• Title/Summary/Keyword: quartz

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A study on anisotropic characteristics of axial strengths in $\alpha$-quartz by using molecular dynamics simulation and uniaxial compression test (분자동력 학 시뮬레이션과 일축압축강도시험을 이용한 $\alpha$-quartz의 결정축에 따른 강도이방성 검토)

  • ;;市川康明;河村雄行
    • Tunnel and Underground Space
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    • v.10 no.1
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    • pp.70-79
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    • 2000
  • We carried out NPT-ensemble (constant-number of particles, pressure, and temperature) Molecular Dynamics (MD) simulations for measuring strength anisotropy under uniaxial compressive stress rotated to the crystallographic axes in $\alpha$-quartz. Uniaxial compressive strengths of a single quartz crystal were measured in directions of the a- and c-axis. Measured uniaxial strength of a single quartz crystal was higher in the direction parallel to the c-axis than that measured in the direction normal to the c-axis. However the reverse was found in calculated uniaxial strengths by MD simulation. The contradictive result of strengths was observed in both cases but was found to be different in origin. Strength anisotropy of defectless $\alpha$-quartz crystal in MD simulation is basically caused by structural difference of quartz. By contrast, anisotropy of measured strength in the uniaxial compression test is related to oriented micro-defects developed during crystal growth.

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The evaluation of correction methods and effect of kaolinite on quantitative analysis of quartz in respirable dust by FTIR direct-on-filter method (직접필터법을 이용한 석영 분석시 고령석의 영향 및 보정방법 평가)

  • Phee, Young Gyu
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.19 no.1
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    • pp.1-7
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    • 2009
  • To establish the Fourier-Transform Infra-Red spectrophotometry(FTIR) Direct-On-Filter(DOF) technique as a useful analytical method for quartz in respirable dust samples, an influence of the kaolinite should be corrected. Respirable dust, created in a dust chamber containing the standard material of quartz and kaolinite were collected using a cyclone equipped with a 25 mm, $0.8\;{\mu}m$ pore size DM filter as a collection medium. This study was designed to compare three methods of correction for kaolinite when quantifying the content of quartz, including the least square, the optimum choice and the spectral subtraction methods. The content of quartz in the respirable dust samples was overestimated by 6.2% when mixed with kaolinite(35.5% by weight). The content of quartz containing kaolinite(72.8% by weight) were overestimated by 32%. The spectral subtraction method underestimated the quartz content by 1.5%, while the other two correction methods, the optimum choice and the least square method, overestimated the quartz content by 1.9% to 6.4% and 0.04 to 1.1%, respectively. The results of this study are suggested that, when correcting for effects of kaolinite on quantitative analysis of quartz in respirable dust by FTIR direct-on-filter method, the least square method produce the most unbiased results be compared with those of other correction methods.

Optimization of Fused Quartz Cantilever DRIE Process and Study on Q-factors (비정질 수정 캔틸레버의 식각 공정 최적화 및 Q-factor 연구)

  • Song, Eun-Seok;Kim, Yong-Kweon;Baek, Chang-Wook
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.2
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    • pp.362-369
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    • 2011
  • In this paper, optimal deep reactive ion etching (DRIE) process conditions for fused quartz were experimentally determined by Taguchi method, and fused quartz-based micro cantilevers were fabricated. In addition, comparative study on Q-factors of fused quartz and silicon micro cantilevers was performed. Using a silicon layer as an etch mask for fused quartz DRIE process, different 9 flow rate conditions of $C_4F_8$, $O_2$ and He gases were tested and the optimum combination of these factors was estimated. Micro cantilevers based on fused quartz were fabricated from this optimal DRIE condition. Through conventional silicon DRIE process, single-crystalline silicon micro cantilevers whose dimensions were similar to those of quartz cantilevers were also fabricated. Mechanical Q-factors were calculated to compare intrinsic damping properties of those two materials. Resonant frequencies and Q-factors were measured for the cantilevers having fixed widths and thicknesses and different lengths. The Q-factors were in a range of 64,000 - 108,000 for fused quartz cantilevers and 31,000 - 35,000 for silicon cantilevers. The experimental results supported that fused quartz had a good intrinsic damping property compared to that of single crystalline silicon.

Analysis of resonant frequency in microstrip antennas using X-cut Quartz plates (X-cut quartz를 이용한 마이크로스트립 안테나의 해석)

  • Kang, Hyun-Il;Hwang, Hyun-Suk;Lee, Kyu-Il;Lee, Tae-Yong;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.380-381
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    • 2006
  • A technique to control the operating frequency of microstrip antenna by using the X-cut quartz substrate has been investigated experimentally and theoretically. We consider 6, 8 and 10 GHz resonance frequency in three dimensional quartz plates. Equation of linear piezoelectricity are solved for the thickness-shear approximation of X-cut quartz plates. At X-band frequencies, the microstrip antenna was voltage-controllable using the dc electric field dependence of the piezoelectric constant of X-cut quartz. This work demonstrates advantageous application for X-cut quartz plate in microstrip antenna substrates.

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Effect of quartz powder, quartz sand and water curing regimes on mechanical properties of UHPC using response surface modelling

  • Mosaberpanah, Mohammad A.;Eren, Ozgur
    • Advances in concrete construction
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    • v.5 no.5
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    • pp.481-492
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    • 2017
  • The aim of this paper is to investigate the effect of quartz powder (Qp), quartz sand (Qs), and different water curing temperature on mechanical properties including 7, 14, 28-day compressive strength and 28-day splitting tensile strength of Ultra High Performance Concrete and also finding the correlation between these variables on mechanical properties of UHPC. The response surface methodology was monitored to show the influences of variables and their interactions on mechanical properties of UHPC, then, mathematical models in terms of coded variables were established by ANOVA. The offered models are valid for the variables between: quartz powder 0 to 20% of cement substitution by cement weight, quartz sand 0 to 50% of aggregate substitution by crushed limestone weight, and water curing temperature 25 to $95^{\circ}C$.

Tin, Tungsten Mineralization in Bonghwa-Uljin Area (봉화(奉化)-울진지역(蔚珍地域)의 석(錫), 중석광화작용(重石鑛化作用))

  • Park, Hee-In;Lee, Sang Man
    • Economic and Environmental Geology
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    • v.17 no.1
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    • pp.1-15
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    • 1984
  • The tin and tungsten deposits are embedded around the age unknown Buncheon granite gneiss which intruded the Precambrian schists, gneiss and amphibolites in Bonghwa-Uljin area. Pegmatite dike swarm developed intermittently about 4km along the southern border of Buncheon granite gneiss at Wangpiri area. Thickness of pegmatite dikes range from 0.5 to 15m. Pegmetite is consisted of quartz, microcline, albite, muscovite and frequently topaz, tourmaline, garnet, fluorite, fluorapatite and lepidolite. Pegmatite dikes are greisenized, albitized and microclinized along dike walls. Cassiterites are irregularly disseminated through the intensely greienized and albitized parts of the pegmatite. Cassiterite crystals are mainly black to dark brown and contain considerable Ta and Nb. Average Ta and Nb contents of the four cassiterite samples are 5300 and 3400 ppm. The Ssangjeon tungsten deposits is embedded within the pegmatite dike developed along the northern contact of Buncheon granite gneiss with amphibolite. This pegmatite developed 2km along the strike and thickness varies from 10 to 40m. Mineral constituents of the pegmatite are quartz, microcline, plagioclase, muscovite, biotite, tourmaline and garnet. Ore minerals are ferberite and scheelite with minor amount of molybdenite, arsenopyrite, pyrrhotite, pyrite, chalcopyrite, sphalerite, galena, pentlandite, bismuthinite, marcasite, and fluorite. Color and occurrence of quartz reveals that quartz formed at three different stages; quartz I, the earliest milky white quartz formed as a rock forming mineral of simple pegmatite; quartz II, gray to dark gray quartz which replace the minerals associated with quartz I; quartz III, the latest white translucent quartz which replace the quartz I and H. All of the ore minerals are precipitated during the quartz II stage. Fluid inclusion in quartz I and II are mainly gaseous inclusions and liquid inclusions are contained in quartz III and fluorite. Salinities of the inclusion in quartz I and II ranges from 4.5 to 9.5 wt. % and 5.1 to 6.0 wi. % equivalent NaCl respectively. Salinities of the inclusion in fluorite range from 3.5 to 8.3 wt. % equivalent NaCl. Homogenization temperatures of the inclusion in quartz I, II and III range from 415 to $465^{\circ}C$, from 397 to $441^{\circ}C$ and 278 to $357^{\circ}C$. Data gathered in this study reveals that tin and tungsten mineralization in this area are one of prolonged event after the pegmatite formation around Buncheon granite gneiss.

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A study on quantification of α-quartz, cristobalite, kaolinite mixture in respirable dust using by FTIR (FTIR를 이용한 호흡성 분진중 α-quartz, cristobalite, kaolinite 혼합물 정량 분석 연구)

  • Eun Cheol Choi;Seung Ho Lee
    • Analytical Science and Technology
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    • v.36 no.6
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    • pp.315-323
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    • 2023
  • This study is to quantify α-quartz, cristobalite and kaolinite using by FTIR in respirable dust generated in the mining workplace. Various minerals in mines can interfere with peaks when quantifying respirable crystalline silica by FTIR. Therefore, for accurate quantification, it is necessary to remove interfering substances or correct the peaks that cause interference. To confirm the peaks occurring in α-quartz, cristobalite and kaolinite, each standard material was diluted with KBr and scanned in the range of 400 cm-1 to 4000 cm-1 using by FTIR. As a result of scanning the analytes, it was decided to use the peaks of 797.66 cm-1 and 695.25 cm-1 for α-quartz, 621.58 cm-1 for cristobalite, and 3696.47 cm-1 for kaolinite. When the above materials are mixed, interference occurs at the peak for quantification, which is corrected by the calculation formula. The analysis of the mixture of α-quartz and cristobalite shows the average bias (%) of 2.64 (corrected) at α-quartz (797.66 cm-1), 5.61 (uncorrected) at α-quartz (695.25 cm-1) and 1.51 (uncorrected) at cristobalite (621.58 cm-1). The analysis of the mixture of α-quartz and kaolinite shows the average bias(%) of 1.79(corrected) at α-quartz (797.66 cm-1), 3.92 (corrected) at α-quartz (695.25 cm-1) and 2.58 (uncorrected) at kaolinite (3696.47 cm-1). The analysis of the mixture of cristobalite and kaolinite shows the average bias (%) of 2.15 (corrected) at cristobalite (621.58 cm-1), 4.32 (uncorrected) at kaolinite (3696.47 cm-1). The analysis of the mixture of αquartz and cristobalite and kaolinite shows the average bias (%) of 1.93(corrected) at α-quartz (797.66 cm-1), 6.47 (corrected) at α-quartz (695.25 cm-1) and 1.77 (corrected) at cristobalite (621.58 cm-1) and 2.61 (uncorrected) at kaolinite (3696.47 cm-1). The experimental results showed that the deviation caused by peak interference by two or three substances could be corrected to less than 6 % of the average deviation. This study showed the possibility of correcting and quantifying when various interfering substances that are difficult to remove are mixed.

MECHANICAL PROPERTIES OF QUARTZ FIBER POST (Quartz fiber post의 물리적 특성에 관한 연구)

  • Lee Young-Soo;Kang Ik-Je
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.1
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    • pp.68-78
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    • 2002
  • The post core system has been used for reconstructon of severely damaged crown by caries or trauma. But problems such as crown exfoliation, post core fracture and root fracture have been reported. Ideal mechanical properies of the post require high fracture strength, high elastic limit and high resistance against fatigue and corrosion Modulus of elasticity of the post should be similar with that of dentine. Low hardness is also required for the convenience of post removal in failure. Furthermore, the post itself must be translucent for the esthetical purpose. Several types of the post have been developed to satisfy the criteria above mentioned. The purpose of this study was to find out the mechanical properties of quartz fiber post by comparing with those of gold post and zirconia post. The results of this study were as follows : 1. Maximal fracture strength and stiffness of quartz fiber post were similar with those of gold post and zirconia post. 2. Young's modulus and hardness of quartz fiber post were lower than those of gold post and zirconia post. Mechanical property of quartz fiber post against post fracture was similar with that of gold post and zirconia post. Mechanical property of quartz fiber post against root fracture was higher than that of gold post and zirconia post. Quartz fiber post could be removed easily due to low hardness.

Electric Properties of LB Films using Impedance Analysis of Quartz Crystal (수정진동자의 임피던스 해석에 의한 LB막의 전기적 특성)

  • Jin, Cheol-Nam;Kim, Gyeong-Hwan;Yu, Seung-Yeop;Gwon, Yeong-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.7
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    • pp.503-507
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    • 1999
  • Quartz crystal in contact with viscoelastic medium was described directly in terms of the electrical equivalent circuit of the system. Stearic acid was used as viscoelastic medium and deposited on the surface of quartz crystal using the Langmuir-Blodgett(LB) method. Impedance properties of quartz crystal coated with LB films which were investigated by using admittance diagram and $Ζ-\theta$ plot a method of impedance analysis. When stearic acid LB film was deposited on the surface of quartz crystal, resonant frequency of quartz crystal was changed about 100 Hz/layer. This result illustrates the ability of the sensor system to detect small amounts of special gas in air.

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Feasibility Study on Quartz Liner Application for Marine Diesel Engine Visualization

  • Lee Kyo Seung;Baek Moon Yeal;Assanis Dennis N.
    • Journal of Ship and Ocean Technology
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    • v.8 no.4
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    • pp.34-44
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    • 2004
  • Engine visualization is the most important process to develop the new engine. But this step has a major difficulty that is almost impossible to access the engine on running. Therefore, little indication from the experimental and analytical results has been so far. This work has conducted the important issue of developing a quartz liner. And it has given us good qualitative and quantitative results of temperature and stress fields in the quartz cylinder by considering forced convection of outside quartz liner, thickness of the quartz liner and preheating effect to operate quartz engine safely.