• 제목/요약/키워드: quicklime

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소각재 및 산업부산물을 이용한 직접 수성탄산화 반응 특성 (Characteristics of Direct Aqueous Carbonation Reaction Using Incinerated Ash and Industrial By-Products)

  • 박동규;한승만;최창식
    • 청정기술
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    • 제30권2호
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    • pp.113-122
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    • 2024
  • 본 연구에서는 이산화탄소 자원화의 일환으로 실험실 규모의 직접 수성탄산화 반응기를 이용하여 소각재와 더불어 탈황 석고, 저급 생석회 및 제강슬래그 등 다양한 알칼리성 산업부산물 6종을 대상으로 이산화탄소 포집 특성을 고찰하였다. 각 시료별 용해 특성과 더불어 반응 전, 후 열중량 분석을 통해 주요 반응 구조를 확인할 수 있었고, 이를 통해 반응성 CaO 함량을 정의하였다. 실험 결과, 생석회의 포집 용량 및 효율은 각각 473 g/kg, 86.9%로 결정할 수 있었으며, 탈황석고 및 소각재 역시 각각 51.1 ~ 131.7 g/kg, 51.2 ~ 87.7% 수준으로 비교적 높게 평가할 수 있다. 이에 반해 제강슬래그의 경우 생성 및 후처리 조건의 영향으로 포집 효율은 10% 미만으로 나타났으며 탄산화 공정 적용을 위해 생산 조건에 따른 영향에 대한 최적화가 요구된다. 본 연구를 통해 소각재를 비롯하여 생석회 및 탈황석고의 이산화탄소 포집특성이 이산화탄소 포집 공정 적용에 적절한 수준으로 판단할 수 있었으며, 이산화탄소전환 탄산칼슘의 건설소재 등 자원화 기술 개발의 기초자료를 확보할 수 있었다.

페로니켈슬래그 미분말 및 혼화재의 복합사용에 따른 모르타르의 강도 및 내구성 평가 (Evaluation of Strength and Durability of Mortar using Ferronickel Slag Powder and Admixtures)

  • 조설아;유정환;박상순
    • 한국건설순환자원학회논문집
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    • 제7권3호
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    • pp.262-270
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    • 2019
  • 본 논문에서는 페로니켈슬래그 미분말 및 혼화재의 복합사용에 따른 모르타르의 강도 및 내구성 평가를 실시하였다. 페로니켈슬래그 및 생석회, 석고, 염화칼슘을 OPC 대비 20%로 치환하여 복합사용 하였으며, 휨강도 및 압축강도, SEM분석을 통한 모르타르의 강도 평가를 실시하였다. 석고를 혼화재로 사용하였을 때 초기강도 발현은 보이지만, 페로니켈슬래그 및 생석회, 염화칼슘을 혼화재로 복합사용 하였을 때 강도발현과 강도증진효과가 극대화 되었으며, 혼화재의 적절한 복합사용이 미세한 공극 채움과 밀도개선효과로 인해 강도와 내구성 개선에 영향을 주는 것으로 판단된다. 또한 화학적침식저항성 및 XRD 분석을 통해 혼화재의 적절한 복합사용은 수화 생성물인 Muscovite의 함량에 따라 강도가 증가하는 경향을 보였고, 규산염은 산 알칼리에는 용해되지 않으므로 화학적 침식 저항 성능이 OPC에 비하여 우수한 것으로 사료된다.

장기적 건조수축에 의한 보강혼합토의 단위 중량 및 압축강도 분석 (Variation of Unit Weight and Compressive Strength by Long-Term Dry Shrinkage of Reinforced Soil Mixture)

  • 이상호;차현주;장병욱
    • 한국농공학회지
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    • 제42권6호
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    • pp.90-97
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    • 2000
  • In this study, the variation of unit weight and unconfined compressive strength were investigated, calcium carbonate, quicklime, portland cement, 19mm length monofilaments and fibrillated fiber were used as reinforcement materials. And calcium chloride was added to cement and calcium carbonate reinforced soil mixture in order to accelerate setting and hardening speed. It appears that unit weight is highest in calcium carbonate reinforced soil mixture with mixing rate of 9%. According to increasing the amount of fiber in soil mixture, the unit weight decreased. It shows that the more the amount of monofilament fiber is added in soil mixture, the higher the compressive strength is, but the compressive strength is decreased in fibrillated fibrillated fiber added soil mixture with more than 1.0% of mixing rate.

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파라핀 고화제를 이용한 하수 슬러지 고화처리를 위한 기본 연구 (Fundamental Study on the Solidification of Sewage Sludge by Paraffin Binder)

  • 정하익;조진우;임재상;김상길
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2000년도 가을 학술발표회 논문집
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    • pp.443-446
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    • 2000
  • The feasibility study on paraffin binder as a solidifying agent of digested sewage sludge cake was peformed. The availability of paraffin binder as a solidifying agent was investigated by several tests. Based on the tests, it is ascertained that paraffin binder with a small amount of quicklime and fly ash enhances the solidification of digested sewage sludge cake. Paraffin binder shortened the drying time of digested sewage sludge cake and solidified sludge with paraffin was not dissolved in water again. Also, the unconfined compressive strength of solidified sludge with paraffin increases.

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석회와 여러 첨가제에 의한 토질안정처리 (Soil-Lime and Additives Stabilization)

  • 민덕기;황광모;박근호
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2000년도 가을 학술발표회 논문집
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    • pp.657-664
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    • 2000
  • Weak and soft compressible clay deposits are commonly found in natural subgrade soils. These Soils need to be stabilized for using the subbase materials of highway constructions. This paper presents that a chemical treatment using chemical additives comprised of sulfate(SO$_4$) and chloride(Cl) is evaluated for stabilizing soft clay deposits and lime. The physical and mechanical characteristics of soil-lime and additives are described by means of a laboratory study. The study results indicate that the presence of chlorides encouraged the efficiency of lime stabilization, and the use of calcium chloride with quicklime is the best additive for improving soil behavior. The treated soil with lime-calcium chloride can have the adaptability to the subbase materials of highway constructions.

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Navigation based on Multi Cylindrical Environment Map

  • Park, Youngsup;Hyekyung Ko;Cheungwoon Cho;Kyunghyun Yoon
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2001년도 ICCAS
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    • pp.167.6-167
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    • 2001
  • The cylindrical environment maps of image-based representation methods make high-quality, simple and low-price real-time navigation possible. In this paper, we propose a method to navigate from one viewpoint to the next in the virtual inside space, composed of several cylindrical environment maps. Our system is classified into the two modules. first of all, the panoramic image viewer that employs the rotation and zoom-in/out methods to navigate the virtual inside space, such as the Quicklime VR. The other is smooth real-time navigation using cubic mesh interpolation when the viewpoint moves from one environment map to another in the virtual space.

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보강혼합토분의 물리적 특성 (Physical properties of Reinforced soil Mixture powder)

  • 이상호
    • 한국농공학회지
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    • 제42권5호
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    • pp.125-132
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    • 2000
  • This study was performed to evaluate the physical properties of reinforced soil mixture powder. Soil sample was prepared by passing into the standard sieve of No. 200 and reinforcement materials were calcium carbonate, quicklime and portland cement. Fineness, setting time, and compressive strength test for reinforced soil mixture powder were performed and analyzed to investigate their physical properties. The main results were summarized as follow. The compressive strength of soil mixture powder itself and most reinforced was reinforced according to increasing in the mixture rate of reinforcement and the rate of increase was remarkably higher in the cement reinforced soil moisture powder. It was appeared that the early compressive strength is considering higher in the cement reinforced soil moisture powder with 2% of moisture rate of accelerator.

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장기적 건조수축에 의한 보강혼합토의 밀도 및 강도 변화 (Variations of Density and Strength for Reinforced Soil Mixture by Long-Tern Dry Shrinkage)

  • 이상호;차현주;장병욱;박영곤
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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    • pp.239-244
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    • 1999
  • In this study , the variation of dry density and unconfined compressive strength were investigated, calcium carbonate, quicklime, portland cement, 19mm monofilaments and fibrilllated fibers were used as reinforcement materials. And calcium chloride was added to cement and calcium carbonate reinforced soil mixture in order to accelerate setting and hardening speed. It appears that dry density is highest in calcium carbonate reinforced soil mixture with 9% of mixing rae. According to increasing the amount of fibers, in soil mixture , the dry density decreased. The more the amount of monofilament fibers is the higher the compressive strength. But the compressive strength is decreased in fibrrillated fiber added soil mixture with more than 1.0% of mixing rate.

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보강혼합토분의 물리적 특성 (Physical Properties of Reinforced Soil-Mixture Powder)

  • 이상호;차현주;김철영;장병욱
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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    • pp.336-340
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    • 1999
  • This study was performed to evaluate the physical properties of reinforced soil-mixture powder. Soil was used to be powder that passed by the No. 200 mech and the reinforcement as calcium carbonate, quicklime and portland cement used for this study to improve soil. We resulted from fineness , setting time, and compressive strength test of reinforced soil-mixture powder. We've got the two conclusions . The first , in case that we were used reinforced soil-mixture powder included some portland cement, the higher the mixture rates of the reinforcement , the wider the difference theoretical data with experimental data. The second, the setting time of reinforced soil-mixture powder is faster than soil powder itself and the reinforcement for promoting strength was proved that calcium carbonate was proper than others if we compared it with other reinforcment.

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폐 광산 지역 중금속 오염 토양의 석회안정화 적용 시 용출특성 (A Leaching Characteristics on Lime Stabilization of Heavy Metal Contaminated Soil in a Waste Mine Area)

  • 어성욱
    • 한국물환경학회지
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    • 제27권6호
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    • pp.862-867
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    • 2011
  • Pozzolanic-based stabilization/solidification (S/S) is an effective and economic remediation technology to immobilize heavy metals in contaminated soils. In this study, quick lime (CaO) was used to immobilize cadmium and zinc present in waste mine contaminated clayey sand soils. Addition of 5% quicklime to the contaminated soils effectively reduced heavy metal leachability after 2 bed volume operation below the drinking water regulatory limits. Lime addition was revealed to increase the immobilization for all heavy metals in tested pH ranges, so it could be an optimal choice for short-term remediation of heavy metal contaminated soil. The mass balances for these column tests show metal reduction of 92% for Cd and 87% for Zn of total resolved mass in case of 5% lime application.