• Title/Summary/Keyword: random diffusion

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기능성 레진을 이용한 구조화된 나노 입자의 특성

  • 신진섭;박영준;김중현
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.53-53
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    • 2002
  • Alkali-soluble random copolymer (ASR) was used as a functional resin in the emulsion polymerization of styrene to prepare structured nanoparticles. The calorimetric technique was applied to study the kinetics of emulsion polymerization of styrene using ASR and conventional ionic emulsifier, sodium dodecyl benzene sulfonate (SDBS). ASR could form aggregates like micelles and the solubilization ability of the aggregates was dependent on the neutralization degree of ASR. The rate of polymerization in ASR system was lower than that in SDBS system. This result can be explained by the creation of a hairy ASR layer around the particle surface, which decreases the diffusion rate of free radicals through this region. Although a decrease in particle size was observed, the rate of polymerization decreased with increasing ASR concentration. The higher the concentration of ASR is, the thicker and denser ASR layer may be, and the more difficult it would therefore be for radicals to reach the particle through this layer of ASR. The rate of polymerization decreased with increasing the neutralization degree of ASR. The aggregates with high neutralization of ASR are less efficient in solubilizing the monomer and capturing initiator radicals than that of the lower neutralization degree, which leads to decrease in rate of polymerization.

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Visualization of flowfield around Two Circular Cylinders by a Discrete Vortex Method (이산와법에 의한 2원주 주위의 유동장 가시화)

  • Ro Ki-Deok;Lee Young-Hoon;Son Yeong-Tae
    • 한국가시화정보학회:학술대회논문집
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    • 2002.11a
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    • pp.63-66
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    • 2002
  • The Flow patterns around two cylinders in various arrangements were studied by a discrete vortex method. The flow for the surface of each cylinder was represented by arranging bound vortices at adequate intervals. The viscous diffusion of fluid was represented by the random walk method. The vortex distributions, streaklines, timelines and velocity vectors around two cylinders were calculated for centre-to-centre pitch rations of P/D=1.5 and 2.5, attack angles of $\alpha=0^{\circ},\;30^{\circ},\;60^{\circ},\;and\;90^{\circ}$, correspond to the photographs by flow visualization and the flow intereference between two cylinders in var ious arrangements was clearly visualized by a numerical simulation.

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Latent Semantic Indexing Using Semantic Diffusion (의미 확산을 이용한 잠재 의미 색인 방법)

  • Kim, Jin-Hwa;Kim, Yong-Hyuk
    • Proceedings of the Korean Information Science Society Conference
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    • 2010.06c
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    • pp.16-21
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    • 2010
  • 잠재 의미를 색인하는 것은 문서 색인에 있어서 그 색인 품질에 주요한 요인을 차지한다. 본 논문에서 살펴보는 의미 확산 방법은 문서 집합에 나타나는 단어들의 의미적 연관성을 바탕으로 활성화 작용 모델(spreading activation model)을 구축하고 색인 대상 문서의 단어 분포를 출발점으로 삼아, 그 모델 안에서 의미적으로 수렴할 수 있도록 랜덤 워크 방법(random walk method)1)을 수정한 변형 방법을 이용해 확률을 확산시킨다. 이 방법은 단어 사이의 연관성을 따라 탐색하며 동의어와 다의어 등 단순 단어 일치로는 알 수 없는 의미적 유사 단어들이 의미 있는 확률 분포를 갖게 한다. 이는 단어들의 의미 분포를 가중치 그래프를 통해 보다 합리적으로 다루게 된다. 실험에서는 문서 분류를 시행하여 평균 정확도 및 정확도-재현율 곡선을 산출하였고, 비교 실험을 통해서 전반적인 우수성을 관찰할 수 있었다.

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Investigating nonlinear forced vibration behavior of multi-phase nanocomposite annular sector plates using Jacobi elliptic functions

  • Mirjavadi, Seyed Sajad;Forsat, Masoud;Barati, Mohammad Reza;Hamouda, A.M.S.
    • Steel and Composite Structures
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    • v.36 no.1
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    • pp.87-101
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    • 2020
  • A multi-scale epoxy/CNT/fiberglass annular sector plate is studied in this paper in the view of determining nonlinear forced vibration characteristics. A 3D Mori-Tanaka model is employed for evaluating multi-scale material properties. Thus, all of glass fibers are assumed to have uni-direction alignment and CNTs have random diffusion. The geometry of annular sector plate can be described based on the open angle and the value of inner/outer radius. In order to solve governing equations and derive exact forced vibration curves for the multi-scale annular sector, Jacobi elliptic functions are used. Obtained results demonstrate the significance of CNT distribution, geometric nonlinearity, applied force, fiberglass volume, open angle and fiber directions on forced vibration characteristics of multi-scale annular sector plates.

Phase Transitions and Phase Diagram of the Island Model with Migration

  • Park, Jeong-Man
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1219-1224
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    • 2018
  • We investigate the evolutionary dynamics and the phase transitions of the island model which consists of subdivided populations of individuals confined to two islands. In the island model, the population is subdivided so that migration acts to determine the evolutionary dynamics along with selection and genetic drift. The individuals are assumed to be haploid and to be one of two species, X or Y. They reproduce according to their fitness values, die at random, and migrate between the islands. The evolutionary dynamics of an individual based model is formulated in terms of a master equation and is approximated by using the diffusion method as the multidimensional Fokker-Planck equation (FPE) and the coupled non-linear stochastic differential equations (SDEs) with multiplicative noise. We analyze the infinite population limit to find the phase transitions from the monomorphic state of one type to the polymorphic state to the monomorphic state of the other type as we vary the ratio of the fitness values in two islands and complete the phase diagram of our island model.

An Improved Pseudorandom Sequence Generator and its Application to Image Encryption

  • Sinha, Keshav;Paul, Partha;Amritanjali, Amritanjali
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.16 no.4
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    • pp.1307-1329
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    • 2022
  • This paper proposes an improved Pseudorandom Sequence Generator (PRSG) based on the concept of modular arithmetic systems with non-integral numbers. The generated random sequence use in various cryptographic applications due to its unpredictability. Here the mathematical model is designed to solve the problem of the non-uniform distribution of the sequences. In addition, PRSG has passed the standard statistical and empirical tests, which shows that the proposed generator has good statistical characteristics. Finally, image encryption has been performed based on the sort-index method and diffusion processing to obtain the encrypted image. After a thorough evaluation of encryption performance, there has been no direct association between the original and encrypted images. The results show that the proposed PRSG has good statistical characteristics and security performance in cryptographic applications.

Enhanced ion-exchange properties of clinoptilolite to reduce the leaching of nitrate in soil

  • Kabuba, John
    • Analytical Science and Technology
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    • v.35 no.2
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    • pp.41-52
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    • 2022
  • The leaching of nitrate from soil increases the concentration of elements, such as nitrogen, phosphorus, and potassium, in water, causing eutrophication. In this study, the feasibility of using clinoptilolite as an ion-exchange material to reduce nitrate leaching in soil was investigated. Soil samples were collected from three soil depths (0 - 30, 30 - 90, and 90 - 120 cm), and their sorption capacity was determined using batch experiments. The effects of contact time, initial concentration, adsorbent dosage, pH, and temperature on the removal of NO3- were investigated. The results showed that an initial concentration of 25 mg L-1, a contact time of 120 min, an adsorbent dosage of 5.0 g/100 mL, a pH of 3, and a temperature of 30 ℃ are favorable conditions. The kinetic results corresponded well with a pseudo-second-order rate equation. Intra-particle diffusion also played a significant role in the initial stage of the adsorption process. Thermodynamic studies revealed that the adsorption process is spontaneous, random, and endothermic. The results suggest that a modification of clinoptilolite effectively reduces the leaching of nitrate in soil.

Travel Times of Radionuclides Released from Hypothetical Multiple Source Positions in the KURT Site (KURT 환경 자료를 이용한 가상의 다중 발생원에서의 누출 핵종의 이동 시간 평가)

  • Ko, Nak-Youl;Jeong, Jongtae;Kim, Kyung Su;Hwang, Youngtaek
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.4
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    • pp.281-291
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    • 2013
  • A hypothetical repository was assumed to be located at the KURT (KAERI Underground Research Tunnel) site, and the travel times of radionuclides released from three source positions were calculated. The groundwater flow around the KURT site was simulated and the groundwater pathways from the hypothetical source positions to the shallow groundwater were identified. Of the pathways, three pathways were selected because they had highly water-conductive features. The transport travel times of the radionuclides were calculated by a TDRW (Time-Domain Random Walk) method. Diffusion and sorption mechanisms in a host rock matrix as well as advection-dispersion mechanisms under the KURT field condition were considered. To reflect the radioactive decay, four decay chains with the radionuclides included in the high-level radioactive wastes were selected. From the simulation results, the half-life and distribution coefficient in the rock matrix, as well as multiple pathways, had an influence on the mass flux of the radionuclides. For enhancing the reliability of safety assessment, this reveals that identifying the history of the radionuclides contained in the high-level wastes and investigating the sorption processes between the radionuclides and the rock matrix in the field condition are preferentially necessary.

Probabilistic Service Life Analysis of GGBFS Concrete Exposed to Carbonation Cold Joint and Loading Conditions (탄산화에 노출된 GGBFS 콘크리트의 콜드 조인트 및 하중 재하를 고려한 확률론적 내구수명 해석)

  • Kim, Tae-Hoon;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.39-46
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    • 2020
  • Carbonation is a deterioration which degrades structural and material performance by permitting CO2 and corrosion of embedded steel. Service life evaluation through deterministic method is conventional, however the researches with probabilistic approach on service life considering loading and cold joint effect on carbonation have been performed very limitedly. In this study, probabilistic service life evaluation was carried out through MCS (Monte Carlo Simulation) which adopted random variables such as cover depth, CO2 diffusion coefficient, exterior CO2 concentration, and internal carbonatable materials. Probabilistic service life was derived by changing mean value and COV (Coefficient of variation) from 100 % to 300 % and 0.1 ~ 0.2, respectively. From the analysis, maximum reduction ratio (47.7%) and minimum reduction ratio (11.4%) of service life were obtained in cover depth and diffusion coefficient, respectively. In the loading conditions of 30~60% for compressive and tensile stress, GGBFS concrete was effective to reduce cold joint effect on carbonation. In the tensile condition, service life decreased linearly regardless of material types. Additionally service life rapidly decreased due to micro crack propagation in the all cases when 60% loading was considered in compressive condition.

Probabilistic Service Life Evaluation for OPC Concrete under Carbonation Considering Cold Joint and Induced Stress Level (콜드조인트 및 재하 응력을 고려한 탄산화에 노출된 OPC 콘크리트의 확률론적 내구수명평가)

  • Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.6
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    • pp.45-52
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    • 2019
  • Steel corrosion due to carbonation in RC (Reinforced Concrete) structures easily occurs in urban cities with high CO2 concentration. RC structures are always subjected to external loading with various boundary conditions. The induced stress level causes changes in diffusion of harmful ion like CO2. In this work, a quantification of carbonation progress with stress level is carried out and carbonation prediction is derived through the relations. Determining the design parameters like cover depth, CO2 diffusion coefficient, carbonatable materials, and exterior CO2 concentration as random variables, service lifes under carbonation with design parameter's variation are obtained through MCS(Monte Carlo Simulation). Additionally the service life with different stress level is derived and the results are compared with those from deterministic method. Cover depth and cement hydrates are evaluated to be very effective to resist carbonation, and the proposed method which can consider the effect of stress on service life can be applied to maintenance priority determination.