• Title/Summary/Keyword: rare earth

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Electrical Property of $BaTiO_3$ Ceramics(II) ($BaTiO_3$ 세라믹의 전기적성질(II))

  • 윤기현;송효일;윤상옥;이형복
    • Journal of the Korean Ceramic Society
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    • v.18 no.2
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    • pp.75-78
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    • 1981
  • The electrical conductivity of $(M_2O_3)_x (BaTiO_3)_{1-x}$ has been measured over the temperature range of 30 to 27$0^{\circ}C$. The substitution of rare earth oxide such as $La_2O_3$, $Nd_2O_3$, or $Dy_2O_3$ can be represented by $M_2O_3$. The additional mole fraction of the rare earth oxide is ranged over 0.0015 to 0.0030. The electrical conductivity exhibits an anomalous decrease near the tetragonal to cubic transition about 12$0^{\circ}C$. The decrease in the electrical conductivity is observed at the higher impurity concentrations owing to space charge layer. The increase in the electrical conductivity is observed as the impurity ion is varied from $La^{+3}$$Nd^{+3}$ to $Dy^{+3}$, due to overlap of 4f electrons of the inner shell.

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Mechanical Properties of Hot-Pressed SiC with Rare-Earth Oxide (희토류 산화물을 첨가한 일축가압소결 탄화규소의 기계적 특성)

  • 최철호;이충선;박광자;조덕호;김영욱
    • Journal of the Korean Ceramic Society
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    • v.37 no.2
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    • pp.158-163
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    • 2000
  • Six different SiC ceramics with SiO2-Re2O3 (Re=Yb, Er, Y, Dy, Gd, Sm) as sintering additives have been fabricated by hot-pressing the SiC-Re2Si2O7 compositions at 1850$^{\circ}C$ for 2 hr under a pressure of 25 MPa. The room temperature strneth and the fracture toughness of the hot-pressed ceramics were characterized and compared with those of the ceramics sintered with YAG (Y3Al5O12). Five SiC ceramics (Re=Yb, Er, Y, Dy, Gd) investigated herein showed sintered densities higher than 94% of theoretical. Tthe SiC-Re2Si2O7 compositions showed lower strength and comparable toughness to those from SiC-YAG composition, owing to the chemical reaction between SiO2 and SiC during sintering. SiC ceramics fabricated from a SiC-Y2Si2O7 composition showed the best mechanical properties of 490 MPa and 4.8 MPa$.$m1/2 among the compositions investigated herein.

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Comparison of Vehicle Efficiency Applying Rare Earth Free Concentrated-Flux Synchronous Motor and Rare Earth Interior Permanent Magnet Synchronous Motor According to Driving Cycle (전기자동차 구동용 비희토류 자속집중형 전동기와 희토류 전동기의 주행사이클에 따른 차량 효율 비교)

  • Cha, Kyoung-Soo;Kim, Dong-Min;Lim, Myung-Seop;Hong, Jung-Pyo
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.858-859
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    • 2015
  • 현재 전기자동차 구동전동기는 일반적으로 희토류 영구자석을 사용한 동기전동기를 사용하고 있다. 하지만 희토류는 수급불안정성이 높아 자동차 업계는 희토류 전동기를 대체할 수 있는 방안을 찾고 있으며 그 방안 중 하나가 비희토류 자속집중형 전동기이다. 비희토류 영구자석의 수를 늘려서 희토류 전동기와 동일한 크기에 유사한 출력을 만족하게 설계했다. 마지막으로 전기자동차 구동용 비희토류 자속집중형 전동기의 특성 및 크기를 희토류 전동기와 비교하고 두 전동기를 탑재한 차량을 Advisor(Advanced Vehicle Simulator)를 사용해 주행사이클에 대한 차량효율을 비교할 것이다.

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Optical, Mechanical and Tribological Properties of $Y_2O_3$ $Er_2O_3$ and $Nd_2O_3$ Doped Polycrystalline Silicon Nitride Ceramics

  • Joshi, Bhupendra;Lee, Su-Wan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.51.1-51.1
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    • 2010
  • $Y_2O_3$ $Er_2O_3$ and $Nd_2O_3$ doped polycrystalline silicon nitride were prepared by hot pressed sintering at $1850^{\circ}C$ and their optical transmittance were investigated in visible and in infrared region. Mechanical and tribological properties were also investigated. Grain growth in silicon nitride was reduced with addition of $Y_2O_3$ and $Nd_2O_3$. 1 wt.% of each rare earth metal were sintered with 3 wt.% MgO, 9wt.% AlN and 87 wt.% of ${\alpha}-Si_3N_4$. Adding these rare earth metal oxides shows good mechanical properties as high strength and toughness and also shows low friction coefficient.

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The Defect Characterization of Rare-earth Intensifying Screen Material by Doppler Broadening Positron Annihilation Spectrometer (도플러 넓어짐 스펙트럼을 이용한 희토류 증감지 결함 특성)

  • Lee C. Y.;Kim C. G.;Song G. Y.;Kim J. H.
    • Korean Journal of Materials Research
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    • v.15 no.6
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    • pp.370-374
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    • 2005
  • Doppler broadening spectrometer for positron annihilation experiment(DBPAS) has been used to characterize nano size defect structures in materials. DBPAS measures the concentration, spatial distribution, and size of open volume defects in the rare-earth intensifying screen materials. The screens were exposed by X-ray varying the exposed doses from 3, 6, 9, and 12 Gy with 6 W and 15 MV respectively and also irradiated by 37 MeV proton beams ranging from 0 to $10^{12}ptls$. The S parameter values increased as the exposed time and the energies increased, which indicated the defects were generated more. The S parameters of the samples with X-rays varied from 0.5098 to 0.5108, on the other hand, as proton beams varied from 0.4804 to 0.4821.

Exciplex emission in bilayer Light-emitting device

  • Liang, Yu-Jun;Zhang, Hong-Jie;Han, Sang-Do;Jung, Young-Ho;Taxak, Vinod Bala
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.762-765
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    • 2002
  • The bilayer organic light-emitting diode using Al (DBM) $_3$ (DBM=Dibenzoylmethane) as an emitting material and poly (N-vinylcarbazole) (PVK) as hole-transport material, emitted bright blue-green light instead of blue light. The blue-green emission is attributed to exciplex formation at the solid interface between Al (DBM) $_3$ and the hole-transport material. The exciplex formation was evidenced by the measurement of the photoluminescence spectra and lifetimes of Al (DBM) $_3$, PVK and an equimolar amount of mixture of Al (DBM) $_3$ and PVK.

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Physical ppropperties in Rare-earth Compounds

  • Takashi, Suzuki
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.18-18
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    • 1998
  • F First I will introduce our works how to improve the crystal growth t technique for Rare earth pnictides and chalcogenides. All these substances h have hi양1 vapor pressure and high melting print up to 3$\alpha$)()C. 까len we employ m the tungsten or molybden crucibles and enclose the sample by 빼e welding of m the lid with high current electron beam. We cannot elevate the temperature up t to 3$\alpha$)()C without suitable radiation shield because rate of radiation loss r rapidly increase in such a high temperature regions. There were no good r radiation shield but we discovered that the p-BN could work as an excellent r radiation shield after checking of the many substances. S Secondly I will show several interesting and unusual 뻐ysical properties of obtained crystals under high magnetic field, hi양1 pressure and also i including angle resolve photoemission spectroscopy. I will stress the p properties of the low carrier concentration with strong correlation on C댐, U USb and Yb4As3

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A Study on the Rare-earth Boronizing Treatment of STD 61 Steel (열간금형용강의 희토류붕화처리에 관한 연구)

  • Kim, C.C.;Youn, J.H.;Jang, Y.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.4
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    • pp.217-223
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    • 2000
  • The boronizing effects of STD 61 steel have been studied on the micro structure and hardness. The STD 61 Steel was soaked in molten salt, consisted of KCl, $BaCl_2$, NaF, $B_2O_3$, FeB, and Ce, at various temperatures and times. The boronizing conditions for the peak hardness were the temperature range of $900^{\circ}C$ to $950^{\circ}C$ for 5 hr and that of $1000^{\circ}C$ for 3 hr, respectively. Four boride layers such as FeB, $Fe_2B$, ${\alpha}$ and matrix layer surface were observed from the microscopic surface examination. The thickness of boride layer was increased by increasing the boronizing time and the temperature. The structure of boride layer was tooth shape.

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Novel Properties of Boron Added Amorphous Rare Earth-transition Metal Alloys for Giant Magnetostrictive and Magneto-optical Recording Materials

  • Jai-Young Kim
    • Journal of Magnetics
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    • v.3 no.3
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    • pp.78-81
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    • 1998
  • Large magneto crystalline anisotropy energy and demagnetization energy of rare earth-transition metal (RF-TM) alloys play roles of bottlenecks towards their commercial applications for giant magnetostrictive and blue wavelength magneto optical recording materials, respectively. To solve the above problems, boron is added into amorphous RE-TM alloys to produce its electron transferring. The boron added amorphous RE-TM alloys show novel magnetic and magneto-optical properties as follows; 1) an amorphous $(Sm_{33}Fe_{76})$97B3 alloy obtains the magnetostriction of$ -550{times}10^{-6}$ at 400 Oe compared with saturation magnetostriction of$ -60{\times}10^{-6}$ in conventional Ni based alloys, 2) an amorphous$ (Nd_{33}Fe_{67})_{95}B_5$ alloy increases effective magnetic anisotropy to$ -0.5{\times}10^{-6} ergs/cm^3 from -3.5{\times}10^6 ergs/cm^3$ without boron, which correspond to the polar Kerr rotation angles of 0.52$^{\circ}$and 0.33$^{\circ}$, respectively. These results attribute to selective 2p-3d electron orbits exchange coupling (SEC).

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Epitaxial Growth of Rare-earth Ion Doped $CaF_2$ layers by MBE

  • Ko, J.N.;Chen, Y.;Fukuda, T.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.3-7
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    • 1998
  • The rare-earth ions (R3+, R=Nd, Er) doped CaF2 layers have been grown on CaF2(111) substrate by molecular beam epitaxy. The epitaxial relationship and the crystallinity of CaF2:R3+ layers depending on the concentration of R3+ were studied by reflection high-energy electron diffraction (RHEED). In aspect of application as buffer layer in semiconductor-related hybrid structure, the lattice displacement between CaF2:R3+ layers and CaF2(111) substrate was investigated by X-ray rocking curve analysis.

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