• 제목/요약/키워드: quenching

검색결과 1,437건 처리시간 0.031초

산화제 제어 확산화염의 화염구조 및 NO 생성 특성에 관한 수치해석적 연구 (Numerical Study on Flame Structure and NO Formation Characteristics in Oxidizer-Controlled Diffusion Flames)

  • 이창언;한지웅
    • 대한기계학회논문집B
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    • 제26권5호
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    • pp.742-749
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    • 2002
  • Numerical Study with detailed chemistry has been conducted to investigate the flame structure and NOx formation characteristics in oxygen -enhanced(CH$_4$/O$_2$-$N_2$) and oxygen-enhanced-EGR(CH$_4$/O$_2$-$CO_2$) counter diffusion flame with various strain rates. A small amount of $N_2$is included in oxygen-enhanced-EGR combustion, in order to consider the inevitable $N_2$contamination by $O_2$production process or air infiltration. The results are as follows : In CH$_4$/O$_2$-$CO_2$flame it is very important to adopt a radiation effect precisely because the effect of radiation changes flame structure significantly. In CH$_4$/O$_2$-$N_2$flame special strategy to minimize NO emission is needed because it is very sensitive to a small amount of $N_2$. Special attention is needed on CO emission by flame quenching, because of increased CO concentration. Spatial NO production rate of oxygen-enhanced combustion is different from that of air and oxygen-enhanced-EGR combustion in that thermal mechanism plays a role of destruction as well as production. In case CH$_4$/O$_2$-$CO_2$flame contains more than 40% $CO_2$it is possible to maintain the same EINO as that of CH$_4$/Air flame with accomplishing higher temperature than that of CH$_4$/Air flame. EINO decreases with increasing strain rate, and those effects are augmented in CH$_4$/O$_2$flame.

산화제 제어 화염의 구조 및 NO 생성 특성 (Structure and NO formation characteristics of oxidizer-controlled diffusion flames)

  • 한지웅;이창언
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집B
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    • pp.185-190
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    • 2001
  • Numerical Study with detailed chemistry has been conducted to investigate the flame structure and NOx formation characteristics in oxygen-enhanced$(CH_4/O_2-N_2)$ and oxygen-enhanced-EGR$(CH_4/O_2-CO_2)$ counter diffusion flame with various strain rates. A small amount of $N_2$ is included in oxygen-enhanced-EGR combustion, in order to consider the inevitable $N_2$ contamination by $O_2$ production process or air infiltration. The results are as follows : In $CH_4/O_2-CO_2$ flame it is very important to adopt a radiation effect precisely because the effect of radiation changes flame structure significantly. In $CH_4/O_2-N_2$ flame special strategy to minimize NO emission is needed because it is very sensitive to a small amount of $N_2$. Special attention is needed on CO emission by flame quenching, because of increased CO concentration. Spatial NO production rate of oxygen-enhanced combustion is different from that of air and oxygen-enhanced-EGR combustion in that thermal mechanism plays a role of destruction as well as production. In case $CH_4/O_2-CO_2$ flame contains more than 40% $CO_2$ it is possible to maintain the same EINO as that of $CH_4/Air$ flame with accomplishing higher temperature than that of $CH_4/Air$ flame. EINO decreases with increasing strain rate, and those effects are augmented in $CH_4/O_2$ flame. Complementary study is needed with extending the range of strain rate variation.

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유압 피스톤 펌프 소재의 피로특성 연구 (Study on Fatigue Property of Material for Oil Hydraulic Piston Pump)

  • 김남석;남기우;김현수
    • 대한기계학회논문집A
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    • 제35권5호
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    • pp.555-559
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    • 2011
  • 본 연구는 유압 피스톤 펌프 재료로 사용되고 있는 SACM645소재를 사용하여 모재, QT(quenching & tempering) 시험편 및 QT 질화시험편의 피로특성을 조사하였다. 피로특성 조사결과는 다음과 같다. QT 질화시험편은 피로한도가 인장강도의 80%로 나타나 아주 높은 값을 나타내었다. 이것은 시험편 표면에 단단한 질화처리를 실시하여 피로균열의 발생을 지연시켰고, 피로균열이 발생하더라고 소재가 단단하여 균열진전속도가 늦었다고 판단된다. 파면 관찰결과 피로균열진전 영역에서는 모두 스트라이에이션이 관찰되었고, 피로균열진전 이외의 영역에서 QT 시험편은 벽개파괴의 양상을, 모재와 Qt 질화시험편은 딤플 파괴의 양상을 나타내었다.

초소형 정적 연소기에서의 연소 한계에 대한 실험적 연구 (Experiment on the Limit Scale of Combustion in Constant Volume Micro Combustor)

  • 나한비;권세진;김세훈;이대훈
    • 한국추진공학회지
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    • 제7권4호
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    • pp.27-32
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    • 2003
  • 초소형 정적 연소기의 연소 성능에 대한 실험을 수행하였다. 연소기 형상과 크기의 영향을 알아보기 위해 몇 가지 형태의 연소기를 제작하였다. 연소기는 납작한 원통형 정적 연소기로써 연소기의 지름이 15mm인 경우에 대해서 높이가 1mm, 2mm, 3mm인 것을 제작하였고, 지름의 영향을 알아보기 위해서 연소기의 높이와 지름이 각각 2mm 와 7.5mm 인 것을 제작하였다. 사용된 연료는 당량비 1인 메탄과 공기의 혼합기체와 당량비 1과 2인 수소와 공기 혼합 기체이다 실험을 통하여 연소중의 압력 변화를 측정하였다. 최대 압력은 연소기의 높이와 초기 압력이 증가할수록 증가하였다 화염의 전파를 쉴리렌 방법을 이용하여 가시화를 하였다. 열손실의 영향을 극복하고 화염의 전파가 가능하게 하는 초기 압력을 제시하였다.

Composition Effect of the Outer Layer on the Vesicle Fusion Catalyzed by Phospholipase D

  • Park, Jin-Won
    • Bulletin of the Korean Chemical Society
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    • 제35권12호
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    • pp.3509-3513
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    • 2014
  • Phospholipase D (PLD) catalyzed the generation of phosphatidic acid (PA) from phosphatidylcholine (PC) at the outer layer of the vesicles prepared through layer by layer via a double emulsion technique. The generation induced a curvature change in the vesicles, which eventually led them to fuse each other. The ratio of two-fatty-acid-tail ethanolamine (PE) to one-fatty-acid-tail ethanolamine (PE) was found to acquire the condition where the mixed-phospholipid vesicles were stable identically with pure two-fatty-acid-tail PC. The effect of the outer-layer mixture on the PLD-induced vesicle fusion was investigated using the fluorescence intensity change. 8-Aminonaph-thalene-1,3,6-trisulfonic acid disodium salt (ANTS) and p-Xylene-bis(N-pyridinium bromide) (DPX) were encapsulated in the vesicles, respectively, for the quantification of the fusion. The fluorescence scale was calibrated with the fluorescence of a 1/1 mixture of ANTS and DPX vesicles in NaCl buffer taken as 100% fluorescence (0% fusion) and the vesicles containing both ANTS and DPX as 0% fluorescence (100% fusion), considering the leakage into the medium studied directly in a separate experiment using vesicles containing both ANTS and DPX. The fusion data for each composition were acquired with the subtraction of the leakage from the quenching. From the monitoring, the vesicle fusion caused by the PLD reaction seems dominantly to occur rather than the vesicle lysis, because the composition effect on the fusion was observed identically with that on the change in the vesicle structure. Furthermore, the diameter measurements also support the fusion dominancy.

건강 에틸아세테이트 분획의 예쁜꼬마선충 내의 항산화 효과 (Anti-oxidative Activity of Ethyl acetate Fraction of the Dried Ginger in Caenorhabditis elegans)

  • 이은별;김준형;임재윤;김혜수;김대성;은재순;한순천;김대근
    • 생약학회지
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    • 제47권2호
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    • pp.179-185
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    • 2016
  • Ginger (Zingiber officnale Roscoe, Zingiberaceae), which is a well-known food seasoning, has been used as a traditional medicine for the treatment of gastrointestinal disorder, vomiting and cough in Korea, China and Japan. Ethanol extract from the dried ginger (DG) was successively partitioned as methylene chloride, ethyl acetate, n-butanol and $H_2O$ soluble fractions. Among those fractions the ethyl acetate soluble fraction (EDG) showed the most potent DPPH radical scavenging and superoxide quenching activities. To know the effect of antioxidant activities of EDG, we tested the activities of superoxide dismutase (SOD) and catalase together with oxidative stress tolerance and intracellular ROS level in Caenorhabditis elegans. To investigate whether EDG-mediated increased stress tolerance was due to regulation of stress-response gene, we quantified SOD-3 expression using transgenic strain including CF1553. Consequently, EDG elevated SOD and catalase activities of C. elegans, reduced intracellular ROS accumulation in a dose-dependent manner. Moreover, EDG-treated CF1553 worms exhibited significantly higher SOD-3::GFP intensity.

Evaluation of biochemical and free radical scavengers of Digitaria exilis L. under osmotic stress

  • Oyinade A., David;Oluwole, Osonubi;Jacob, Oyetunji Olusola
    • Journal of Plant Biotechnology
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    • 제46권4호
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    • pp.331-337
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    • 2019
  • Digitaria exilis L. is an under-utilized crop with high nutritional and medicinal values. It thrives in and is well-adapted to arid areas with low soil nutrients. Using biochemical markers, this study investigates the mechanisms by which D. exilis responds to osmotic stress. Three accessions Dinat Iburua (DIN), Jakah Iburua (JAK) and Jiw Iburua (JIW) were collected from National Cereal Research Institute, Niger State. Two accessions, NG/11/JD/061 and NG/11/JD/062 were also collected from National Centre for Genetic Resources and Biotechnology, Ibadan. Murashige and Skoog medium of approximately 1.2 L was supplemented with polyethylene glycol 6000 to create osmotic pressures of -9.29, -13.93, -20.13, -26.32, -32.51, and 0 MPa (control). Sterilized seeds were inoculated in the medium and placed in the growth room for 4 weeks. Proline accumulation was significantly high in all JAK plants under osmotic stress. Proline and ascorbate peroxidase (p<0.05) activities were directly correlated, thus reinforcing the survivability of JAK during stress. Catalase (CAT) activity was also significantly induced in JAK under osmotic stress, which synergistically improved its tolerability. As a result, >50% of OH-, H2O2, and NO radicals were scavenged. However, other accessions including DIN, NG061, NG062, and JIW showed variations in their responses to different levels of osmotic stress, although not significant. Therefore, JAK possesses a well-equipped free radical quenching system that is protected by the accumulation of the osmolyte proline; therefore, accession JAK is considered osmotolerant. CAT and superoxide dismutase activities were osmostabilized against oxidative stress by proline.

쌍로울형 박판연속주조공정의 개발과 자동화에 관한 연구 (The Study on Automation and Development of Strip Continuous Casting by Twin Roller Type)

  • 이상매;김영도;백남주;강충길
    • 한국정밀공학회지
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    • 제7권1호
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    • pp.37-52
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    • 1990
  • In this study, the characteristics of cooling and rolling during strip casting process is obtained in comparison with the experimental and analytical results. The prupose of this study is to effectively analyze the thermal and mechanical deformation of roller applying the results of the heat transfer and the pressure distribution to boundary conditions. And then the relation between strip thickness and roll deformation is shown. The second purpose is to obtain the proper condition of the continuous casting for stainless steel. The summary and conclusions can be made on the basis of the results obtained by the theories and experiments. a) The strip casting condition for the fine surface quality of tin-alloy as-cast material was obtained in accordance with the velocity of roll rotation and initial roll gap. b) The experimental condition that the dimension of the cast strip thickness coincide with that of the initial roll gap was according to the experimental result of continuous casting by twin-roll type. c) The thermoelastic finite element model to calculate the roll deformation is represented. Thermoelastic model prediction for the roll deformation are in good agreement with the experimental results considering the thermal expansion of the roll. d) The higher cooling rates were obtained by a twin-roller quenching technique. Also quenched microstructure of the rapidly solidified shell was verified. e) The magnitude of roll deformation due to the thermal expansion and roll separating force is quantit- atively represented in the analysis of continuous casting for stainless steel.

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Effect of Electron Accepters on Step-up Photophobic Responses of Blephalisma japonicum

  • Youssef, Tareq;Angelini, Nicola;Gioffre, Domenico;Sgarbossa, Antonella;Lenci, Francesco
    • Journal of Photoscience
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    • 제7권1호
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    • pp.1-4
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    • 2000
  • The photosensory ciliates Blepharisma japonicum and Stentor coeruleus use the hypericin-derived pigments blepharismin and stentorin, respectively, as photoreceptor chromophores. Fluorescence quenching studies have shown that the first excited singlet state of hypericin and the purified chromophores blepharismin and stentorin can be deactivated by electron transfer to an acceptor molecule with a suitable reducing potential [1,2]. This paper reports the result of a series of photobehavioral experiments performed with the aim to ascertain if the same electron accepters which quench the photoreceptor pigment fluorescence in vitro may also compete with the native acceptor molecule in its natural physiological environment. Individual cell trajectories were examined before and after light stimulation, in the presence and in the absence of potential "in vivo" electron accepters, with a microvideo-recording apparatus. Our data, on Blepharisma cells, showed that as the negative reduction potential of the electron acceptor increases, a pronounced decrease in cell photoresponsiveness was detected. A dramatic effect on cell photoresponsiveness was noticed in the presence of 1,4-benzoquinone that has the lowest negative reduction potential. Such an effect on the percentage of photoreacting cells was moderate in the case of 1,4-naphthoquinone, with a relatively higher negative reduction potential. In the presence of benzophenone, which has the highest negative reduction potential, no significant effect on photoreacting cells was noticed. Our results can support the hypothesis that in the pigment granules such a light-induced charge transfer from excited blepharismin to a suitable electron acceptor triggers sensory transduction processes in B. japonicum.

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The Limited Impact of AGN Outflows: IFU study of 20 local AGNs

  • Bae, Hyun-Jin;Woo, Jong-Hak;Karouzos, Marios;Gallo, Elena;Flohic, Helene;Shen, Yue;Yoon, Suk-Jin
    • 천문학회보
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    • 제42권1호
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    • pp.28.1-28.1
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    • 2017
  • To investigate AGN outflows as a tracer of AGN feedback on the host galaxies, we perform integral-field spectroscopy of 20 type 2 AGNs at z<0.1 using the Magellan/IMACS and the VLT/VIMOS. The observed objects are luminous AGNs with the [O III] luminosity >$10^{41.5}erg/s$, and exhibit strong outflow signatures in the [O III] kinematics. We obtain the maps of the narrow and broad components of [O III] and $H{\alpha}$ lines by decomposing the emission-line profile. The broad components in both [O III] and $H{\alpha}$ represent the non-gravitational kinematics, (i.e., gas outflows), while the narrow components represent the gravitational kinematics (i.e., rotational disks), especially in $H{\alpha}$. By using the spatially integrated spectra within the flux-weighted size of the narrow-line region, we estimate the outflow energetics. The ionized gas mass is $(1.0-38.5){\times}10^5M_{\odot}$, and the mean mass outflow rate is $4.6{\pm}4.3M_{\odot}/yr$, which is a factor of ~260 higher than the mean mass accretion rate $0.02{\pm}0.01M_{\odot}/yr$. The mean energy injection rate is $0.8{\pm}0.6%$ of the AGN bolometric luminosity Lbol, while the mean momentum flux is $(5.4{\pm}3.6){\times}L_{bol}/c$, except for two most kinematically energetic AGNs. The estimated energetics are consistent with the expectations for energy-conserving outflows from AGNs, yet we do not find any supporting evidence of instantaneous star-formation quenching due to the outflows.

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