• 제목/요약/키워드: rate constant(k)

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제하-재재하 시 CRS 압밀 시험의 최적 변형률 속도 (Optimal Strain Rate of Unloading-Reloading Cycle in Constant Rate of Strain Consoildation Test)

  • 박가현;윤찬영;정충기
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 추계 학술발표회
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    • pp.1156-1167
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    • 2010
  • The constant rate of strain (CRS) consolidation test has been widely used to evaluate consolidation characteristics of soils instead of the standard Incremental Loading Test. In practical problems, after the ground improvement, the condition of the soil is over-consolidated. Therefore, it is important to determine the recompression indices and the coefficient of consolidation(or the coefficient of swelling) of unloading-reloading cycle to predict the settlement behavior. However, since standard testing procedures or studies related with strain rate are insufficient especially in unloading-reloading cycle, it is difficult to predict the settlement field behavior accurately from the CRS consolidation test results in spite of its lots of strengths. The several CRS consolidation tests were performed changing the unloading strain rate from 0.2%/hr to 20%/hr with vertical drainage condition using the reconstituted kaolinite sample. For the reconstituted kaolinite sample in CRS consolidation test, the recompression indices are insensitive to the strain rate. It is revealed that the coefficient of consolidation of reloading is affected by the developed pore pressure during unloading. Additionally, the test should be conducted in the positive pore pressure ratio range (3~15%) to obtain the reasonable coefficient of consolidation in the whole range(loading, unloading and reloading).

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Crystallization Behavior and Electrical Properties of BNN Thin Films by IBSD Process

  • Lou, Jun-Hui;Jang, Jae-Hoon;Lee, Hee-Young;Cho, Sang-Hee
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.960-964
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    • 2004
  • [ $Ba_2NaNb_5O_{15}$ ](BNN) thin films have been prepared by the ion beam sputter deposition (IBSD) method on Pt coated Si substrate at temperature as low as $600^{\circ}C$ XRD, SEM were used to investigate the crystallization and microstructure of the films. It was found that the films were crack-free and uniform in microstructure. The electric properties of thin films were carried out by observation of D-E hysteresis loop, dielectric constant and leakage current. It was found the deposition rate strongly influenced the phase formation of the films, where the phase of $BaNb_2O_6$ was always formed when the deposition rate was high. However, the single phase (tungsten bronze structure ) BNN thin film was obtained with the deposition rate as low as $22{\AA}/min$. The remanent polarization Pr and dielectric constant are about 1-2 ${\mu}C/cm^2$ and $100\sim200$, respectively. It was also founded the electric properties of thin films were influenced by the deposition rate. The Pr and dielectric constant of films increased with the decrease of deposition rate. The effects of annealing temperature and annealing time to the crystallization behavior of films were studied. The crystallization of thin film started at about $600^{\circ}C$. The adequate crystallization was gotten at the temperature of $650^{\circ}C$ when the annealing time is 0.5 hour or at the temperature of $600^{\circ}C$ when the annealing time is long as 6 hours.

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도시 하수 폐기물의 고주파 건조 (Drying by Microwave Irradiation of Sewage Waste)

  • 박수인;박광하
    • 분석과학
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    • 제10권6호
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    • pp.418-426
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    • 1997
  • 고주파를 이용한 오니의 건조특성에 대하여 살펴보고 재래식 건조특성과 비교 분석하였다. 고주파 건조는 빠른 속도와 높은 효율을 보였다. 재래식 건조에서는 항율건조기간이 나타나지 않았고 수분은 모세관현상에 의하여 이동하였다. 오니의 수분 중 자유수와 결합수는 존재하지 않았다. 고주파 건조에서 감율건조기간이 두 부분으로 나타났으며, 수분의 이동은 확산에 의하여 일어났다. 증발 표면적이 커질수록 수분의 제거가 촉진되었고, 오니의 지름이 커질수록 넓은 범위의 항율건조 기간이 나타났으며, 모양에 따라서도 건조특성이 다르게 나타났다. 고주파 건조에서는 오니의 중심부에서 가장 먼저 온도가 상승하였으며, 항율건조기간에서 $80{\sim}100^{\circ}C$로 일정하게 유지되면서 가장 높았다.

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Co(Ⅱ)$(dimethyl bipyridine)_3(ClO_4)_2$의 전기화학적 성질과 산소환원에 대한 전극 촉매 효과 (Electrocatalytic Effect on the Oxygen Reduction and Electrochemical Properties of Co(Ⅱ)-dimethyl Bipyridine Perchlorate)

  • 김일광;박종술;한완수;김윤근;전일철
    • 대한화학회지
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    • 제41권8호
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    • pp.385-391
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    • 1997
  • Co$(dimethyl bipyridine)_3(ClO_4)_2$의 확산계수$(D_0)$와 전극반응속도상수$(K_0)$를 순환전압전류법과 대시간전류법으로 구하였다. 확산계수에 대한 용매, 농도, 주사속도 등의 영향과 반응속도상수에 대한 온도변화의 영향을 조사하였다. 25$^{\circ}C$에서 확산계수는 $5.54{\times}10^{-6 }cm^2/sec$이었고, 반응속도상수는 $2.39{\times}10^{-3 }/s$ 이었으며, 용매의 점도가 커질수록 봉우리전류값과 확산계수는 감소하였다. 반응속도상수에 대한 온도의 영향으로부터, ${\Delta}G^{\neq},\;{\Delta}H^{\neq},\;{\Delta}S$ 등의 열역학적 파라미터를 구하였다. 이 화합물은 $O_2$분자의 환원에서 봉우리전류를 크게 증가시키고, 환원전위를 양(+)전위방향으로 이동시키는 열역학적 전극촉매현상을 보였다.

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COMBUSTION CHARACTERISTICS OF INHOMOGENEOUS METHANE-AIR MIXTURE IN A CONSTANT VOLUME COMBUSTION CHAMBER

  • Choi, S.H.;Jeon, C.H.;Chang, Y.J.
    • International Journal of Automotive Technology
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    • 제5권3호
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    • pp.181-188
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    • 2004
  • A cylindrical constant-volume combustion chamber was used to investigate the flow characteristics at the spark electrode gap and the combustion characteristics of an inhomogeneous charge methane-air mixture under several parameters such as stratified pattern, initial charge pressure, ignition time and the excess air ratio of the initial charge mixture. Flow characteristics including mean velocity and turbulence intensity were analyzed by a hot-wire anemometer. The combustion pressure development, measured by a piezo-electric pressure transducer, was used to investigate the effect of initial charge pressure, excess air ratio and ignition times on combustion pressure and combustion duration. It was found that the mean velocity and turbulence intensity had the maximum value around 200-300 ms and then decreased gradually to near-zero value at 3000 ms. For the stratified patterns, the combustion rate under the rich injection (RI) condition was the fastest. Under the initial charge conditions, the second mixture was accompanied by an increase in the combustion rate, and that the higher the mass which is added in the second stage injection, the faster the combustion rate.

無煙炭의 反應成에 關한 硏究 (第1報) 反應成 試驗藏置의 試作 (Studies on the Reactivity of Korean Anthracites. (Part 1) Setting-Up of an Apparatus for Testing the Reactivity of Korean Anthracites)

  • 한태희;이재성;신성식
    • 대한화학회지
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    • 제6권1호
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    • pp.47-53
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    • 1962
  • The "reactivity" of coal is one of the important characteristics of a coal used as a process raw material as well as a fuel. In this study, the reactivity was measured in terms of the magnitude of the reaction rate constant in the reduction of carbon dioxide with coal. A reactivity-testing apparatus was designed and constructed, and its performance characteristics were investigated by using Korean anthracite and hard-wood charcoal. Experiments were carried out at temperatures ranging from 750 to 1100$^{\circ}C$ with pulverized Korean anthracite whose sizes range from 1 to 10mm in diameter. Results showed that the reaction rate constant was not appreciably affected by the particle size investigated, and the reactivities of the anthracite and the charcoal were found to be a function of reaction temperature alone. It was also found that a straight line was produced when the logarithm of the rate constant is plotted against the reciprocal of the absolute temperature. The reactivities of the charcoal were found to be 2 to 10 times higher than those of the anthracite at a temperature ranging from 750 to 1100$^{\circ}C$, and 90% of carbon dioxide was reduced to carbon monoxide by the anthracite at a temperature above 1050$^{\circ}C$.

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카르바마제핀의 체내동태에 대한 신장해의 영향 (Effect of Renal Failure on Pharmacokinetics of Carbamazepine in Rabbits)

  • 이종기;박현진;조행남
    • 한국임상약학회지
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    • 제9권2호
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    • pp.92-96
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    • 1999
  • The pharmacokinetics of carbamazepine(100 mg/kg, oral) in the folic acid-induced renal failure rabbits was studied. Renal failure was induced by the i.v. injection of folic acid (50, 100, and 200 mg/kg). At folic acid dose of 100 and 200 mg/kg, the serum creatinine concentration (Scr) and blood urea nitrogen (BUN) increased significantly compared with control rabbits. Plasma concentrations and area under the plasma level-time curve (AUC) of carbamazepine increased significantly at folic acid dose of 100 and 200 mg/kg. The elimination rate constant (Kel) of carbamazepine decreased significantly, and half-life $(t_{1/2})$ of carbamazepine increased significantly at folic acid dose of 100 and 200 mg/kg. The serum creatinine concentration (Scr) correlated well with AUC and elimination rate constant (Kel) of carbamazepine, as well as BUN with AUC and elimination rate constant (Kel) of carbamazepine. These results suggest that adjustment of the dosage regimen of carbamazepine is desirable, and serum creatinine concentration (Scr) as well as BUN can be used for adjusting the dosage regimen of carbamazepine in renal failure.

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회전매체를 이용한 완전혼합 활성슬러지 공법의 Kinetic Constant의 산정 (Estimation of Kinetic Constant in Moving Media Complete Mixing Activated Sludge Reactor)

  • 김홍태
    • 물과 미래
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    • 제27권4호
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    • pp.49-57
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    • 1994
  • 하수와 우유를 섞은 합성폐수를 처리하기 위해 회전매체를 이용한 완전혼합활성슬러지 공법의 kinetic constant 값을 산정한 결과, $K_{m}$(유기물제거속도) 값은 저부하의 경우는 3.75~8/hr, 고부하인 경우는 8.57~12.5/hr이며, $K_{e}$값은 저부하인 경우 0.007~0.03/hr, 고부하인 경우는 0.09/hr로, $K_{s}$(내호흡계수) 값은 저부하인 경우 1.73~3.68/hr, 고부하인 경우는 3.84~5.75/hr로 나타났으며, Y 값은 0.46gVSS/g$BOD_{5}$로 산정 되었다.

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복합 냉풍 건조기 개발 (Development of the mixed desiccant cooling dryer)

  • 최현웅;김영일;박승태;유경록
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.242-247
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    • 2009
  • The present study has been conducted to reduce the cold air drying rate. According to the cold air drying method, the quality-excellent product could be made and there would be little change of color, taste and smell. As compared with the hot air drying, the cold air drying equipment has the superior dehumidification in a constant drying zone. However, in a falling drying zone that equipment is not energy-efficient because the drying period could be longer by the dehumidificated.

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전해가공 시의 정밀도위 향상을 위한 음극 설계와 모사 (Cathode design and simulation in electrochemical machining)

  • 유시철;조수익;손헌준;강탁
    • 한국표면공학회지
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    • 제30권4호
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    • pp.239-247
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    • 1997
  • The electrochemical machining of carbon steel was carried in various electrolytes which contain NACl and $NaCIO_3$. Though electrolyte containg NaCl yields fast machining rate, dimensional control is rather difficult. In the case of electrolyte with $NaCIO_3$, dimensional control of anode shape can be obtained through modification of cathode design. Mathematical modeling is also performed for these systems and agreements are good compared with experimental date. The constant gap experiment butween two electrode yielded faster machining rate than constant cathode moving rate experiment.

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