• Title/Summary/Keyword: quasi-cyclic

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Semi-Circular Potential Sweep Voltammetry: Electrochemically Quasi-Reversible System

  • Park, Kyungsoon;Hwang, Seongpil
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.379-383
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    • 2020
  • The novel voltammetry using a semi-circular potential wave for quasi-reversible charge transfer system on electrode is theoretically investigated. Compared with conventional voltammetry based on linear sweep such as linear sweep voltammetry (LSV), semi-circular potential sweep voltammetry (SCV) may decrease the charging current outside the center of potential range and increase the faradaic current at the midpoint due to variable scan rate. In this paper, we investigate the system based on macroelectrode where simple 1 dimensional (1 D) diffusion system is valid with various charge transfer rate constant (k0). In order to observe the amplification at midpoint, voltammetric response with different midpoint ranging from -200 mV to 200 mV are studied. SCVs shows both the shift of peak potential and the amplification of peak current for quasi-reversible electrode reaction while only higher peak current is observed for reversible reaction. Moreover, the higher current at midpoint enable the amplification of current at low overpotential region which may assist the determination of onset potential as a figure-of-merit in electrocatalyst.

A Study on the 4-level quasi-geostropic numerical model (4층 준지균 수치모형에 관한 연구)

  • 이우진;이천우
    • Water for future
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    • v.17 no.3
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    • pp.211-219
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    • 1984
  • A 4-level baroclinic numerical model is designed by using the vorticity equation and Omega equation. Block-Cyclic-Reduction method is applied to the solution of the Helmholtz defferential equation, which is proved to be better than the Relaxation method from the composite viewpoint of accuracy, stability and economy. It was investigated whether the model explains the physical process influenced by voricity and temperature advection. It was also examined if the model atmosphere describes the general circulation. This examination is similar to Phillips(1956). The result of this numerical experiment shows that the model explains qualitatively the Quasi-Geostrophic theory for the development of Baroclinic wave, as throughly described in Holton(1972).

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Experimental Study on Seismic Resistance of A Unreinforced Cement Brick Building (비보강 시멘트벽돌 건물의 내진성능 실험연구)

  • 김장훈
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2000.04a
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    • pp.298-307
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    • 2000
  • The behavior of a unreinforced cement brick building structure subjected to earthquake loading was experimentally investigated. for this four full size wall specimens were tested under quasi-static in-plane cyclic loading. Experimental observations indicate that the failure modes of unreinforced masonry walls are principally governed by sliding or/and rocking depending on the aspect ration and magnitude of axial loading. Also found was the flexure or shear mode resulting from the degraded strength of brick and/or mortar due to the cyclic loading effect.

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Electrochemical Study of Molecular Devices Using Functional LB Monomolecular Layer Compounds (신기능성 LB 단분자막을 이용한 분자소자의 전기화학적 연구)

  • Park, Soo-Gil
    • Applied Chemistry for Engineering
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    • v.2 no.4
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    • pp.311-329
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    • 1991
  • Electrochemical behavior of surface active Osmium bipyridine complex adsorbed in a monomolecular layer on tin oxide electrodes by the Langmuir-Blodgett method was studied. Theoretical equation of cyclic voltammetry of electrode reactions for redox species adsorbed as monolayer form was discussed by reversible and quasi-reversible waves. The film was transferred onto the $SnO_2$ electrode surface and then amounts of charge on the electrode were measured in the technique of cyclic voltammetry. The electron transfer mediation of these monolayer with $Fe^{2+}$, TEMPOL and others were studied. And the cyclic voltammetry were simulated by taking into account the interaction parameters. From these values, we found it possible to fit almost all measured cyclic voltammograms with these parameters. The recent works and directions using LB method were introduced with various applicable field.

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FREE CYCLIC CODES OVER FINITE LOCAL RINGS

  • Woo, Sung-Sik
    • Bulletin of the Korean Mathematical Society
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    • v.43 no.4
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    • pp.723-735
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    • 2006
  • In [2] it was shown that a 1-generator quasi-cyclic code C of length n = ml of index l over $\mathbb{Z}_4$ is free if C is generated by a polynomial which divides $X^m-1$. In this paper, we prove that a necessary and sufficient condition for a cyclic code over $\mathbb{Z}_pk$ of length m to be free is that it is generated by a polynomial which divides $X^m-1$. We also show that this can be extended to finite local rings with a principal maximal ideal.

Multi-Size Circular Shifter Based on Benes Network with High-Speed 3×3 Switch (고속 3×3 스위치를 이용한 Benes 네트워크 기반 Multi-Size Circular Shifter)

  • Kang, Hyeong-Ju
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.11
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    • pp.2637-2642
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    • 2015
  • The low-density parity check(LDPC) code is being widely used due to its outperformed error-correction ability. The decoder of the quasi-cyclic LDPC(QC-LDPC) codes, a kind of LDPC codes, requires a multi-size cyclic shifter(MSCS) performing rotation of various sizes. The MSCS can be implemented with a Benes network, which requires a $3{\times}3$ switch if the number of data to be rotated is a multiple of 3. This paper proposes a control signal generation with lower complexity and a faster $3{\times}3$ switch. For the experiment, the proposed schemes are applied to the MSCS of an IEEE 802.16e WiMAX QC-LDPC code decoder. The result shows that the delay is reduced by about 8.7%.

Fatigue Damage of Quasi-Isotropic Composite Laminates Under Tensile Loading in Different Directions

  • Kim, In-Kweon;Kong, Chang-Duk;Han, Kyung-Seop
    • Journal of Mechanical Science and Technology
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    • v.14 no.5
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    • pp.483-489
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    • 2000
  • The purpose of this work is to investigate fatigue damage of quasi-isotropic laminates under tensile loading in different directions. Low cycle fatigue tests of $[0/-60/60]_s$ laminates and $[30/-30/90]_s$ laminates were carried out. Material systems used are AS4/Epoxy and AS4/PEEK. The fatigue damage of $[30/-30/90]_s$ is very different from that of $[0/-60/60]_s$. The experimental results are compared with the result obtained from the method for determining strain energy release rate components proposed by the authors. The analytical results were in good agreement with the experimental results. It is proved that the failure criterion based on the strain energy release rate is an appropriate approach to predict the initiation and growth of delaminations under cyclic loading.

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Research of Plastic response by Quasi-Static Test for Circulr Hollow R.C. Bridge Pier (준정적 실험에 의한 중공원형 콘크리트 교각의 소성응답 연구)

  • 정영수
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 1999.04a
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    • pp.247-255
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    • 1999
  • Because of relatively heavy dead weight of concrete itself and unavoidable heat of massive concrete in bridge piers circular hollow columns are widely used in Korean highway bridges Since the occurrence of 1995 Kobe earthquake there have been much concern about seismic design for various infrastructures inclusive of bridge structures. It is however understood that there are not much research works for nonlinear behavior circular hollow columns subjected to earthquake motions. The ultimate of this experimental research is to investigate nonlinear behavior of hollow reinforced concrete bridge piers under the quasi-static cyclic load test and than to enhance their ductility by strengthening the plastic hinge region with glassfiber sheets. It can be concluded from Quasi-static test for 7 bridge piers that approximate 4-5 ductility factor can be experimentally obtained for bridge piers nonseismically designed in conventional way which approximate 5-6 ductility factor for those seismically designed.

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Performance Evaluation on Static Loading and Cyclic Loading for Structural Insulated Panels (구조용단열패널의 정적가력과 반복가력 성능 평가)

  • Nah, Hwan-Seon;Lee, Hyeon-Ju;Choi, Sung-Mo
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.4 no.1
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    • pp.33-39
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    • 2013
  • Structural insulated panels, structurally performed panels consisting of a plastic insulation bonded between two structural panel facings, are one of emerging products with a viewpoint of its energy and construction efficiencies. These components are applicable to fabricated wood structures. In Korea, there are few technical documents regulated structural performance and engineering criteria in domestic market. This study was conducted to identify fundamental performance of both monotonic load and quasi static cyclic load for SIPs in shear wall application. Static test results showed that maximum load was 44.3kN, allowable shear load was 6.1kN/m, shear stiffness was 1.23 M N/m, and ductility ratio was 3.6. Cyclic test was conducted by two kinds of specimens : single panel and double panels. Cyclic test results, which were equivalent to static test results, showed that maximum load was 45.42kN, allowable shear load was 6.3kN/m. Furthermore the accumulated energy dissipation capability for double panels was as 2.3 times as that for single panel. From performance of structural tests, it was recommended that the allowable shear load for panels was at least 6.1kN/m.

Thickness Effect on Compressive Fatigue Behavior of Al-Si-Ca Alloy Foam (Al-Si-Ca 합금 폼의 피로 거동에 대한 두께 효과)

  • Kim, Il-Hyun;Hossain, Mynul;Kim, Am-Kee
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.179-182
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    • 2007
  • The compressive fatigue tests on the closed cell Al-Si-Ca alloy foams with two different thicknesses were performed using a load ratio of 0.1. The quasi-static and cyclic compressive behaviors were obtained respectively. The fatigue stress-life (S-N) curves were evaluated from the obtained cyclic compressive behaviors. S-N curves were presented for the onset of progressive shortening. It turned out that the fatigue strength showed higher value for the thicker foam and the onset of shortening of thinner foam took place earlier. The crushing was found to initiate in a single band which broadens gradually with additional fatigue cycles. Progressive shortening of the specimen took place due to a combination of low cycle fatigue failure and cyclic ratcheting.

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