• Title/Summary/Keyword: quenching temperature

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CHILLING SENSITIVITY OF CUCUMBER PLANTS MONITORED IN TERMS OF CHLOROPHYLL FLUORESCENCE

  • Kang, In-Soon;Moon, Byoung-Yong;Seo, Kye-Hong;Chun, Hyun-Sik;Lee, Chin-Bum
    • Journal of Photoscience
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    • v.3 no.1
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    • pp.9-14
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    • 1996
  • For three cultivars of chilling-sensitive cucumber plants, chilling sensitivity was evaluated in terms of photosynthetic activity using Chl fluorescence techniques. Low-temperature treatment caused a decrease in photosynthetic activities of cucumber leaves, measured as CO$_2$ exchange, as well as the decrease in the stomatal conductance. FR of the three cultivars decreased after chilling for 24 h in light and the extent of decline of F$_R$ was the greatest in 'Chosaeng' cultivar. When these plants were recovered from light-chilling, 'Chosaeng' and 'Samchuk' cultivars did not fully restore the original value of F$_R$ after 24 h of recovery, in contrast to 'Ilmi' cultivar which showed a rather efficient recovery. The results of FR study showed that 'Chosaeng' was most susceptible, whereas Ilmi was most resistant, to chilling among the three cultivars of cucumber plants. When quenching coefficients for chlorophyll fluorescence was analyzed after chilling the cucumber plants for 24 h in light, 'Chosaeng' elicited more rapid declines in the coefficients for photochemical quenching (qQ), non-photochemical quenching (qNP) and energy-dependent quenching (qE) than 'Ilmi' and 'Samchuk'. The implications of these observations are discussed in relation to the growth habits of the respective cultivars in the field. The results showed that measurement of chlorophyll fluorescence was an effective means of screening chilling tolerance of cucumber plants. Furthermore, the study on the chlorophyll fluorescence induction and fluorescence quenching charactersitics showed that low temperature could accelerate inhibition of photosynthesis in chilling-sensitive plants, by limiting Calvin cycle activity and disrupting, in part, the energy dissipation mechanims of the photosystem II.

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Removal of residual ozone in drinking water treatment using hydrogen peroxide and sodium thiosulfate (과산화수소와 티오황산나트륨을 이용한 정수처리공정에서의 잔류오존 제거)

  • Kwon, Minhwan;Kim, Seohee;Ahn, Yongtae;Jung, Youmi;Joe, Woo-Hyun;Lee, Kyunghyuk;Kang, Joon-Wun
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.4
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    • pp.481-491
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    • 2015
  • The aim of this study was to evaluate the chemical quenching system for residual ozone and to determine the operating condition for the quenching system. Hydrogen peroxide ($H_2O_2$) and sodium thiosulfate ($Na_2S_2O_3$) were investigated as quenching reagents for ozone removal, and the tendency of each chemical was notably different. In the case of $H_2O_2$, the degradation rate of ozone was increased as the concentration of $H_2O_2$ increase, and temperature and pH value have a significant effect on the degradation rate of ozone. On the other hand, the degradation rate of ozone was not affected by the concentration of $Na_2S_2O_3$, temperature and pH value, due to the high reactivity between the ${S_2O_3}^{2-}$ and ozone. This study evaluates the decomposition mechanism of ozone by $H_2O_2$ and $Na_2S_2O_3$ with consideration for the water quality and reaction time. Furthermore, the removal test for the quenching reagents, which can be remained after reaction with ozone, was conducted by GAC process.

Effects of Stability and Volume Fraction of Retained Austenite on the Tensile Properties for Q&P and AM Steels (Q&P와 AM강의 잔류오스테나이트 분율과 안정도에 따른 인장특성 거동)

  • Byun, Sang-Ho;Oh, Chang-Suk;Nam, Dae-Geun;Kim, Young-Seok;Kang, Nam-Hyun;Cho, Kyung-Mox
    • Korean Journal of Materials Research
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    • v.19 no.6
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    • pp.305-312
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    • 2009
  • The effects of Quenching and Partitioning (Q&P) and Annealed Martensite (AM) heat treatment on the microstructure and tensile properties were investigated for 0.24C-0.5Si-1.5Mn-1Al steels. The Q&P steels were annealed at a single phase ($\gamma$) or a dual phase (${\gamma}+{\alpha}$), followed by quenching to a temperature between $M_s$ and $M_f$. Then, enriching carbon was conducted to stabilize the austenite through the partitioning, followed by water quenching. The AM steels were intercritically annealed at a dual phase (${\gamma}+{\alpha}$) temperature and austempered at $M_s$ and $M_s{\pm}50^{\circ}C$, followed by cooling in oil quenching. The dual phase Q&P steels showed lower tensile strength and yieldyield strength than those of the single phase Q&P steels, and tThe elongation for the dual phase Q&P steel was partitioning 100s higher than that of that for the single phase Q&P steels as the partitioning time was less than 100s up to partitioning 100s. For AM steels, the tensile/yield strength decreased and the total elongation increased as the austempering temperature increased. The stability of the retained austenite controlled the elongation for Q&P steels and the volume fraction of the retained austenite controlled the elongation for AM steels.

A Study on the Prediction of Thermally-Induced Residual Stress and Birefringence in Quenched Polystyrene Plate Including Free Volume Theory (자유 체적이론을 고려한 급냉 폴리스티렌판에 발생하는 잔류응력과 복굴절 형성에 관한 연구)

  • Kim, Jong-Sun;Yoon, Kyung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.1
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    • pp.77-87
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    • 2003
  • The residual stress and birefringence in injection-molded plastic parts can be divided into the flow-induced residual stress and birefringence produced in flowing stage, the thermally-induced residual stress and birefringence produced in cooling stage. However, the physics involved in the generation of the thermally-induced residual stress and birefringence still remains to be understood. Because polymer experiences viscoelastic history near the glass-transition temperature it is hard to model the entire process. Volume relaxation phenomenon was included to predict the final thermally-induced residual stress and birefringence in quenched plastic parts more accurately. The present study focused on comparing the predicted values far thermally-induced residual stress and birefringence with and without volume relaxation behavior (or free volume theory) under free and constrained quenching conditions. As a result, tile residual stress remained as a tensile stress at the center and as a compressible stress near the surface for the free quenching cases. In contract the residual stress remained as a compressible stress at the center and as a tensile stress near the surface fur the constrained quenching cases. The residual birefringence remained as minus values at the center and as plus values near the surface for the free quenching cases. Interestingly the residual birefringence showed minus values in entire zone for the constrained quenching cases. In the prediction of birefringence only the case including free volume theory showed the correct result for the distribution of birefringence in thickness direction.

Thin Film Thermal Sensor using Amorphous Chalcogenide Semiconductor (비정질 칼코게나이드 반도체를 이용한 박막온도센서)

  • Moon, H.D.;Lim, D.J.;Kim, H.Y.;So, D.S.;Lee, J.M.;Cho, B.H.;Kim, Y.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.727-730
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    • 2002
  • Chalcogenide glassy semiconductors(CGS) can be obtained by the melt quenching technique. We have investigated the thin film heterostructures : metal-chalcogenide glassy semiconductors, where metal is copper, and chalcogenide glassy semiconductors are glasses of the system As-Se. Cu/CGS film heterostructure were produced in the vacuum evaporator by the method of vacuum thermal evaporation. Doped films are very sensitive to external actions, and this property allows developing supersensitive precision sensors of temperature, humidity, illumination, and etc. based on them. Cu/CGS film has shown that resistance strongly depend on the temperature. The slop of temperature and resistance shows linear.

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A Study on the Heat Transfer of the High Temperature Metals in Quenching - The Latent Heat of Phase Transformation and Cooling Curves - (고온강재의 담금질 전열에 관한 연구)

  • 윤석훈
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.27 no.4
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    • pp.321-327
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    • 1991
  • Experiments of quenching were made with cylindrical specimens of carbon steel S45C of diameters from 12 to 30mm were performed. The specimens were heated by electric furnace and quenched by immersion method. In order to analyze the temperature profile(cooling curves) of carbon steel including the latent heat of phase transformation, nonlinear heat conduction problem was calculated by the numerical method of inverse heat conduction problem using the apparent heat capacity method. The difference between the calculated and the experimented cooling curves was caused by the latent heat of phase transformation, and the effects of the latent heat were especially manifest at the cooling curves of center of specimens. The temperature and the quantity of the latent heat of phase transformation depend on the cooling speed at A sub(1) transformation point, and the region for cooling speed to become zero was caused by the latent heat of phase transformation.

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Effect of Heat Treatments on the Microstructures and Mechanical Properties of OCTG (유정용 강관의 미세조직 및 기계적 성질에 미치는 열처리의 영향)

  • Choi, Jong-Min;Noh, Sang-Woo;Yi, Won-Jae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.5
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    • pp.252-261
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    • 2017
  • This study examined the effect of heat treatment on the microstructure and mechanical properties of J55 line pipe steel. The experiments were carried out at under the following various conditions: austenization temperature($880^{\circ}C$, $910^{\circ}C$, $940^{\circ}C$), cooling methods(water quenching, oil quenching) and tempering temperature(none, $550^{\circ}C$, $650^{\circ}C$). The phase diagram and CCT curve were simulated based on the chemical composition of J55 steel to predict the microstructures. In the results, A1, A3 temperature decreased. As the austenization temperature increased, existing austenite grains grew exponentially which seriously degraded their mechanical properties. Various microstructures, including martensite, bainite, ferrite, and pearlite, developed in accordance with the heat treatments and were closely correlated with hardness, tensile strength and toughness. Martensite was formed after water quenching, but bainite and ferrite appeared after oil quenching. FeC precipitation formed and coarsened during tempering, which improved their toughness.

PROPERTIES OF ZR ALLOY CLADDING AFTER SIMULATED LOCA OXIDATION AND WATER QUENCHING

  • Kim, Hyun-Gil;Kim, Il-Hyun;Jung, Yang-Il;Park, Jeong-Yong;Jeong, Yong-Hwan
    • Nuclear Engineering and Technology
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    • v.42 no.2
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    • pp.193-202
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    • 2010
  • In order to study the cladding properties of zirconium after a loss-of-coolant accident (LOCA)-simulation oxidation and water quenching test, commercial Zircaloy-4 and two kinds of HANA claddings were oxidized at temperatures ranging from $900^{\circ}C$ to $1250^{\circ}C$ and exposed for 300 s, and then cooled to $700^{\circ}C$ before quenching. Microstructural observations were made to evaluate the matrix characteristics with the chemical compositions after the LOCA-simulation test. Ring compression testing was then performed to compare the ductile behaviour of the HANA and Zircaloy-4 claddings. An X-ray diffraction (XRD) analysis was carried out for temperatures ranging from room temperature to $1250^{\circ}C$ for the oxide layer to verify the oxide crystal structure at each oxidation temperature.

THERMAL SHOCK FRACTURE OF SILICON CARBIDE AND ITS APPLICATION TO LWR FUEL CLADDING PERFORMANCE DURING REFLOOD

  • Lee, Youho;Mckrell, Thomas J.;Kazimi, Mujid S.
    • Nuclear Engineering and Technology
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    • v.45 no.6
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    • pp.811-820
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    • 2013
  • SiC has been under investigation as a potential cladding for LWR fuel, due to its high melting point and drastically reduced chemical reactivity with liquid water, and steam at high temperatures. As SiC is a brittle material its behavior during the reflood phase of a Loss of Coolant Accident (LOCA) is another important aspect of SiC that must be examined as part of the feasibility assessment for its application to LWR fuel rods. In this study, an experimental assessment of thermal shock performance of a monolithic alpha phase SiC tube was conducted by quenching the material from high temperature (up to $1200^{\circ}C$) into room temperature water. Post-quenching assessment was carried out by a Scanning Electron Microscopy (SEM) image analysis to characterize fractures in the material. This paper assesses the effects of pre-existing pores on SiC cladding brittle fracture and crack development/propagation during the reflood phase. Proper extension of these guidelines to an SiC/SiC ceramic matrix composite (CMC) cladding design is discussed.

A Thermodynamic Study on the Interaction of Quinolone Antibiotics and DNA

  • Lee, Byung-Hwa;Yeo, Ga-Young;Jang, Kyeung-Joo;Lee, Dong-Jin;Noh, Sang-Gyun;Cho, Tae-Sub
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1031-1034
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    • 2009
  • Fluorescence of quinolones including norfloxacin, ciprofloxacin and S- and R-ofloxacin is quenched upon association with single and double-stranded DNA (ss- and ds-DNA). The ratios of fluorescence intensity in the presence of DNA to its absent were plotted with respect to the DNA concentration to construct the Stern-Volmer plot. The slope of the Stern-Volmer plot become larger as the temperature is lowered, ensuring that the fluorescence quenching is static process, i.e., the fluorescence is quenched by formation of the non-fluorescent complex between quinolone and DNA. In the static quenching mechanism, the quenching constant which is equivalent to the slope of the Stern-Volmer plot, is considered as the equilibrium constant for the association of quinolones and DNA. From the temperature-dependent equilibrium constant, ${\Delta}H^0\;and\;{\Delta}S^0$ was obtained using the van’t Hoff relation. In general, association of the quinolone with ds- as well as ss-DNA is energetically favorable (an exothermic) process while the entropy change was unfavorable. Due to the steric effect of the substituents, the effect of the quinolone ring is smaller on the ss-DNA compared to ds-DNA.