• Title/Summary/Keyword: rate of release

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Numerical Analysis of Effect of Inhomogeneous Pre-mixture on Pressure Rise Rate in HCCI Engine by Using Multizone Chemical Kinetics (화학반응수치해석을 이용한 HCCI기관의 예혼합기의 성층화성이 연소시의 압력 상승률에 미치는 영향)

  • Lim, Ock-Taeck
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.5
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    • pp.449-456
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    • 2010
  • The HCCI engine is a prospective internal combustion engine with which high diesel-like efficiencies and very low NOx and particulate emissions can be achieved. However, several technical issues must be resolved before HCCI engines can be used for different applications. One of the issues concerning the HCCI engine is that the operating range of this engine is limited by the rapid pressure rise caused by the release of excessive heat. This heat release is because of the self-accelerated combustion reaction occurring in the engine and the resulting engine knock in the high-load region. The purpose of this study is to evaluate the role of thermal stratification and fuel stratification in reducing the pressure rise rate in an HCCI engine. The concentrations of NOx and CO in the exhaust gas are also evaluated to confirm combustion completeness and NOx emission. The computation is carried out with the help of a multizone code, by using the information on the detailed chemical kinetics and the effect of thermal and fuel stratification on the onset of ignition and rate of combustion. The engine is fueled with dimethyl ether (DME), which allows heat release to occur in two stages, as opposed to methane, which allows for heat release in a single stage.

Hazard Distance from Hydrogen Accidents (수소가스사고의 피해범위)

  • Jo, Young-Do
    • Journal of the Korean Institute of Gas
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    • v.16 no.1
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    • pp.15-21
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    • 2012
  • An analysis was completed of the hazards distance of hydrogen accidents such as jet release, jet fire, and vapor cloud explosion(VCE) of hydrogen gas, and simplified equations have been proposed to predict the hazard distances to set up safety distance by the gas dispersion, fire, and explosion following hydrogen gas release. For a small release rate of hydrogen gas, such as from a pine-hole, the hazard distance from jet dispersion is longer than that from jet fire. The hazard distance is directly proportional to the pressure raised to a half power and to the diameter of hole and up to several tens meters. For a large release rate, such as from full bore rupture of a pipeline or a large hole of storage vessel, the hazard distance from a large jet fire is longer than that from unconfined vapor cloud explosion. The hazard distance from the fire may be up to several hundred meters. Hydrogen filling station in urban area is difficult to compliance with the safety distance criterion, if the accident scenario of large hydrogen gas release is basis for setting up the safety distance, which is minimum separation distance between the station and building. Therefore, the accident of large hydrogen gas release must be prevented by using safety devices and the safety distance may be set based on the small release rate of hydrogen gas. But if there are any possibility of large release, populated building, such as school, hospital etc, should be separated several hundred meters.

A Study on Critical Strain Energy Release Rate Mode II of Chemically Treated SiC-filled Epoxy Composites (표면처리된 탄화규소강화 에폭시 복합재료의 GIIC 특성)

  • Park, Soo-Jin;Oh, Jin-Seok
    • Journal of Adhesion and Interface
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    • v.6 no.4
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    • pp.1-6
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    • 2005
  • In this work, the effect of chemical treatments on surface properties of SiC was investigated in crack resistance properties of SiC/epoxy composites. The surface properties of SiC were determined by acid/base values and FT-IR measurements. Also the crack resistance properties of the composites were studied in critical strain energy release rate mode II ($G_{IIC}$) measurements. As a result, the acidically treated SiC had higher acid value than that of untreated SiC or basically treated SiC. The crack resistance properties of the composites had been improved in the specimens treated by acidic solution. These results were could be attributed to the acide-base intermolecular interaction between SiC and epoxy resin, resulting in increase of the degree of adhesion at interfaces.

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A Study on the Fire Hazard of Transportation Oil (수송기관용 오일의 화재위험성에 관한 연구)

  • Park, Young Ju;Hwang, Me Jung;Lee, Hae Pyeong;Lee, Seung Chul;Lee, Chang Hyun
    • Journal of the Korean Society of Safety
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    • v.29 no.3
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    • pp.114-120
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    • 2014
  • The purpose of this study is to conduct the study of the combustion and thermal characteristics through transportation oil for the analysis of fire hazard. Transportation oil breaks down into fuels such as diesel for civilian demands, gasoline, DF1(diesel for military), high sulfur diesel(for marine), kerosene and JP1(for aviation), and lubricants like brake fluid, power steering oil, engine oil, and automatic and manual transmission oil. The experiments of flash point, ignition point, flame duration time, heat release rate were carried out using TAG closed cup flash point tester(AFP761), Cleveland open cup auto flash point analyzer(AFP762), KRS-RG-9000 and Dual cone calorimeter. As a result, the fuel's ignition points were lower than lubricants, especially that of gasoline was not conducted as it has below zero one. Gasoline has the highest ignition point of about $600^{\circ}C$, while the other fuels showed $400{\sim}465^{\circ}C$. For flame duration time, lubricants had over 300 seconds, but fuels had less than 300 seconds except high sulfur diesel(350 seconds). Total heat release rate ranged $287{\sim}462kW/m^2$ for lubricants and gasoline showed the highest total heat release rate, $652kW/m^2$.

Analytical Study on Interface Debonding of Reinforced Concrete Beams Strengthened with Carbon Fiber Sheet(CFS) (탄소섬유쉬트로 보강된 철근콘크리트보의 계면박리에 대한 해석적 연구)

  • Sim, Jong-Sung;Bae, In-Hwan
    • Magazine of the Korea Concrete Institute
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    • v.11 no.2
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    • pp.177-186
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    • 1999
  • The purpose of this study is to analyze the interface debonding of RC beams strengthened by carbon fiber sheet(CFS). The behavior of damaged RC beams strengthened with CFS is analytically investigated next using linear elastic fracture mechanics(LEFM) approach and the finite element method. The study includes an investigation of the separation mode by interface fracture of the strengthening materials due to the interfacial shear and normal stresses. The numerical method is presented to obtain the value of interfacial fracture parameter such as the strain energy release rate. Based on the results of this study, it is found that the critical case occurs when the interfacial cracks occur within a short region of the flexural crack. The CFS strengthening has not an adequate factor of safety against interfacial debonding of CFS. Furthermore, for the thicknesses of the adhesive studied[1mm~3mm], it is no noticeable effect on the strain energy release rate.

A Study on Fire Characteristics of Sofa Cover Materials (소파커버의 연소특성에 관한 연구)

  • 이광흠;박영근;윤명오;현성호;김동일
    • Fire Science and Engineering
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    • v.17 no.2
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    • pp.35-42
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    • 2003
  • In this study, we tried to evaluate the ignitibility, flammability, heat release rate, and toxicity of five different types of burning artificial leather sofa covers that are widely used in entertainment service industry buildings. As the results of this study, putting the artificial leathers under fire conditions we found out following results auto-ignition temperature was$ 427~437^{\circ}C$, limiting oxygen index was 19~20%; at heat flux of $25 kW\m^2$, ignition time was 10~16s and peak heat release rate was $147~277 kW\m^2$; and at heat flux of$ 35 kW\m^2$, ignition time was 6~9s and peak heat release rate was $176~296 kW\m^2$. The toxic materials discharged from the burning leathers were 5,550~6,290 ppm of CO, 18,500~23,400 ppm of $CO_2$, 110~140 ppm, of HCl, 13~65 ppm of HCN and 145~220 ppm of NOx.

Effect of $K^+-channel$ Blockers on the Muscarinic- and $A_1-adenosine-Receptor$ Coupled Regulation of Electrically Evoked Acetylcholine Release in the Rat Hippocampus

  • Yu, Byung-Sik;Kim, Do-Kyung;Choi, Bong-Kyu
    • The Korean Journal of Physiology and Pharmacology
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    • v.2 no.2
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    • pp.147-154
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    • 1998
  • It was attempted to clarify the participation of $K^+-channels$ in the post-receptor mechanisms of the muscarinic and $A_1-adenosine$ receptor- mediated control of acetylcholine (ACh) release in the present study. Slices from the rat hippocampus were equilibrated with $[^3H]$choline and the release of the labelled products was evoked by electrical stimulation (3 Hz, 5 V/cm, 2 ms, rectangular pulses), and the influence of various agents on the evoked tritium-outflow was investigated. Oxotremorine (Oxo, $0.1{\sim}10\;{\mu}M$), a muscarinic agonist, and $N^6-cyclopentyladenosine$ (CPA, $1{\sim}30\;{\mu}M$), a specific $A_1-adenosine$ agonist, decreased the ACh release in a dose-dependent manner, without affecting the basal rate of release. 4-aminopyridine (4AP), a specific A-type $K^+-channel$ blocker ($1{\sim}100\;{\mu}M$), increased the evoked ACh release in a dose-related fashion, and the basal rate of release is increased by 3 and $100\;{\mu}M$. Tetraethylammonium (TEA), a non-specific $K^+-channel$ blocker ($0.1{\sim}10\;{\mu}M$), increased the evoked ACh release in a dose-dependent manner without affecting the basal release. The effects of Oxo and CPA were not affected by $3\;{\mu}M$ 4AP co-treatment, but 10 mM TEA significantly inhibited the effects of Oxo and CPA. 4AP ($10\;{\mu}M$)- and TEA (10 mM)-induced increments of evoked ACh release were completely abolished in Ca^{2+}-free$ medium, but these were recoverd in low Ca^{2+}$ medium. And the effects of $K^+-channel$ blockers in low Ca^{2+}$ medium were inhibited by $Mg^{2+}$ (4 mM) and abolished by $0.3\;{\mu}M$ tetrodotoxin (TTX). These results suggest that the changes in TEA-sensitive potassium channel permeability and the consequent limitation of Ca^{2+}$ influx are partly involved in the presynaptic modulation of the evoked ACh-release by muscarinic and $A_1-adenosine$ receptors of the rat hippocampus.

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Improved Dissolution of Poorly Water Soluble TD49, a Novel Algicidal Agent, via the Preparation of Solid Dispersion

  • Lee, Hyoung-Kyu;Cho, Hoon;Han, Hyo-Kyung
    • Journal of Pharmaceutical Investigation
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    • v.40 no.3
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    • pp.181-185
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    • 2010
  • The objective of this study was to improve the extent of drug release as well as the dissolution rate of TD49, a novel algicidal agent, via the preparation of solid dispersion (SD). Among the various carriers tested, $Solutol^{(R)}$ HS15 was most effective to enhance the solubility of TD49. Subsequently, SDs of TD49 were prepared by using $Solutol^{(R)}$ HS15 and their solubility, dissolution characteristics and drug crystallinity were examined at various drug-carrier ratios. Solubili ty of TD49 was increased significantly in accordance with increasing the ratio of $Solutol^{(R)}$ HS15 in SDs. Compared to untreated powders and physical mixtures (PMs), SDs facilitated the faster and greater extent of drug release in water. Particularly, SD having the drug-carrier ratio of 1:20 exhibited approximately 90% of drug release within 1 hr. Differential scanning calorimetry (DSC) thermograms and X-ray diffraction (XRD) patterns suggested that SDs might enhance the dissolution of TD49 by changing the drug crystallinity to an amorphous form in addition to the increased solubilization of drug in the presence of $Solutol^{(R)}$ HS15. In conclusion, SD using $Solutol^{(R)}$ HS15 appeared to be effective to improve the extent of drug release and the dissolution rate of poorly water soluble TD49.

In Vitro Percutaneous Absorption of Ondansetron Hydrochloride from Pressure-sensitive Adhesive Matrices through Hairless Mouse Skin

  • Gwak, Hye-Sun;Oh, Ik-Sang;Chun, In-Koo
    • Archives of Pharmacal Research
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    • v.26 no.8
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    • pp.644-648
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    • 2003
  • To investigate the feasibility of developing a new ondansetron transdermal system, the effects of vehicles and penetration enhancers on the in vitro permeation of ondansetron hydrochloride (OS) from a pressure-sensitive adhesive (PSA) matrices across dorsal hairless mouse skin were studied. Vehicles employed in this study consisted of various ratios of propylene glycol monocaprylate (PGMC)-diethylene glycol monoethyl ether (DGME) co-solvents and PGMC-propylene glycol (PG) co-solvents with 3% oleic acid. $Duro-Tak^\circledR$ 87-2100 and $Duro-Tak^\circledR$ 87-2196 were used as PSAs. The concentration of DGME in PGMC-DGME co-solvent system affected the release rate; as the concentration of DGME increased, the release rate decreased. The cumulative release amount of OS increased as the ratio of PSA to drug solution decreased. The permeation flux was also primarily affected by the amount of PSAs; as the amount decreased, the permeation flux increased. The overall fluxes from matrix formulations were significantly lower when compared to those obtained from solution formulations. The ratio of PG to PGMC did not affect permeation flux, while the lag time decreased significantly from $5.14\pm3.31 to 0.31\pm0.12$ h as the PG increased from 40% to 60%.

Study on Mechanism of Combustion Instability in a Dump Gas Turbine Combustor (모형가스터빈 연소기내 연소불안정성에 대한 연구)

  • Lee, Jong-Ho;Lee, Yeon-Ju;Jeon, Chung-Hwan;Jang, Yeong-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.9
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    • pp.1284-1291
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    • 2002
  • Combustion instabilities are an important concern associated with lean premixed combustion. Laboratory-scale dump combustor was used to understand the underlying mechanisms causing combustion instabilities. Experiments were conducted at atmospheric pressure and sound level meter was used to track the pressure fluctuations inside the combustor. Instability maps and phase-resolved OH chemiluminescence images were obtained at several conditions to investigate the mechanism of combustion instability and relations between pressure wave and heat release rate. It showed that combustion instability was susceptible to occur at higher value of equivalence ratio (>0.6) as the mean velocity was decreased. Instabilities exhibited a longitudinal mode with a dominant frequency of ∼341.8 Hz, which corresponded to a quarter wave mode of combustor. Heat release and pressure waves were in-phase when instabilities occurred. Rayleigh index distribution gave a hint about the location where the strong coherence of pressure and heat release existed. These results also give an insight to the control scheme of combustion instabilities. Emission test revealed that NOx emissions were affected by not only equivalence ratio but also combustion instability.