• 제목/요약/키워드: rate constant(k)

검색결과 3,147건 처리시간 0.033초

부피법 자동장치를 이용한 유사 일정 압력에서 Mg의 수소 흡수 및 방출 반응에 대한 연구 (The Study of the Hydrogen Absorption and Desorption Reactions of Mg under Near Constant Pressure Using the Sievert's Type Automatic Apparatus)

  • 한정섭;김선중
    • 한국수소및신에너지학회논문집
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    • 제30권1호
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    • pp.8-13
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    • 2019
  • In order to apply the Sievert's type automatic apparatus to thermal analysis of hydrogen absorbing materials, the Sievert's type automatic apparatus was modified in my laboratory. In this study, an experiment was conducted to see if hydrogen absorption and desorption reactions are possible under near constant pressure (${\pm}0.05atm$) using this device. The hydrogenation and dehydrogenation of the Mg-H system was investigated. And the program was also modified for the kinetics. It was found that it is possible to measure the hydrogen absorption rate under near constant pressure of Mg by using the modified Sievert's type automatic apparatus at 573 K and 598 K. And using this system, the hydrogen desorption rate of Mg hydride under near constant pressure at 623 K was also measurable. However, since the hydrogen desorption rate of Mg hydride is fast at 648 K, the hydrogen desorption reaction did not proceed within a constant pressure range of $0.15{\pm}0.05atm$.

동적인 고정 및 가변 전송을 서비스를 위한 다중 서비스 네트워크 스위치의 성능 분석 (Performance Evaluation of Multiservice Network Switch for Dynamic Constant-and Adaptive-rate Services)

  • 이태진
    • 정보처리학회논문지C
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    • 제9C권3호
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    • pp.399-406
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    • 2002
  • 본 논문에서는 고정 전송율 서비스 및 가변 전송율 서비스 호들이 동적으로 네트워크에 들어와서 데이터를 전송하고, 데이터를 모두 전송하면 네트워크에서 사라지는 동적인 다중 서비스 네트워크에서, 고정 전송율 및 가변 전송율 서비스의 요구 성능을 만족하기 위한 네트워크 스위치(링크)의 성능 분석 및 설계 방법을 제안한다. 먼저 동적인 다중 서비스 네트워크의 링크를 Harkov 체인을 이용해 모델하고, QBD (Quasi-Birth-Death) 프로세스와 행렬 방정식을 이용해 가변 전송율 서비스의 호들에 할당될 전송율의 성능을 구한다. 즉, 가변 전송율 서비스의 평균 호수를 추정하고 이를 바탕으로, 호당 평균 전송율 및 평균 전송 지연 시간을 구한다. 고정 전송율 서비스의 성능은 고정 전송율 서비스 호들의 차단 확률(blocking probability)로 구해진다. 이렇게 해서 구해진 고정 전송율 및 가변 전송율 서비스의 성능을 이용해서, 고정 전송율 및 가변 전송율 서비스 호들의 요구 성능(전송율, 전송 지연 시간, 호의 차단 확률 등)을 만족하기 위한 네트워크 링크의 용량을 설계하는 방법을 제안한다. 이러한 방법을 데이터 및 음성(비디오)을 동시에 지원하는 네트워크 스위치의 성능 분석 및 용량 설계에 이용할 수 있다.

Experimental Study on Single Bubble Growth Under Subcooled, Saturated, and Superheated Nucleate Pool Boiling

  • Kim Jeong-Bae;Lee Jang-Ho;Kim Moo-Hwan
    • Journal of Mechanical Science and Technology
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    • 제20권5호
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    • pp.692-709
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    • 2006
  • Nucleate pool boiling experiments with constant wall temperature were performed using pure R1l3 for subcooled, saturated, and superheated pool conditions. A microscale heater array and Wheatstone bridge circuits were used to maintain the constant wall temperature and to measure the instantaneous heat flow rate accurately with high temporal and spatial resolutions. Images of bubble growth were taken at 5,000 frames per second using a high-speed CCD camera synchronized with the heat flow rate measurements. The bubble geometry was obtained from the captured bubble images. The effect of the pool conditions on the bubble growth behavior was analyzed using dimensionless parameters for the initial and thermal growth regions. The effect of the pool conditions on the heat flow rate behavior was also examined. This study will provide good experimental data with precise constant wall temperature boundary condition for such works.

온라인 서명 검증을 위한 SVM의 커널 함수와 결정 계수 선택 (Selection of Kernels and its Parameters in Applying SVM to ASV)

  • 판윈허;우영운;김성훈
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2015년도 추계학술대회
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    • pp.1045-1046
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    • 2015
  • When using the Support Vector Machine in the online signature verification, SVM kernel function should be chosen to use non-linear SVM and the constant parameters in the kernel functions should be adjusted to appropriate values to reduce the error rate of signature verification. Non-linear SVM which is built on a strong mathematical basis shows better performance of classification with the higher discrimination power. However, choosing the kernel function and adjusting constant parameter values depend on the heuristics of the problem domain. In the signature verification, this paper deals with the problems of selecting the correct kernel function and constant parameters' values, and shows the kernel function and coefficient parameter's values with the minimum error rate. As a result of this research, we expect the average error rate to be less than 1%.

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N,N-dimethylaniline에 의한 Coumarin 색소분자의 형광 소광 (Fluorescence Quenching of Coumarin Laser Dyes by N,N-dimethylaniline)

  • 박국희;강태종
    • 대한화학회지
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    • 제42권1호
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    • pp.22-27
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    • 1998
  • 여러 가지 용매에서 N,N-dimethylaniline에 의한 coumarin 153과 coumarin 481분자의 형광소광효과를 조사하였다. 소광속도상수와 분자의 확산속도상수간의 관계로부터 소광과정이 분자의 확산과 어느정도 상호연관성을 갖고 있음을 알 수 있었다. slip boundary조건 보다stick boundary 조건을 적용하였을 때 분자확산 속도상수와 실험적인 소광속도상수와의 차이가 작게 나타났다. cyclohexane 과 같은 비극성용매에서의 소광속도 상수는 이론적인 확산속도상수 값과 오차범위 내에서 거의 일치하였으나 acetonitrile과 같은 극성용매에서는 소광속도상수는 확산속도상수보다 일관되게 작게 나타났다. 이것은 coumarin 분자의 형광소광이 분자간 확산에 의한 충돌 뿐만 아니라 분자내 전하분리와 같은 과정에 의해서도 진행되는 것으로 해석할 수 있다.

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Estimation of Nitrogen Dioxide Source Generation and Ventilation Rate in Residence Using Multiple Measurements in Korea

  • Chung, Moon-Ho;Yang, Won-Ho
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2004년도 International Conference Current Challenges and Advances in Environmental Health
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    • pp.45-50
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    • 2004
  • Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Alt hough technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Daily indoor and outdoor NO2 concentrations were measured for 30 consecutive days in 28 houses in Brisbane, Australia, and for 21 consecutive days in 37 houses in Seoul, Korea. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and NO2 source strength were estimated. Geometric means of ventilation rate were 1.44 ACH in Brisbane, assuming a residential NO2 deposition constant of 1.05 hr-1, and 1.36 ACH in Seoul, with the measured residential NO2 deposition constant of 0.94 hr-1. Source strengths of N02 were 15.8 ${\pm}$ 18.2 ${\mu}$g/m3${\cdot}$hr and 44.7 ${\pm}$ 38.1 ${\mu}$g/m3${\cdot}$hr in Brisbane and Seoul, respectively. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

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시판 아스피린 정제의 생체내 이용율 (Bioavailability of Commercially Available Aspirin Tablets in Human)

  • 이진환;최준식;백채선;범진필
    • Journal of Pharmaceutical Investigation
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    • 제19권3호
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    • pp.131-136
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    • 1989
  • This study was attempted to investigate the dissolution rate and the bioavailability after oral administration of commercially available aspirin tablets in normal volunteers. The dissolution test was conducted in artificial gastric juice using basket method with three aspirin preparations (A, B and C) which were chemically equivalent. The results were as follows; The dissolution rate was higher in the order of three different brand B>A >C. Area under the blood concentration and peak blood concentration were larger in the order of brand A>B>C. Absorption rate constant and peak time were larger in the order of brand B>A>C, and there was a little difference in elimination rate constant and biological half-life. The correlation of the dissolution rate and absorption rate constant, as well as correlation of the dissolution rate and peak time showed significant linear relationship respectively. From the results of this experiment, it can be concluded that the bioavailability of aspirin tablets showed much difference according to commercial preparations, and that the bioavailability of aspirin tablets in human may be predicted from the results of dissolution rate studies.

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주택 실내.외 이산화질소 측정을 이용한 환기량 및 발생량 추정 (Estimation of Ventilation and Generation Rates Using Nitrogen Dioxide Measurements of Indoor and Outdoor in Houses)

  • 양원호;임성국;손부순
    • 한국환경과학회지
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    • 제17권10호
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    • pp.1069-1073
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    • 2008
  • Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Although technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and $NO_2$ generation rate were estimated. Mean of ventilation rate was 1.41 ACH in houses, assuming a residential N02 deposition constant of 0.94 $hr^{-1}$. Mean generation rate of $NO_2$ was 16.5 ppbv/hr. According to house characterization, inside smoking and family number were higher $NO_2$ generation rates, and apartment was higher than single-family house. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

광산화 및 광촉매 공정에서 VOCs의 산화반응 속도 산출에 관한 연구 (A Study on the reaction rate constant by UV Photooxidation and Photo-catalytic oxidation process)

  • 정창훈;이경호
    • 한국환경과학회지
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    • 제13권1호
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    • pp.37-40
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    • 2004
  • In this study, the decomposition of gas-phase TCE, Benzene and Toluene, in air streams by direct UV Photolysis and UV/TiO$_2$ process was studied. For direct UV Photolysis, by regressing with computer calculation to the experimental results the value of reaction rate constant k of TCE, Toluene and Benzene in this work were determined to be 0.00392s$\^$-l/, 0.00230s$\^$-1/ and 0.00126s$\^$-1/, respectively. And the adsorption constant K of TCE, Toluene and Benzene in this work were determined to be 0.0519 mol$\^$-l/ ,0.0313mo1$\^$-1/ and 0.0084mo1$\^$-1/, respectively. For UV/TiO$_2$ system by regressing with computer calculation to the experimental results the value of reaction rate constant k of TCE, Toluene, and Benzene in this work were determined to be 5.74g/$\ell$$.$min, 3.85g/$\ell$$.$min, and 1.18g/$\ell$$.$min, respectively. And the catalyst adsorption constant K of TCE, Toluene, and Benzene in this work were determined to be 0.0005㎥/mg, 0.0043㎥/mg and 0.0048㎥/mg, respectively.