄 및 그물길이 전체의 43∼62%를 차지하였다. 2. 망구의 높이는 예망 속도와 끌줄길이의 증가에 따라 직선적으로 감소하며, 예망 속도에 의한 감소율이 끌줄 길이에 의한 감소율보다 현저히 크게 나타났는데 그 높이의 변화는 3.1∼4.0m로 나타났다. 3. 양 날개끝의 간격이 커지면 망고는 낮아지나 끌줄 길이가 증가할수록 날개 끝 간격의 증가에 대한 망구 높이 감소율의 비는 점차 작아졌다. 4. 망고에 대한 양 날개 끝 간격의 비는 예망속도와 끌줄 길이의 증가에 따라 점차 커졌는데, 그 비는 4.17∼7.81로 나타났다.

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토끼 동방결절 박동수에 대한 아데노신의 작용 (Inhibitory action of adenosine on sinus rate in isolated rabbit SA node)

  • 채헌;서경필;김기환
    • Journal of Chest Surgery
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    • 제16권2호
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    • pp.199-212
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    • 1983
  • The inhibition/influences of adenine compounds on the heart have been described repeatedly by many investigators, since the first report by Druny and Szent-Gyorgyi [1929]. These studies have shown that adenosine and adenine nucleotides have an over-all effect similar to that of acetylcholine [ACh] by slowing and weakening the heartbeat. The basic cellular and membrane events underlying the inhibitory action of adenosine on sinus rate, however, are not well understood. Furthermore, the physiological role of adenosine in regulation of the heartbeat remains still to be elucidated. Therefore, this study was undertaken in order to examine the response of rabbit SA node to adenosine and to compare the response to that of ACh. Isolated SA node preparation, whole atrial pair, or left atrlal strip was used in each experiment. Action potentials of SA node were recorded through the intracellular glass microelectrodes, which were filled with 3M KCI and had resistance of 30-50 M. All experiments were performed in a bicarbonate-buffered Tyrode solution which was aerated with 3% $CO_2-97%$ $O_2$ gas mixture and kept at $35^{\circ}C$. Spontaneous firing rate of SA node at 35C [Mean + SEM, n=16] was 154 + 3.3 beats/min. The parameters of action potentials were: maximum astolic potential [MDP], -731.7mV: overshoot [OS], 9 + 1.4mV; slope of pacemaker potential [SPP], 94 3.0mV/sec.Adenosine suppressed the firing rate of SA node in a dose dependent manner. This inhibitory effect appeared at the concentration of $10^{-6}M$ and was potentiated in parallel with the increase in adenosine concentration. Changes in action potential by adenosine were dose-dependent increase of MDP and decrease of SPP until $10^{-4}$. Above this concentration, however, the amplitude of action potential decreased markedly due to the simultaneous decrease of both MDP and OS. All these effects of adenosine were not affected by pretreatment of atropine [2mg/l] and propranolol [$5{\times}10^{-6}M$]. ACh [$10^{-6}M$] responses on action potential were similar to those of adenosine by increasing MDP and decreasing SPP. These effects of ACh disappeared by pretreatment of atropine [2mg/1]. Inhibition/effects of adenosine and ACh on sinus rate were enhanced synergistically with the simultaneous administration of adenosine and ACh. Marked decrease of overshoot potential was the most prominent feature on action potential. Dipyridamole [DPM], which is known to block the adenosine transport across cell membrane, definitely potentiated the action of adenosine . Adenosine suppressed the sinus rate and atrial contractility in the same dosage range, even in the reserpinized preparation. Above` results suggest that adenosine suppresses pacemaker activity, like ACh, by acting directly on the membrane of SA node, increasing MDP and decreasing SPP.

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건축물 구조체에 적용가능한 모르타르에 관한 실험적 연구 (An Experimental Study on Mortar to Apply Building Structure)

  • 권미옥;박흥이;권희성;김성진;임남기;정상진
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2008년도 춘계 학술논문 발표대회
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    • pp.83-86
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    • 2008
  • The concrete used most in construction materials. There is an overcrowded iron dimensions use of the concrete at time of the other concrete theory on the reinforcing rod back which did congestion and compares it with this, and there are more few dimensions of the aggregate than concrete, and quantity of aggregate passage is superior in mortar than concrete. If a volume rate of the aggregate writes mortar than concrete against this, therefore, unit amount increases, and quantity of paste increases and quantity of dry shrinkage than increase concrete. However, I let I regulate lay priest distribution of the aggregate, and the results rates increase and reduce unit amount and decrease quantity of dry shrinkage, and separation resistance and the gap passage characteristics are judged because it can be it in a substitute document of very superior concrete. I came to carry out the study that I watched to let I was useful a little more and do the improvement repair of a become building wall body, a basement pillar and repair reinforcement of the assistant in the reinforcing rod back, the old age when I made congestion here. I regulated lay priest distribution of the aggregate in the study and regulated substitution rate of the aggregate (40%, 50%, 60%) and divided W/C 30%, 40% standards and produced mortar and I compared quantity of air by this, slump, compression robbery and showed it this time.

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도열병 품종저항성과 도체내 성분과의 관계 (Relationship between some chemical components in the rice plants and varietal reaction to blast disease)

  • 백수봉
    • 한국응용곤충학회지
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    • 제9권1호
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    • pp.15-20
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    • 1970
  • 수도품종명 도열병 저항성 차이와 도체내 성분과의 관계를 구명코저 저항성 품종, 중간정도 품종, 감수성인 품종의 실소 및 당 함량을 비교한 결과를 요약하면 다음과 같다. 1) 전질소, 전당 함량은 저항성인 품종이 감수성인 품종에 비해 전질소는 적고 전당은 많았다. 따라서 C/N 률은 저항성 품종이 감수성인 품종에 비해 높았다. 2) Free amino acid에 있어서는 저항성인 품종이 감수성인 품종에 비해 Glutamine, Valine 그리고 Leucine 과 Iso-leucine함량이 많았다. 3) 각종당액에서 전분합성은 저항성인 품종이 감수성인 품종에 비해 Fructose, Glucose에서는 높았고 Sucrose에서는 낮았으나 Indica type로 저항성인 Zenith에서는 오히려 전분합성이 감수성인 다다조 보다 떨어졌다. 4) 질소비료를 증시하면 전질소함량은 보비보다 증가하는데 그 증가율은 저항성인 품종에서 낮은 경향이었다. 전당은 분벽초기에 감소되며 그 감소율은 저항성인 품종이 더 떨어졌고 분벽최성기에는 오히려 증가하였는데 그 증가율은 저항성인 품종이 높은 경향이었다.

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고밀집 Glassy Carbon 섬유 다발체 전극 전해계를 이용한 금속 이온의 in-situ 전해 역추출 특성 연구 (A Study on in-situ Electrolytic Stripping of a Metal Ion by Using a Highly Packed Glassy Carbon Fiber Column Electrode System)

  • 김광욱;김영환;이일희;유재형
    • 공업화학
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    • 제9권4호
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    • pp.475-480
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    • 1998
  • 본 연구에서는 고밀집 glassy carbon (GC) 섬유 다발체 전극 전해계를 사용하여 우라늄 (VI)를 함유한 유기상과 질산 수용상의 혼합상에서 전해 역추출시 우라늄 (VI) 환원 전해특성 연구가 수행되었고, 이에 관한 전해 역추출 모델을 제시하였다 우라늄 (VI) 전해환원 반응은 혼합상 내의 수용상에서 보다 혼합상 내의 유기상에서 빨리 일어났다. 유기상의 유속이 증가하는 경우 역추출 과정에서 유기상 내 우라늄 이온의 확산 저항 증가에 의해서 수용상으로의 역추출은 증가하다 일정하게 되었으며, 수용상 유속 변화는 총 우라늄 (VI) 환원전류에는 영향을 주지 않았다. 전해반응이 없는 경우보다 전해 반응이 동반되는 경우 우라늄 역추출이 보다 효과적으로 이루어 짐을 알 수 있었다.

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$CF_4$$O_2$를 이용한 저유전율 물질인 Methylsilsequioxane의 RIE와 MERIE 공정 (Reactive Ion Etching and Magnetically Enhanced Reactive Ion Etching Process of Low-K Methylsilsequioxane Insulator Film using $CF_4$ and $O_2$)

  • 정도현;이용수;이길헌;김광훈;이희우;최종선
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1491-1493
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    • 2000
  • Continuing improvement of microprocessor performance involves in the device size. This allow greater device speed, an increase in device packing density, and an increase in the number of functions that can reside on a single chip. However this has led to propagation delay, crosstalk noise, and power dissipation due to resistance-capacitance(RC) coupling become significant due to increased wiring capacitance, especially interline capacitance between the metal lines on the same metal level. So, MSSQ which has the permittivity between 2.5-3.2 is used to prevent from these problems. For pattering MSSQ(Methylsilsequioxane), we use RIE(Reactive Ion Etching) and MERIE(Magnetically enhanced Reactive Ion Etching) which could provide good anisotropic etching. In this study, we optimized the flow rate of $CF_{4}/O_2$ gas, RF power to obtain the best etching rate and roughness and also analyzed the etching result using $\alpha$-step profilemeter, SEM, infrared spectrum and AFM.

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