• 한국세라믹학회지
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• 제31권8호
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• pp.841-848
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• 1994

The sintering behavior of La-modified PbTiO3 ceramics was investigated in order to improve the poor sinterability of PbTiO3. Addition of La improved the sinterability. It was confirmed that this improvement was due to the decrease in tetragonality ratio c/a of crystal lattice. The variations of dielectric constant and pyroelectric coefficient were measured with temperature. It was observed that with the increase of La content, Curie temperature decreased and dielectric constant at room temperature increased. La-modified PbTiO3 ceramics had smaller pyroelectric figure of merits than those of pyroelectric materials in use. The effects of grain size on dielectric and pyroelectric properties were also investigated. The change of grain size had effect on maximum dielectric constant and pyroelectric coefficient, but is had little effect on pyroelectric figure of merit at room temperature. The closer examination near ferro-paraelectric phase transition temperature revealed that the behavior of phase transition approached a more relaxor character with the increase of La content and the decrease of grain size.

• KIEE International Transactions on Electrophysics and Applications
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• 제4C권2호
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• pp.73-76
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• 2004

0-3 PbTiO$_3$/P(VDF/TrFE) nanocomposite thin films for passive pyroelectric infrared sensors were fabricated by a two-step spin coating technique. 65wt% VDF and 35 wt% TrFE was formed into a P(VDF/TrFE) powder. Nano size PbTiO$_3$ powder was used. 0-3 connectivity of PbTiO$_3$/P(VDF/TrFE) composite film was successfully achieved and observed using SEM photography. The dielectric constant and pyroelectric coefficient were measured and compared with P(VDF/TrFE). A very low dielectric constant (13.48 at 1KHz and sufficiently high pyroelectric coefficient (3.101 nC/$\textrm{cm}^2$ㆍk at 5$0^{\circ}C$) were measured. This nanocomposite can be used for a new pyroelectric infrared sensor to achieve better performance.

• 한국재료학회지
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• 제17권4호
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• pp.236-238
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• 2007

[ 0-3PbTiO_3/P$ ](VDF/TrFE) nanocomposites thin films for passive pyroelectric infrared sensor have been fabricated by two-step spin coating technique. 65 wt% VDF and 35 wt% TrFE was formed to a P(VDF/TrFE) poder Nano size $PbTiO_3$ powder was used. 0-3 connectivity of $PbTiO_3$(VDF/TrFE) composites film is achieved and also observed by SEM photography successfully. The dielectric constant, and pyroelectric coefficient measured and compared with P (VDF/TrFE). A very low dielectric constant (13.48 at 1 kHz) and high enough pyroelectric coefficient (3.101 $nC/cm^2$.k at $50^{circ}C$) neasured. This nanocomposites can be used for a new pyroelectric infrared sensor for better performance.

• Coupled systems mechanics
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• 제2권1호
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• pp.1-22
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• 2013

Under thermal environment, Magneto-Electro-Elastic (MEE) material exhibits pyroelectric and pyromagnetic effects which can be used for enhancing the performance of MEE sensors. Recently studies have been published on material constants such as pyroelectric constant and pyromagnetic constant for magneto-electro-thermo-elastic smart composite. Hence, the main aim of this paper is to study the pyroelectric and pyromagnetic effects on behavior of MEE plate under different boundary conditions subjected to uniform temperature. A numerical study is carried out using eight noded brick finite element under uniform temperature rise of 100 K. The study focused on the pyroelectric and pyromagnetic effects on system parameters like displacements, thermal stresses, electric potential, magnetic potential, electric displacements and magnetic flux densities. It is found that, there is a significant increase in electric potential due to the pyroelectric and pyromagnetic effects. These effects are visible on electric and magnetic potentials when CFFC and FCFC boundary conditions are applied. Additionally, the pyroelectric and pyromagnetic effects at free edge is dominant (nearly thrice the value in CFFC in comparison with FCFC) than at middle of the plate. This study is a significant contribution to sensor applications.

• 한국세라믹학회지
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• 제26권6호
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• pp.755-762
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• 1989

A pyroelectric ceramic material based on Pb(Sn1/2Sb1/2)O3 modified PZT system is studied as a function of the amount of Pb(Sn1/2Sb1/2)O3 and PbTiO3. With increasing the Pb(Sn1/2Sb1/2)O3 amount the dielectric constant increases up to 10mol% and then decreases, but the pyroelectric coefficient decreases and as the PbTiO3 contents increase in the 10mol% added PZT system, the dielectric constant increases but the infrared sensitivity decreases. The good pyroelectric material has low dielectric constant and no pyrochlore phase, but does not depend in the amount of remanent dipole, and its composition sites around ferroelectric-to-antiferroelectric phase boundary.

• 한국표면공학회지
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• 제36권5호
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• pp.413-417
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• 2003

The effect of 0-0.7 ㏖% addition of $Cr_2$$O_3$on the dielectric, pyroelectric, and piezoelectric properties were studied in the (Mg$0.7Pb_{1}$$3/Nb_{2}$3/)$O_3$-$0.3PbTiO_3$(0.7PMN-0.3PT) ceramics with composition near the morphotropic phase boundary. The dielectric constant and loss of the ceramics samples were measured as a function of temperature at various frequencies (0.1-100 KHz). The pyroelectric coefficient was measured by using the Byer-Roundy method as a function of temperature. Dielectric, pyroelectric, and piezoelectric constant achieved the maximum values of 0.4 ㏖% $Cr_2$$O_3$The transition temperature is continuously shifted to lower temperature with an increase of a small amount of $Cr_2$$O_3$.

• 조명전기설비학회논문지
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• 제29권4호
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• pp.77-84
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• 2015

PZT ceramics, usually used pyroelectric materials exhibited a relatively highly Curie temperture(Tc) of $250-450^{\circ}C$ and permittivity constant of 500-1600. In this paper, the pyroelectric infrared detectors are applied two different types of pyroelectric materials, that is tetragonal crystal of ferroelectric $PbTiO_3$ and rhombohedral crystal of $Pb(Zr,Ti)O_3$. PZT ceramics shows not only highly Curie temperture but also excellent pyro and piezoelectric properties at the Zr/Ti(=52/48) ratio. Therefor in this paper, the pyroelectric infrared detectors are applied PZT ceramics, and obtained sensitive sensing characteristics by expriment case studies.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1988년도 학술발표초록집
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• pp.34-34
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• 1988

The pyroelectricity of poly(vinylidenefluoride) films prepared by varying the draw ratio and the poling field was investigated. As the draw ratio and the electric field on poling of the drawn samples increased, so did the pyroelectric coefficient. But the effect of electric field on the pyroelectricity was greater than that of draw ratio. The pyroelectric and piezoelectric activities could be explained by the polarization using the thermally stimulated current. The relation between pyroelectric coefficient and piezoelectric stress constant showed a good linearity.

• 한국세라믹학회지
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• 제27권1호
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• pp.35-42
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• 1990

In the present investigation, ceramic PZT and Polymer were prepared. The former is Pb[(Sn1/2Sb1/2)0.1 Ti0.27Zr0.63]O3 including Pb(Sn1/2Sb1/2)O3 with good pyroelectric effect, and the latter PVA(Poly Vinyl Alcohol) with good plasticity. Then, they were fabricated to be flat by using 0-3 connectivity which is rather easily fabricated and capable of making thin film, extending surface area among the connectivities. Such were applied to the sample as variation of intensity of poling field, poling temperature, volume fraction between ceramic and polymer. Then dielectric constant, pyroelectric current, pyroelectric coefficient and the figure of merit were measured. And then their effects on pyroelectric characteristics were observed.

• 한국세라믹학회지
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• 제33권8호
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• pp.863-870
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• 1996

Fabricated modified PZT system for pyroelectric IR sensor were analyzed and characterized for dielectric piezoelectric and pyroelectric properties. Particle size and distribution of source powders were controlled by attrition milling process. 0.05PSS+yPT+(0.95-y)PZ+0.4 wt%MnO2 system was fabricated and investigated sintering density crystal structure and micro-structure through sintering conditions sintering temperature and sintering atmosphere. The poled sintered system of y=0.11 showed the lowest dielectric constant. The dielectric constants were increased with increasing y-mole ratio. The pyroelectric properties of modified PZT systems which were assembled to TO-5 package were measured by IR measurement system average out-voltage of 0.05PSS+0.1PT+0.84PZ+ wt%MnO2 was 3V.