• Title/Summary/Keyword: rate capacity effect

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Synergy Effect of K Doping and Nb Oxide Coating on Li1.2Ni0.13Co0.13Mn0.54O2 Cathodes

  • Kim, Hyung Gi;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.12 no.4
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    • pp.377-386
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    • 2021
  • The Li-rich oxides are promising cathode materials due to their high energy density. However, characteristics such as low rate capability, unstable cyclic performance, and rapid capacity fading during cycling prevent their commercialization. These characteristics are mainly attributed to the phase instability of the host structure and undesirable side reactions at the cathode/electrolyte interface. To suppress the phase transition during cycling and interfacial side reactions with the reactive electrolyte, K (potassium) doping and Nb oxide coating were simultaneously introduced to a Li-rich oxide (Li1.2Ni0.13Co0.13Mn0.54O2). The capacity and rate capability of the Li-rich oxide were significantly enhanced by K doping. Considering the X-ray diffraction (XRD) analysis, the interslab thickness of LiO2 increased and cation mixing decreased due to K doping, which facilitated Li migration during cycling and resulted in enhanced capacity and rate capability. The K-doped Li-rich oxide also exhibited considerably improved cyclic performance, probably because the large K+ ions disturb the migration of the transition metals causing the phase transition and act as a pillar stabilizing the host structure during cycling. The Nb oxide coating also considerably enhanced the capacity and rate capability of the samples, indicating that the undesirable interfacial layer formed from the side reaction was a major resistance factor that reduced the capacity of the cathode. This result confirms that the introduction of K doping and Nb oxide coating is an effective approach to enhance the electrochemical performance of Li-rich oxides.

Comparison of lymphocyte DNA damage levels and total antioxidant capacity in Korean and American diet

  • Lee, Min Young;Kim, Hyun A;Kang, Myung Hee
    • Nutrition Research and Practice
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    • v.11 no.1
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    • pp.33-42
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    • 2017
  • BACKGROUND/OBJECTIVE: This study aims to measure the in vitro antioxidant capacity of Korean diet (KD) with American diet (AD) as a control group and to examine the ex vivo DNA damage reduction effect on human lymphocytes. MATERIALS/METHODS: The KD applied in this study is the standard one-week meals for Koreans (2,000 kcal/day) suggested by 2010 Dietary Reference Intakes for Koreans. The AD, which is the control group, is a one-week menu (2,000 kcal/day) that consists of foods that Americans would commonly take in according to the National Health and Nutrition Examination Survey. The antioxidant capacity of each menu was measured by means of the total phenolic assay and 3 in vitro antioxidant activity assays (2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activity, trolox equivalent antioxidant capacity (TEAC), Oxygen radical absorbance capacity ($ORAC_{ROO{\cdot}}$)), while the extent of ex vivo lymphocyte DNA damage was measured by means of the comet assay. RESULTS: When measured by means of TEAC assay, the in vitro antioxidant capacity of the KD of the day was higher than that of the AD (P < 0.05) while there was no significant difference in total phenolic contents and DPPH and ORAC assays. The ex vivo lymphocyte DNA damage protective effect of the KD was significantly higher than that of the AD (P < 0.01). As for the one-week menu combining the menus for 7 days, the total phenolic assay (P < 0.05) and in vitro antioxidant capacity (P < 0.001, DPPH; P < 0.01, TEAC) of the KD menu were significantly higher than those of the AD menu. Likewise, the ex vivo DNA damage reduction rate of the Korean seven-day menu was significantly higher than that of the American menu (P < 0.01). CONCLUSION: This study demonstrates that the high antioxidant capacity and DNA damage protective effect of KD, which consists generally of various plant foods, are higher than those of typical AD.

NUMERICAL ANALYSIS ON INTERNAL FLOW OF OIL JET COOLING THE PISTON (피스톤 냉각용 Oil jet 유동해석)

  • Kwon J.H.;Jung H.Y.;Lee J.H.;Choi Y.H.;Lee Y.W.
    • 한국전산유체공학회:학술대회논문집
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    • 2005.10a
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    • pp.219-222
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    • 2005
  • Recently, the interest of the engine capacity and environment of the atmosphere is increasing, so the researches for the engine capacity have been conducted for a long time. But the internal environment of an automotive engine is very severe. A piston is exposed to combustion gas of over $2000^{\circ}C$ and strong friction is occurred by high speed motion in the cylinder. The fraction between piston and wall of the cylinder causes the increase of temperature in the engine. The temperature of the engine has an effect on the engine capacity. If the temperature is high, the capacity of the engine is low. So we have to maintain the optimum temperature. To maintain the optimum temperature, the enough flow rate of the engine oil is needed. The oil jet is used to control the flow rate of the engine oil and supply the engine oil to the piston and cylinder. The purpose of this study is to check the mass flow rate of the engine oil and the characteristics of internal flow of the oil jet. Flow pattern of the engine oil is very important because it concludes the loss in the oil jet. This study is the previous research about the oil jet and we will consider the movement of the ball check valve to get more accuracy result.

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Strain Rate Effect on the Compressive and Tensile Strength of Hooked Steel Fiber and Polyamide Fiber Reinforced Cement Composite (변형 속도에 따른 후크형 강섬유 및 폴리아미드섬유보강 시멘트 복합체의 압축 및 인장강도 특성)

  • Kim, Hong-Seop;Kim, Gyu-Yong;Lee, Sang-Kyu;Son, Min-Jae;Nam, Jeong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.76-85
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    • 2017
  • In this study, to evaluate the mechanical properties of fiber-reinforced cement composites by strain rate, hydraulic rapid loading test system was developed. And compressive and tensile strength of the hooked steel fiber and polyamide fiber reinforced cement composite were evaluated. As a result, the compressive strength, strain capacity and elastic modulus were increased with increasing strain rate. The effect of compressive strength by type and volume fraction of fibers was not significant. The dynamic increase factor(DIF) of the compressive strength was higher than that of the CEB-FIP model code 2010 and showed a trend similar to that of ACI-349. The tensile strength and strain capacity were increased with increasing strain rate. The hooked steel fibers were drawn from the matrix. The tensile strength and strain capacity of hooked steel fiber reinforced cement composites were increased as the strain rate increased. The tensile strength and deformation capacity of the fiber reinforced cement composites were increased. And, hooked steel fibers were drawn from the matrix. On the other hand, because the bonding properties of polyamide fiber and matrix is large, polyamide fiber was cut-off with out pullout from matrix. The strain rate effect on the tensile properties of polyamide fiber reinforced cement composites was found to be strongly affected by the tensile strength of the fibers.

RELATIONSHIP BETWEEN MILKING FREQUENCY AND UDDER CAPACITY IN FRIESIAN AND JERSEY COWS

  • Alshaikh, M.A.;Salah, M.S.;Aljobeile, H.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.8 no.5
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    • pp.471-476
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    • 1995
  • The relationship between udder maximum capacity (36-h accumulated milk yield) and the response of dairy cows (average producers) to thrice-daily milking was studied in 25 Friesian and 15 Jersey cows using the technique of half-udder study. Maximum half-udder capacity (acual yield) as well as whole udder capacity (estimated by udder measurements) was not altered significantly after 12-day thrice-daily milking period compared with a similar twice-daily period, although there was a positive response to increased milking frequency on secretion rate during this period. No effect of breed, season of the year or stage of lactation was observed on the above relationship. Hours-worth of capacity was higher with increased milking frequency, with Jersey than Friesian. These results suggest that udder capacity is not a limiting factor in increased milk production.

A Study on the DC-Link Miniaturization and the Reduction of Output Current Distortion Rate by Reducing the Effect of 120 Hz Ripple Voltage on Photovoltaic Systems (태양광 발전 시스템의 120Hz 리플 전압 영향 감소를 통한 DC-Link 소형화와 출력 전류 왜곡률 감소에 관한 연구)

  • Song, Min-Geun;Lee, Woo-Cheol
    • The Transactions of the Korean Institute of Power Electronics
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    • v.26 no.5
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    • pp.342-348
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    • 2021
  • The PV module of solar power systems requires maximum power point tracking (MPPT) technique because the power-voltage and current-voltage characteristics vary depending on the surrounding environment. In addition, the 120 Hz ripple voltage on the DC-Link is caused by the imbalance of the system voltage and current. The effect of this 120 Hz ripple voltage reduces the efficiency of the power generation system by increasing the output current distortion rate. Increasing the capacity of DC-Link can reduce the 120 Hz ripple voltage, but this method is inefficient in price and size. We propose a technique that detects 120 Hz ripple voltage and reduces the effect of ripple voltage without increasing the DC-Link capacity through a controller. The proposed technique was verified through simulations and experiments using a 1 kW single-phase solar power system. In addition, the proposed technique's feasibility was demonstrated by reducing the distortion rate of the output current.

Seismic Analysis on Recycled Aggregate Concrete Frame Considering Strain Rate Effect

  • Wang, Changqing;Xiao, Jianzhuang;Sun, Zhenping
    • International Journal of Concrete Structures and Materials
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    • v.10 no.3
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    • pp.307-323
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    • 2016
  • The nonlinear behaviors of recycled aggregate concrete (RAC) frame structure are investigated by numerical simulation method with 3-D finite fiber elements. The dynamic characteristics and the seismic performance of the RAC frame structure are analyzed and validated with the shaking table test results. Specifically, the natural frequency and the typical responses (e.g., storey deformation, capacity curve, etc.) from Model 1 (exclusion of strain rate effect) and Model 2 (inclusion of strain rate effect) are analyzed and compared. It is revealed that Model 2 is more likely to provide a better match between the numerical simulation and the shaking table test as key attributes of seismic behaviors of the frame structure are captured by this model. For the purpose to examine how seismic behaviors of the RAC frame structure vary under different strain rates in a real seismic situation, a numerical simulation is performed by varying the strain rate. The storey displacement response and the base shear for the RAC frame structure under different strain rates are investigated and analyzed. It is implied that the structural behavior of the RAC frame structure is significantly influenced by the strain rate effect. On one hand, the storey displacements vary slightly in the trend of decreasing with the increasing strain rate. On the other hand, the base shear of the RAC frame structure under dynamic loading conditions increases with gradually increasing amplitude of the strain rate.

Effect of Packing Density of ion-Exchange on the Nickel Adsorption Column in Electroplating Rinse Water (이온교환 칼럼 충진비의 변화가 도금폐수 중 니켈이온 흡착에 미치는 영향)

  • 황택성;이진혁
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.551-558
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    • 2002
  • It was observed that adsorption characteristics of sulfonated fabric ion-exchanger for separating nickel ion from electroplating rinse water. Swelling ratio was increased by increasing degree of sulfonation and polarity of solvent. Ion-exchange capacity was also increased by increasing degree of sulfonation and showed 3.38 meq/g at 16% sulfonated ion-exchanger. There was little effects of pH. Adsorption equilibrium was attained within 10 min, and adsorption rate was 7.5 mg/min. Adsorption capacity was not changed after 7 cycles of regeneration process. Regeneration adsorption capacity was slightly decreased to 2.01 meq/g. It confirmed that durability of sulfonated fabric ion-exchanger was suitable for adsorption process. Adsorption equilibrium time was linearly increased by increasing L/D and adsorption capacity showed the ion exchange capacity within the range of 2.71 ∼ 3.01 meq/g in continuous process. Design of adsorption column could be possible for L/D<2. Under constant L/D condition, there is no little pH effect when rinse water is acidic solution, and operation condition of adsorption process was optimized under pH 5.

Mechanical Properties of Aluminium Alloy with Cellular Structure. (미세기공 알루미늄 소재의 기계적 성질)

  • 윤성원;이승후;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.695-698
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    • 2002
  • Induction heating process is one of the most efficient heating process in terms of temperature control accuracy and heating time saving. In the past study, fabrication process of cellular 6061 alloys by powder metallurgical route and induction heating process was studied. To supplement the framing conditions that studied in past study, effect of induction heating capacity and holding time at foaming temperature were investigated. Under the achieved framing conditions, teamed 6061 alloys were fabricated for variation of foaming temperature, and porosities(%)-foaming temperature curves were obtained by try-error experimental method. Uniaxial compression tests were performed to investigate the relationship between porosities(%) and stress-strain curves of framed 6061 alloy. Also, energy absorption capacity and efficiency were calculated from stress-strain curves to investigated. Moreover, dependence of plateau stress on strain rate was investigated in case of cellular 6061 alloy with low porosities(%)

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A Numerical Analysis of a Revised VX Absorption Cooling Cycle (Revised VX흡수식 냉동사이클의수치 해석)

  • 장원영;정은수;김병주
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.6
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    • pp.505-513
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    • 2001
  • A revised VX cycle using ammonia/water as the working fluid is a cycle which is suitable to produce cooling utilizing low temperature hat sources. The cycle was analyzed numerically to investigate the effects of the design and operating conditions on the performance. It was shown that both COP and cooling capacity were significantly influenced by the performance of he rectifier. Insufficient UA of the rectifier reduced both ammonia mass fraction and mass flow rate of the vapor entering the condenser, which produced cooling effect in the evaporator. As the temperature and the mass flow rate of the heat source increased, both COP and exergetic efficiency decreased due to the irreversibilities produced in heat exchangers, but cooling capacity did not vary much. Cooling capacity increased significantly as the coolant temperature decreased, although COP and exergetic efficiency remained nearly constant.

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