• Title/Summary/Keyword: quenching

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A Pyrenylboronic Acid-based Fluorescence Sensor for Highly Efficient Detection of Mercury(II) Ions (효율적인 수은이온 검출을 위한 피렌-보론산 기반의 형광센서 개발)

  • Lee, Seung Yeob;Lee, Seoung Ho
    • Journal of Environmental Science International
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    • v.29 no.2
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    • pp.201-207
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    • 2020
  • A new chemosensor based on a self-assembled system has been devised to detect Hg2+ions efficiently. We demonstrated that the amphiphilic building blocks consisting of pyrene and boronic acid (1) aggregate in aqueous solutions and provide an outstanding sensing platform for sensitive detection. The self-assembled 1 exhibited high selectivity and sensitivity for Hg2+ion detection via fluorescence quenching, where the Hg2+ion detection ensued from a fast transmetallation of 1. The Stern-Volmer (SV) quenching constant for its fluorescence quenching by Hg2+ions was approximately 1.58 × 108 M-1. In addition, self-assembled 1 exhibited excellent sensing abilities at nano-molar concentration levels when tap water and freshwater samples were contaminated with of Hg2+ ions.

A Study on the Heat Transfer of Carbon Steels in Quenching (탄소강의 담금질 열전달에 관한 연구)

  • 김경근;윤석훈
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.2
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    • pp.20-26
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    • 1995
  • The very rapid cooling problem from $820^{\circ}$C to $20^{\circ}$C on the surface of the steel by thermal conduction including the latent heat of phase transformation of steel and by transient boiling heat transfer of water are considered to principal problem in quenching. The transient boiling process of water at the surface of specimen during the quenching process were experimentally analyzed. Then the heat flux was numerically calculated by the numerical method of inverse heat condition problem. In this report, the simulation program to calculate the cooling curves for large rolls was made using the subcooled transient boiling curve as a boundary condition. By this simulation program, the cooling curves of rolls from D=50mm to D=200mm were calculated and the effects of agitation of circulation of water also investigated.

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Modeling for a Coke Dry Quenching Process Using a Theory of a Porous Material (다공질 물질의 냉각현상 연구를 통한 코크스냉각공정의 모델링)

  • Kim, Joo-Han;Lee, Yong-Ju;Kim, Ki-Seok
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.5
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    • pp.697-701
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    • 2012
  • Numerical modeling for a coke dry quenching process was developed and evaluated. The cokes had similar characteristics to a porous material, therefore, its quenching analysis was simplified as a cooling process of porous blocks. A uniform inlet temperature and constant properties of materials in the oven were also assumed. With given operating conditions, temperature profiles in the cokes were calculated and compared to the actual values. The calculated temperature gradient was high at the upper part of the coke flow and the cooling rate decreased as cokes came down to the exit port. The exit port temperature of cokes was similar to the measured value, however, temperature-dependent material properties and operating conditions must be considered to predict the temperature precisely. The calculated results could be applied to design a coke oven to produce high quality cokes.

A Theoretical and Experimental Investigation into Pair-induced Quenching in Bismuth Oxide-based Erbium-doped Fiber Amplifiers

  • Jung, Min-Wan;Shin, Jae-Hyun;Jhon, Young-Min;Lee, Ju-Han
    • Journal of the Optical Society of Korea
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    • v.14 no.4
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    • pp.298-304
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    • 2010
  • The pair-induced quenching (PIQ) effect in a highly doped bismuth oxide-based erbium-doped fiber amplifier (EDFA) was theoretically and experimentally investigated. In the theoretical investigation, the bismuth oxide-based EDFA was modeled as a 6-level amplifier system that incorporated clustering-induced concentration quenching, cooperative up-conversion, pump excited state absorption (ESA), and signal ESA. The relative number of paired ions in a highly doped bismuth oxide EDF was estimated to be ~6.02%, determined by a comparison between the theoretical and the experimentally measured gain values. The impacts of the PIQ on the gain and the noise figure were also investigated.

Development of High-Temperature Heat Flux Gauge for Steel Quenching (강재 급속냉각용 고온 열유속게이지 개발)

  • Lee, Jungho
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.6
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    • pp.323-330
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    • 2010
  • The present study was motivated by increasing demands on quantitative measurements of the heat flux through the water cooling and quenching process of hot steel. The local heat flux measurements are employed by a novel experimental technique that has a function of high-temperature heat flux gauge in which test block assemblies are directly used to measure the heat flux variation during water cooling and quenching of hot steel. The heat flux can be directly achieved by Fourier's law and is also compared with numerical estimation which is solved by inverse heat conduction problem (IHCP). The high-temperature heat flux gauge developed in this study can be applicable to measure cooling rate and history during the actual cooling applications of steelmaking process. In addition, the measurement uncertainty of heat flux is calculated by a quantitative uncertainty analysis which is based on the ANSI/ASME PTC 19.1-2005 standard.

A Study on the critical cooling rate to avoid carbide precipitation in austenitic manganese steels during quenching (고망간 주강품의 열처리시 탄화물 석출방지를 위한 임계 냉각속도에 관한 연구)

  • Kim, Jeong-Tae;Kwahk, Si-Young;Choi, Jeong-Kil;Hong, Chun-Pyo
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.3
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    • pp.206-214
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    • 1999
  • The effect of cooling rate on carbide precipitation during quenching of austenitic manganese steel was investigated by optical microscopy, image analyzer and numerical analysis. A computer program based on the finite difference method for analyzing heat treatment processes was developed in order to evaluate cooling rates and the possibility of carbide precipitation during quenching. The area ratio of carbide precipitated in the austenite matrix was measured by the image analyzer, and used to determine the critical point of carbide precipitation. Temperature-dependent critical cooling rates at the critical points were calculated using the present simulation program, The calculated results showed a good agreement with the experimental ones.

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A Study on Improving Arc Quenching Performance of MCCB by FEM (유한요소법을 이용한 배선용 차단기의 아크소호 성능향상에 관한 연구)

  • Kim, Kil-Sou;Lim, Kee-Joe;Kang, Seong-Hwa;Cho, Hyun-Kil;Lee, Gang-Won;Park, Jung-Nam
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.51-54
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    • 2001
  • This Paper is described basic principles of arc quenching in Molded Case Circuit Breaker. We analyzed magnetic blowout forces acting on the arc in contact system when circuit breakers interrupt fault currents in different three models by 3-D FEM(Finite Element Method). The interrupting time simulated is compared with that of short circuit tests. The results of this study derive valid of the simulation method and present the techniques to improve arc quenching performance.

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Combustion Characteristics in Small Combustion Chamber Size about Quenching Distance (소염 거리에 근접하는 소형 연소실 환경에서의 연소특성)

  • Lee, Dae-Hoon;Choi, Kwon-Hyoung;Kwon, Se-Jin
    • Journal of the Korean Society of Combustion
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    • v.5 no.2
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    • pp.63-68
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    • 2000
  • Combustion phenomenon in scale-downed combustor is investigated. As the combustor scale decreases surface to volume ratio increases and chamber size approaches quenching distance. As the combustor scales down surface to volume ratio increases resulting increased heat loss. And this heat loss can affect quenching and instability of the flame. To investigate this effect plastic mini combustor is made. Stoichiometricaly premixed Hydrogen / air gas is used as fuel. Initial chamber pressure and chamber size are varied and the effects are evaluated. Peak pressure decreased with the decrease in chamber height. As initial chamber pressure decreases peak pressure decreases and this change is more important than scale down effect till the chamber height of 1mm. With this result and further information following the experiments design parameter for micro engine can be established.

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Detection of Nitroaromatic Compounds with Functionalized Porous Silicon Using Quenching Photoluminescence

  • Cho, Sungdong
    • Journal of Integrative Natural Science
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    • v.3 no.4
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    • pp.202-205
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    • 2010
  • Nanocrystalline porous silicon surfaces have been used to detect nitroaromatic compounds in vapor phase. The mode of photoluminescence is emphasized as a sensing attitude or detection technique. Quenching of photoluminescence from nanocrystalline porous surfaces as a transduction mode is measured upon the exposure of nitroaromatic compounds. Reversible detection mode for nitroaromatics is, too, observed. To verify the detection afore-mentioned, photoluminescent freshly prepared porous silicons are functionalized with different groups. The mechanism of quenching of photoluminescence is attributed to the electron transfer behaviors of quantum-sized nano-crystallites in the porous silicon matrix to the analytes(nitroaromatics). An attempt has been done to prove that the surface-derivatized photoluminescent porous silicone surfaces can act as versatile substrates for sensing behaviors due to having a large surface area and highly sensitive transduction mode.

Improved Circuits for Single-photon Avalanche Photodiode Detectors

  • Kim, Kyunghoon;Lee, Junan;Song, Bongsub;Burm, Jinwook
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.14 no.6
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    • pp.789-796
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    • 2014
  • A CMOS photo detection bias quenching circuit is developed to be used with single photon avalanche photodiodes (SPADs) operating in Geiger mode for the detection of weak optical signals. The proposed bias quenching circuits for the performance improvement reduce the circuit size as well as improve the performance of the quenching operation. They are fabricated in a $0.18-{\mu}m$ standard CMOS technology to verify the effectiveness of this technique with the chip area of only $300{\mu}m^2$, which is about 60 % of the previous reported circuit. Two types of proposed circuits with resistive and capacitive load demonstrated improved performance of reduced quenching time. With a commercial APD by HAMAMATSU, the dead time can be adjusted as small as 50 ns.