• Title/Summary/Keyword: rate constant(k)

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Optimal Strain Rate of Unloading-Reloading Cycle in Constant Rate of Strain Consoildation Test (제하-재재하 시 CRS 압밀 시험의 최적 변형률 속도)

  • Park, Ka-Hyun;Yune, Chan-Young;Chung, Choong-Ki
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.1156-1167
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    • 2010
  • The constant rate of strain (CRS) consolidation test has been widely used to evaluate consolidation characteristics of soils instead of the standard Incremental Loading Test. In practical problems, after the ground improvement, the condition of the soil is over-consolidated. Therefore, it is important to determine the recompression indices and the coefficient of consolidation(or the coefficient of swelling) of unloading-reloading cycle to predict the settlement behavior. However, since standard testing procedures or studies related with strain rate are insufficient especially in unloading-reloading cycle, it is difficult to predict the settlement field behavior accurately from the CRS consolidation test results in spite of its lots of strengths. The several CRS consolidation tests were performed changing the unloading strain rate from 0.2%/hr to 20%/hr with vertical drainage condition using the reconstituted kaolinite sample. For the reconstituted kaolinite sample in CRS consolidation test, the recompression indices are insensitive to the strain rate. It is revealed that the coefficient of consolidation of reloading is affected by the developed pore pressure during unloading. Additionally, the test should be conducted in the positive pore pressure ratio range (3~15%) to obtain the reasonable coefficient of consolidation in the whole range(loading, unloading and reloading).

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Crystallization Behavior and Electrical Properties of BNN Thin Films by IBSD Process

  • Lou, Jun-Hui;Jang, Jae-Hoon;Lee, Hee-Young;Cho, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.960-964
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    • 2004
  • [ $Ba_2NaNb_5O_{15}$ ](BNN) thin films have been prepared by the ion beam sputter deposition (IBSD) method on Pt coated Si substrate at temperature as low as $600^{\circ}C$ XRD, SEM were used to investigate the crystallization and microstructure of the films. It was found that the films were crack-free and uniform in microstructure. The electric properties of thin films were carried out by observation of D-E hysteresis loop, dielectric constant and leakage current. It was found the deposition rate strongly influenced the phase formation of the films, where the phase of $BaNb_2O_6$ was always formed when the deposition rate was high. However, the single phase (tungsten bronze structure ) BNN thin film was obtained with the deposition rate as low as $22{\AA}/min$. The remanent polarization Pr and dielectric constant are about 1-2 ${\mu}C/cm^2$ and $100\sim200$, respectively. It was also founded the electric properties of thin films were influenced by the deposition rate. The Pr and dielectric constant of films increased with the decrease of deposition rate. The effects of annealing temperature and annealing time to the crystallization behavior of films were studied. The crystallization of thin film started at about $600^{\circ}C$. The adequate crystallization was gotten at the temperature of $650^{\circ}C$ when the annealing time is 0.5 hour or at the temperature of $600^{\circ}C$ when the annealing time is long as 6 hours.

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Drying by Microwave Irradiation of Sewage Waste (도시 하수 폐기물의 고주파 건조)

  • Park, Soo In;Park, Kwang Ha
    • Analytical Science and Technology
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    • v.10 no.6
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    • pp.418-426
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    • 1997
  • Dewatered digested sewage sludge were heated with microwave and their drying characteristics were investigated on the effect of their surface area, shape, diameter and thickness. The drying characteristics of identical samples in a conventional drying oven were studied. In conventional drying, constant rate period was not found and moisture was evaporated with capillary action. Moisture in the sludge was a bound water and free water was not exist. In microwave drying, the falling rate period was divided into two zones. In falling rate drying period, moisture movement occured by diffusion. The evaporation surface area was a significant variable, the greater heating surface area promoted water removal rate over wide region of water content. Drying rate was slow and constant rate drying period was found in wide moisture content region with increasing diameter. Drying characteristics appeared differently in various shape. In microwave heating, first of all temperature of sludge center was increased and was the highest. Temperature in the constant rate drying period was remained constantly at $80{\sim}100^{\circ}C$.

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Electrocatalytic Effect on the Oxygen Reduction and Electrochemical Properties of Co(Ⅱ)-dimethyl Bipyridine Perchlorate (Co(Ⅱ)$(dimethyl bipyridine)_3(ClO_4)_2$의 전기화학적 성질과 산소환원에 대한 전극 촉매 효과)

  • Kim, Il Kwang;Park, Chong Sool;Han, Wan Soo;Kim, Youn Keun;Jeon, Il Cheol
    • Journal of the Korean Chemical Society
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    • v.41 no.8
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    • pp.385-391
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    • 1997
  • Diffusion Coefficient$(D_0)$ and electrode reaction rate Constant$(K_0)$ of Co$(dimethyl bipyridine)_3(ClO_4)_2$ were determined by cyclic voltammetry and chronoamperometry. It was also investigated that the effects of solvent, concentration, and scan rate, etc. on the diffusion coefficient and the temperature effect on the rate constant. The peak currents and diffusion coefficients were dcreased as increasing the viscosity of solvent. Diffusion coefficient was $5.54{\times}10^{-6 }cm^2/sec$ and the reaction rate constant was $2.39{\times}10^{-3 }/s$ at 25$^{\circ}C$. The thermodynamic parameters such as ${\Delta}G^{\neq},\;{\Delta}H^{\neq},\;and\;{\Delta}S$ were calculated from plotting the reaction rate constants versus the solution temperatures. This compound was shown the catalytic effect on the oxygen reduction that the reduction peak current of oxygen was greatly enhanced and the peak potential was shifted to +0.2 volt.

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COMBUSTION CHARACTERISTICS OF INHOMOGENEOUS METHANE-AIR MIXTURE IN A CONSTANT VOLUME COMBUSTION CHAMBER

  • Choi, S.H.;Jeon, C.H.;Chang, Y.J.
    • International Journal of Automotive Technology
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    • v.5 no.3
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    • pp.181-188
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    • 2004
  • A cylindrical constant-volume combustion chamber was used to investigate the flow characteristics at the spark electrode gap and the combustion characteristics of an inhomogeneous charge methane-air mixture under several parameters such as stratified pattern, initial charge pressure, ignition time and the excess air ratio of the initial charge mixture. Flow characteristics including mean velocity and turbulence intensity were analyzed by a hot-wire anemometer. The combustion pressure development, measured by a piezo-electric pressure transducer, was used to investigate the effect of initial charge pressure, excess air ratio and ignition times on combustion pressure and combustion duration. It was found that the mean velocity and turbulence intensity had the maximum value around 200-300 ms and then decreased gradually to near-zero value at 3000 ms. For the stratified patterns, the combustion rate under the rich injection (RI) condition was the fastest. Under the initial charge conditions, the second mixture was accompanied by an increase in the combustion rate, and that the higher the mass which is added in the second stage injection, the faster the combustion rate.

Studies on the Reactivity of Korean Anthracites. (Part 1) Setting-Up of an Apparatus for Testing the Reactivity of Korean Anthracites (無煙炭의 反應成에 關한 硏究 (第1報) 反應成 試驗藏置의 試作)

  • Hahn, Tae-Hee;Lee, Chai-Sung;Shin, Sung-Sik
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.47-53
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    • 1962
  • The "reactivity" of coal is one of the important characteristics of a coal used as a process raw material as well as a fuel. In this study, the reactivity was measured in terms of the magnitude of the reaction rate constant in the reduction of carbon dioxide with coal. A reactivity-testing apparatus was designed and constructed, and its performance characteristics were investigated by using Korean anthracite and hard-wood charcoal. Experiments were carried out at temperatures ranging from 750 to 1100$^{\circ}C$ with pulverized Korean anthracite whose sizes range from 1 to 10mm in diameter. Results showed that the reaction rate constant was not appreciably affected by the particle size investigated, and the reactivities of the anthracite and the charcoal were found to be a function of reaction temperature alone. It was also found that a straight line was produced when the logarithm of the rate constant is plotted against the reciprocal of the absolute temperature. The reactivities of the charcoal were found to be 2 to 10 times higher than those of the anthracite at a temperature ranging from 750 to 1100$^{\circ}C$, and 90% of carbon dioxide was reduced to carbon monoxide by the anthracite at a temperature above 1050$^{\circ}C$.

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Effect of Renal Failure on Pharmacokinetics of Carbamazepine in Rabbits (카르바마제핀의 체내동태에 대한 신장해의 영향)

  • Lee, Chong Ki;Park, Hyun Jin;Cho, Heng Nam
    • Korean Journal of Clinical Pharmacy
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    • v.9 no.2
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    • pp.92-96
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    • 1999
  • The pharmacokinetics of carbamazepine(100 mg/kg, oral) in the folic acid-induced renal failure rabbits was studied. Renal failure was induced by the i.v. injection of folic acid (50, 100, and 200 mg/kg). At folic acid dose of 100 and 200 mg/kg, the serum creatinine concentration (Scr) and blood urea nitrogen (BUN) increased significantly compared with control rabbits. Plasma concentrations and area under the plasma level-time curve (AUC) of carbamazepine increased significantly at folic acid dose of 100 and 200 mg/kg. The elimination rate constant (Kel) of carbamazepine decreased significantly, and half-life $(t_{1/2})$ of carbamazepine increased significantly at folic acid dose of 100 and 200 mg/kg. The serum creatinine concentration (Scr) correlated well with AUC and elimination rate constant (Kel) of carbamazepine, as well as BUN with AUC and elimination rate constant (Kel) of carbamazepine. These results suggest that adjustment of the dosage regimen of carbamazepine is desirable, and serum creatinine concentration (Scr) as well as BUN can be used for adjusting the dosage regimen of carbamazepine in renal failure.

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Estimation of Kinetic Constant in Moving Media Complete Mixing Activated Sludge Reactor (회전매체를 이용한 완전혼합 활성슬러지 공법의 Kinetic Constant의 산정)

  • 김홍태
    • Water for future
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    • v.27 no.4
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    • pp.49-57
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    • 1994
  • This study was carried out to obtain Kinetic constant of Moving Media Complete Mixing Activated Sludge (MMCMAS) for the wastewater treatment. A laboratory MMCMAS reactor was operated at the organic loading rate of 2.5g$BOD_{5}$/$m^{2}$ /d~48g$BOD_{5}$/$m^{2}$/d kinetic constant of MMCMAS reactor was estimated as follows:

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Development of the mixed desiccant cooling dryer (복합 냉풍 건조기 개발)

  • Choi, Hyun-Woong;Kim, Young-Il;Park, Seung-Tae;Yoo, Kyung-Rok
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.242-247
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    • 2009
  • The present study has been conducted to reduce the cold air drying rate. According to the cold air drying method, the quality-excellent product could be made and there would be little change of color, taste and smell. As compared with the hot air drying, the cold air drying equipment has the superior dehumidification in a constant drying zone. However, in a falling drying zone that equipment is not energy-efficient because the drying period could be longer by the dehumidificated.

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Cathode design and simulation in electrochemical machining (전해가공 시의 정밀도위 향상을 위한 음극 설계와 모사)

  • Yu, S. C.;Jo, S. I.;Sohn, H. J.;Kang, T.
    • Journal of the Korean institute of surface engineering
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    • v.30 no.4
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    • pp.239-247
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    • 1997
  • The electrochemical machining of carbon steel was carried in various electrolytes which contain NACl and $NaCIO_3$. Though electrolyte containg NaCl yields fast machining rate, dimensional control is rather difficult. In the case of electrolyte with $NaCIO_3$, dimensional control of anode shape can be obtained through modification of cathode design. Mathematical modeling is also performed for these systems and agreements are good compared with experimental date. The constant gap experiment butween two electrode yielded faster machining rate than constant cathode moving rate experiment.

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