• Clean Technology
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• v.28 no.3
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• pp.238-248
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• 2022

The world is striving to transition to a carbon-neutral society. It is expected that using hydrogen instead of hydrocarbon fuel will contribute to this carbon neutrality. However, there is a need for combustion technology that controls the increased NOx emissions caused by hydrogen co-firing. Flameless combustion is one of the alternative technologies that resolves this problem. In this study, a numerical analysis was performed using the 1D opposed-flow diffusion flame model of Chemkin to analyze the characteristics of flameless combustion and the chemical reaction of methane-hydrogen fuel according to its hydrogen content and flue gas recirculation rate. In methane combustion, as the recirculation rate (K_v) increased, the temperature and heat release rate decreased due to an increase in inert gases. Also, increasing K_v from 2 to 3 achieved flameless combustion in which there was no endothermic region of heat release and the region of maximum heat release rate merged into one. In H₂ 100% at K_v 3, flameless combustion was achieved in terms of heat release, but it was difficult to determine whether flameless combustion was achieved in terms of flame structure. However, since the NOx formation of hydrogen flameless combustion was predicted to be similar to that of methane flameless combustion, complex considerations of flame structure, heat release, and NOx formation are needed to define hydrogen flameless combustion.

• Polymer(Korea)
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• v.25 no.6
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• pp.884-892
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• 2001

Biodegradable wafers were prepared with poly (L-lactide-co-glycolide) (50 : 50 mole ratio of lactide to glycolide, molecular weight:5000 g/mole) by direct compression method for the sustained release of nifedipine to investigate the possibility of the treatment of hypertension. PLGA wafers were prepared by altering initial drug/polymer loading ratio, wafer thickness, and hydroxypropyl methylcellulose (HPMC) content. These wafers showed new zero-order release patterns for 11 days, and various biphasic release patterns could be obtained by altering the composition of wafers such as addition of matrix binder as HPMC to the PLGA wafer to reduce release rate of initial phase. The onset of polymer mass loss only occured after 4 days and about 40% of mass loss was observed after 11 days nifedipine release. This system had advantages in terms of simplicity in design and obviousness of drug release rate and may be useful as an implantable dosage form.

• Journal of the Korean Society of Combustion
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• v.13 no.2
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• pp.14-22
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• 2008

The CH* chemiluminescence of premixed flames and their dependency on fuel types has been experimentally investigated on laminar methane and propane premixed flames. The measured chemiluminescence intensities are observed linearly proportional to the fuel flow rate, which could be interpreted as the CH* chemiluminescence signal is linearly proportional to the heat release rate under fuel lean conditions. The effect of equivalence ratio could be expressed by an exponential function as ${I_{CH*}}^{\propto}\;a_1\;{\exp}(b_1{\Phi})$, where $a_1\;=\;0.00054$ and $b_1\;=\;4.60$ for methane and $a_1\;=\;0.0056$ and $b_1\;=\;5.02$ for propane. Oscillating flames showed the temporal fluctuation of chemiluminescence intensity: however, the time averaged values are virtually identical to those of quiescent flames under the same fuel flow rate and equivalence ratio conditions. This observation suggests that there is no significant flame stretch effect on chemiluminescence intensity, in average values.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.8
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• pp.1183-1194
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• 1998

This paper describes a theoretical model developed for analyzing the heat transfer of automotive cooling systems. From the model, heat transfer rate of automotive cooling systems can be predicted, providing useful information at the early stages of the design and development. The aim of the study is to develop a simulation program for automotive cooling system analysis and a performance analysis program for analyzing heat exchanger. Heat release rate from combustion gas to coolant through cylinder wall in engine cylinder was analyzed by using a two zone combustion model. This paper studied how cooling condition would affect engine heat release rate and measured temperature distribution of coolant in water jacket.

• Proceedings of the KSR Conference
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• 2005.11a
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• pp.935-940
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• 2005

We generally get the Heat Release Rate by two other method. One is the calculation method from the Oxygen consumption rate and another is the calibration curve method of Temperature rising rate. In this study we compare the results of both test methods with five same specimens. From the test result we get the difference of reproducibility and checked some reasons of the difference. This paper includes some points to be careful for more creditable results for each test method.

• Journal of Pharmaceutical Investigation
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• v.17 no.3
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• pp.111-126
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• 1987

Methyl methacrylate-butyl methacrylate copolymer (MMBM)-dibutyl phthalate (DBP) films were investigated as a potential topical drug delivery system for the controlled release of nitrofurazone. The kinetic analysis of release data indicated that drug release followed a diffusion-controlled granular matrix model, where the quantity released per unit area is proportional to the square root of time. DBP of several hydrophobic plasticizers selected was found to give the highest release of nitrofurazone. However, hydrophilic plasticizers such as propylene glycol and polyethylene glycol 400 had no controlled release properties and acceptable film formation. The effects of changes in film composition, drug concentration, film thickness, pH of release medium, and temperature on the in vitro release of nitrofurazone were analyzed both theoretically and experimentally. The release rate constant (k') was found to be proportional to DBP content, pH, and the temperature of release medium, but independent of film thickness, and drug concentration in a range of 0.1-0.4% by weight. The linear relationship was found to exist between the log k' and DBP content. The release of nitrofurazone from MMBM-DBP (8:2) films was found to be an energy-linked process. Two energy terms were calculated ; the activation energy for matrix diffusion was 13.45 kcal/mole, and the heat of drug crystal solvation was 27.26-29.34 kcal/mole. Observation of scanning electron micrographs and microscopic photographs showed that the incorporation of DBP in films increased markedly the particle size of nitrofurazone dispersed in the film matrix, comparing with the fine dispersion of nitrofurazone in pure MMBM film alone.

• Bulletin of the Korean Chemical Society
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• v.23 no.11
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• pp.1579-1584
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• 2002

Since surfactant or emulsifiers remained on the nanoparticle surface significantly affect the physicochemical properties, the biodegradation rate, the biodistribution, and the biocompatibility of nanoparticles, surfactant-free nanoparticles should be good candidate. surfactant-free PLGA nanoparticles were successfully prepared by both the dialysis method and the solvent diffusion method. The PLGA nanoparticles prepared using the solvent diffusion method has a smaller particle size than the dialysis method. The solvent diffusion method was better for a higher loading efficiency than the dialysis method but the nanoparticle yield was lower. Testosterone (TST) release from the PLGA nanoparticles was dependent on the particle size rather than the drug contents. Testosterone release from the PLGA nanoparticles prepared by the solvent diffusion method using acetone was faster than those prepared by the dialysis method. TST release from the PLGA nanoparticles prepared by the solvent diffusion method using acetone and the dialysis method using dimethylformamide (DMF) was completed for 4 days while the PLGA nanoparticles prepared by the dialysis method using acetone showed approximately 80% TST release after 4 days. Since the PLGA nanoparticle degradation ratio was below 20% within 5 days at all samples while TST release completed within 4 days, TST release was dependent on the diffusion mechanism rather than degradation.

• Proceedings of the Korean Nuclear Society Conference
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• 1995.05a
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• pp.707-712
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• 1995

Grain boundary diffusion plays significant role in the fission gas release, which is one of the crucial processes dominating nuclear fuel performance. Gaseous fission products such as Xe and Kr generated inside fuel pellet have to diffuse in the lattice and in the grain boundary before they reach open space in the fuel rod. In the mean time, the grains in the fuel pellet grow and shrink according to grain growth kinetics, especially at elevated temperature at which nuclear reactors are operating. Thus the boundary movement ascribed to the grain growth greatly influences the fission gas release rate by lengthening or shortening the lattice diffusion distance, which is the rate limiting step. Sweeping fission gases by the moving boundary contributes to the increment of the fission gas release as well. Lattice and grain boundary diffusion processes in the fission gas release can be studied by 'tracer diffusion' technique, by which grain boundary diffusion can be estimated and used directly for low burn-up fission gas release analysis. However, even for tracer diffusion analysis, taking both the intragranular grain growth and the diffusion processes simultaneously into consideration is not easy. Only a few models accounting for the both processes are available and mostly handle them numerically. Numerical solutions are limited in the practical use. Here in this paper, an approximate analytical solution of the lattice and stationary grain boundary diffusion in a polycrystalline solid is developed for the tracer diffusion techniques. This short closed-form solution is compared to available exact and numerical solutions and turns out to be acceptably accurate. It can be applied to the theoretical modeling and the experimental analysis, especially PIE (post irradiation examination), of low burn up fission. gas release.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.7
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• pp.1433-1438
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• 2009

The purpose of this study is to investigate how the ignition spark timing conversion influences the engine performance of LPG/Gasoline Bi-Fuel engine. We propose the control system which can advance the ignition spark timing in LPG fuel mode more than used in gasoline fuel mode. In order to investigate the engine performance during combustion, engine performance are sampled by data acquisition system, for example cylinder pressure, pressure rise rate and heat release rate, while change of the rpm(1500, 2000) and the ignition timing advance($5^{\circ}$,$10^{\circ}$,$15^{\circ}$,$20^{\circ}$) As the result, between 1500rpm and 2000rpm, the cylinder pressure and pressure rise rate was increased when the spark ignition was advanced but pressure rise rate at $20^{\circ}$was smaller value. Also, the heat release rate at 1500rpm was increased but it was lower around $20^{\circ}$at 2000rpm.

• Structural Engineering and Mechanics
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• v.71 no.2
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• pp.153-163
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• 2019

Longitudinal fracture behavior of non-linear elastic beam configurations is studied in terms of the strain energy release rate. It is assumed that the beams exhibit continuous material inhomogeneity along the width as well as along the height of the crosssection. The Ramberg-Osgood stress-strain relation is used for describing the non-linear mechanical behavior of the inhomogeneous material. A solution to strain energy release rate is derived that holds for inhomogeneous beams of arbitrary cross-section under combination of axial force and bending moments. Besides, the solution may be applied at any law of continuous distribution of the modulus of elasticity in the beam cross-section. The longitudinal crack may be located arbitrary along the beam height. The solution is used to investigate a longitudinal crack in a beam configuration of rectangular cross-section under four-point bending. The crack is located symmetrically with respect to the beam mid-span. It is assumed that the modulus of elasticity varies continuously according a cosine law in the beam cross-section. The longitudinal fracture behavior of the inhomogeneous beam is studied also by applying the J-integral approach for verification of the non-linear solution to the strain energy release rate derived in the present paper. Effects of material inhomogeneity, crack location along the beam height and non-linear mechanical behavior of the material on the longitudinal fracture behavior are evaluated. Thus, the solution derived in the present paper can be used in engineering design of inhomogeneous non-linear elastic structural members to assess the influence of various material and geometrical parameters on longitudinal fracture.