• 제목/요약/키워드: pure state

검색결과 550건 처리시간 0.028초

Ag-Cu-Ti 브레이징 합금의 산화거동 (Oxidation Behavior of Ag-Cu-Tio Brazing Alloys)

  • 우지호;이동복;장희석;박상환
    • 한국세라믹학회지
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    • 제35권1호
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    • pp.55-65
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    • 1998
  • Ag-36.8a%Cu-7.4at%Ti 조성의 브레이징 합금을 Si3N4 기판위에 브레이징한 후 브레이징 합금의 산화거동을 대기중 400, 500, 600$^{\circ}C$에서 조사하였다. 브레이징 합금의 구성원소인 Ag는 산화되지 않고 Cu와 Ti가 산화되며, 산화거동은 포물선적 산화법칙을 따랐다. 브레이징 합금의 산화에 따른 활성화에너지는 80kj/ mol 으로서 소량 첨가된 활성원소인 Ti에 의하여 순수한 Cu의 산화시 활성화에너지보다 감소하였다. 산화 초기에 생성되는 외부산화물은 Cu이온의 외부확산에 의해 성장이 지배되는 Cu산화물로 구성되어 있었다. 산화기간이 경과함에 따라 외부산화물층 아래에서 Cu의 농도는 감소되고 Ag의 농도는 증가하는 농도구배가 발생하여, 브레이징 합금의 산화물은 Cu산화물층(CuO)/Ag잉여층/Cu산화물층(Cu2O)/Ag잉여층의 다층구조를 갖았다. 또한, 분위기중의 산소는 Cu산화물 및 Ag잉여층을 통해 브레이징 합금 내부로 확산되어 브레이징 합금내의 Ti와 반응하여 내부산화물 TiO2를 생성하였다.

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False-Positive Mycobacterium tuberculosis Detection: Ways to Prevent Cross-Contamination

  • Asgharzadeh, Mohammad;Ozma, Mahdi Asghari;Rashedi, Jalil;Poor, Behroz Mahdavi;Agharzadeh, Vahid;Vegari, Ali;Shokouhi, Behrooz;Ganbarov, Khudaverdi;Ghalehlou, Nima Najafi;Leylabadlo, Hamed Ebrahmzadeh;Kafil, Hossein Samadi
    • Tuberculosis and Respiratory Diseases
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    • 제83권3호
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    • pp.211-217
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    • 2020
  • The gold standard method for diagnosis of tuberculosis is the isolation of Mycobacterium tuberculosis through culture, but there is a probability of cross-contamination in simultaneous cultures of samples causing false-positives. This can result in delayed treatment of the underlying disease and drug side effects. In this paper, we reviewed studies on false-positive cultures of M. tuberculosis. Rate of occurrence, effective factors, and extent of false-positives were analyzed. Ways to identify and reduce the false-positives and management of them are critical for all laboratories. In most cases, false-positive is occurring in cases with only one positive culture but negative direct smear. The three most crucial factors in this regard are inappropriate technician function, contamination of reagents, and aerosol production. Thus, to reduce false-positives, good laboratory practice, as well as use of whole-genome sequencing or genotyping of all positive culture samples with a robust, extra pure method and rapid response, are essential for minimizing the rate of false-positives. Indeed, molecular approaches and epidemiological surveillance can provide a valuable tool besides culture to identify possible false positives.

Pd 촉매의 부분 산화 조절을 이용한 SnO$_2$박막 센서의 CH$_4$감도 변화 연구 (The effect of initial Pd catalyst oxidation stale on CH$_4$sensitivity of SnO$_2$thin film sensor)

  • 최원국;조정;조준식;송재훈;정형진;고석근
    • 마이크로전자및패키징학회지
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    • 제6권2호
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    • pp.45-49
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    • 1999
  • 이온빔 보조 증착법을 이용하여 제작한 $SnO_2$박막을 기저 물질로한 가연성 센서에 catalyst로 ultra-thin Pd layer를 이온빔 스퍼터링으로 흡착시켰다. 가연성 기체의 센싱 메카니즘에서 Pd 촉매의 역할을 정확하게 조사하기 위해서 진공 및 공기 상에서 annealing 함으로서 Pd 촉매의 초기 산화 상태를 조절하였다. 촉매가 순수한 금속 Pd 클러스터 상태로 존재하는 $SnO_2$센서의 경우에는 PdO 클러스터가 있는 것에 비해 높은 감응성을 보였다. 이것은 PdO 클러스터가 표면 acceptor로 작용을 하는 것으로 생각되며 $SnO_2$로 부터 Pd sub-channel을 통해 전자를 받아 센서의 감도를 낮추고 응답시간을 늦추는 것으로 생각된다.

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Structural, Dielectric and Field-Induced Strain Properties of La-Modified Bi1/2Na1/2TiO3-BaTiO3-SrZrO3 Ceramics

  • Hussain, Ali;Maqbool, Adnan;Malik, Rizwan Ahmed;Zaman, Arif;Lee, Jae Hong;Song, Tae Kwon;Lee, Jae Hyun;Kim, Won Jeong;Kim, Myong Ho
    • 한국재료학회지
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    • 제25권10호
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    • pp.566-570
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    • 2015
  • $Bi_{0.5}Na_{0.5}TiO_3$ (BNT) based ceramics are considered potential lead-free alternatives for $Pb(Zr,Ti)O_3$(PZT) based ceramics in various applications such as sensors, actuators and transducers. However, BNT-based ceramics have lower electromechanical performance as compared with PZT based ceramics. Therefore, in this work, lead-free bulk $0.99[(Bi_{0.5}Na_{0.5})_{0.935}Ba_{0.065}]_{(1-x)}La_xTiO_3-0.01SrZO_3$ (BNBTLax-SZ, with x = 0, 0.01, 0.02) ceramics were synthesized by a conventional solid state reaction The crystal structure, dielectric response, degree of diffuseness and electric-field-induced strain properties were investigated as a function of different La concentrations. All samples were crystallized into a single phase perovskite structure. The temperature dependent dielectric response of La-modified BNBT-SZ ceramics showed lower dielectric response and improved field-induced strain response. The field induced strain increased from 0.17%_for pure BNBT-SZ to 0.38 % for 1 mol.% La-modified BNBT-SZ ceramics at an applied electric field of 6 kV/mm. These results show that La-modified BNBT-SZ ceramic system is expected to be a new candidate material for lead-free electronic devices.

("황제내경(黃帝內經)" 신명개념(神明槪念)의 연구 (Study of Shenming Theory in ${\ulcorner}$Hwang Ti Nei Ching${\lrcorner}$)

  • 김구환;권강범;류도곤
    • 동의생리병리학회지
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    • 제21권4호
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    • pp.803-814
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    • 2007
  • Shenming(神明) exists everywhere in the universe; it affects human beings to feel and contact ideal and peaceful state of Shen(神). Shenming theory(神明思想) in ${\ulcorner}$Hwang Ti Nei Ching${\lrcorner}$ (黃帝內經) was established by ancient Northeastern Asians who were trying to apply paradigm called TianRenHeYi theory(天人合-思想), unifying man and the Great Spirit(絶對精神) of the universe. Based on present, Shenming(神明) is an idea that can estimate will of Shen(神) which has a key to the future; such concept is founded by both human's mind and action that are designed to seek for the uncertain future. Very pure and devoted mind can sympathize with Shen(神) to accept Shenming(神明). Sehnming theory(神明思想) in ${\ulcorner}$Hwang Ti Nei Ching${\lrcorner}$ (黃帝內經) has a basic concept of living balanced life as a human by accepting Shenming(神明), the Spirit of Universe. Thus, it can be summarized into a phrase, 'Shenming(神明) is a process that human conjures his ultimate destiny called the Great Spirit(絶對精神) in himself.' If a man would be guided by Shenming(神明), the Spirit of Universe, he can live peacefully. Therefore, it is essential to study Shenming theory(神明思想) in ${\ulcorner}$Hwang Ti Nei Ching${\lrcorner}$ (黃帝內經) to aid present people's mental health.

국내 친환경 인쇄를 위한 Ink Saving 적용 방법에 관한 연구 (A Study on ink Saving Application Method for Domestic for Eco-Friendly Printing)

  • 구철회
    • 한국인쇄학회지
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    • 제30권2호
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    • pp.35-45
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    • 2012
  • Need color separation process to appear number of minimum printing plate waterway maximum printing color at printing process. This time, printing plate is separated three primary colors of C(cyan), M(magenta), Y(yellow). Appear all colors of printing such three primary colors. But, three primary color ink appears 100% dark gray that is not clean as chroma is neared color to 0 because is not pure. As well as, the ink area rate that is whole by over print amount increase of three primary is expanded. As a result, influence in secondary printablity set-off growth by inaccurate color reproduction and ink dry badness, trapping efficiency decline etc.. Apply ink saving method that is replaced as K ink in consisted dark color constituent because three primary colors are over print each other adding one more K(black) plate by method to improve these problem. Therefore, can reduce extension of the total ink area rate, and help in correct color appearance control. As well as, eco-friendly printing process attains improving printablity at the same time curtailment of printing expense by reducing requirement of total ink. Usually, there are UCR(under color removal) and GCR(gray component replacement) to ink saving application method. But, the practical use limit is insufficient state to tribe of technological investigation or field application about these method in domestic printing field. Therefore, in this research, ink saving been bringing by one method of eco-friendly printing confirmed that is applicable in usual domestic printing environment. Also, searched result getting in printablity by ink saving application.

결정형이 생체이용률에 미치는 영향 (Effect of Crystal Form on Bioavailability)

  • 손영택
    • Journal of Pharmaceutical Investigation
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    • 제34권6호
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    • pp.443-452
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    • 2004
  • Habit is the description of the outer appearance of a crystal. If the environment of a growing crystal affects its external shape without changing its internal structure, a different habit results. Crystal habit and the internal structure of a drug can affect bulk and physicochemical properties, which range from flowability to chemical stability. A polymorph is a solid crystalline phase of a given compound resulting from the possibility of at least two different arrangements of the molecules of that compound in the solid state. Chemical stability and solubility changes due to polymorphism can have an impact on a drug's bioavailability and its development program. During crystallization from a solution, crystals separating may consist of a pure component or be a molecular compound. Solvates are molecular complexes that have incorporated the crystallizing solvent molecule in their lattice. When the solvent incorporated in the solvate is water, it is called a hydrate. To distinguish solvates from polymorphs, which are not molecular compounds, the term pseudopolymorph is used. Identification of possible hydrate compounds is important since their aqueous solubilities can be significantly less than their anhydrous forms. Conversion of an anhydrous compound to a hydrate within the dosage form may reduce the dissolution rate and extent of drug absorption. An amorphous solid may be treated as a supercooled liquid in which the arrangement of molecules is random. Amorphous solids lack the three-dimensional long-range order found in crystalline solids. Since amorphous forms are usually of higher thermodynamic energy than corresponding crystalline forms, solubilities as well as dissolution rates are generally greater. A study on crystal form includes characterization of (l)crystal habit, (2)polymorphism, (3)pseudopolymorphism, (4)amorphous solid.

밀기울배지를 이용한 Bacillus natto ${\alpha}-Amylase$ 생산 (${\alpha}-Amylase$ production of Bacillus natto IAM 1212 in the wheat bran medium)

  • 김광;박인호;선우양일
    • KSBB Journal
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    • 제6권2호
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    • pp.143-146
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    • 1991
  • 세균액화형의 ${\alpha}-amylase$의 공업적 생산의 효율성을 높이기 위한 연구의 일환으로 제분공장과 도정공장의 분산물인 밀기울과 쌀겨를 이용하여 배양배지를 조성하고 B. subtilus와 A. oryzae 및 B. natto를 배양한 후 액화형 ${\alpha}-amylase$의 활성을 조사한 결과 B. subtilus와 A. oryzae의 경우 순수배지와 비교하였을 때 큰 차이가 없었으나 B. natto의 경우 외밀기울에서 액화활성이 다른 대구조에 비하여 크게 나타났는데 순수 배지를 이용한 액화활성은 crude enzyme에서 27.3 unit/ ml이고, 최종 액화 활성은 1,255.8u / ml인데 반해 외밀기울을 이용한 액화 활성은 crude enzyme에서 256.0 unit/ ml이고, 최종 액화 활성은 10,700 unit 이었으며 최적 배양온도는 $37^{\circ}C$이며 최적 배양액 pH는 6.8이었다. 그리고 정제된 효소의 분자량은 34,000dalton이었다. 이상의 결과로 보아 밀거울이 ${\alpha}-amylase$의 공업적 생산을 위한 저렴한 기질로 사용될만한 가치가 있다고 사료된다.

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Development of Cr cold spray-coated fuel cladding with enhanced accident tolerance

  • Sevecek, Martin;Gurgen, Anil;Seshadri, Arunkumar;Che, Yifeng;Wagih, Malik;Phillips, Bren;Champagne, Victor;Shirvan, Koroush
    • Nuclear Engineering and Technology
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    • 제50권2호
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    • pp.229-236
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    • 2018
  • Accident-tolerant fuels (ATFs) are currently of high interest to researchers in the nuclear industry and in governmental and international organizations. One widely studied accident-tolerant fuel concept is multilayer cladding (also known as coated cladding). This concept is based on a traditional Zr-based alloy (Zircaloy-4, M5, E110, ZIRLO etc.) serving as a substrate. Different protective materials are applied to the substrate surface by various techniques, thus enhancing the accident tolerance of the fuel. This study focuses on the results of testing of Zircaloy-4 coated with pure chromium metal using the cold spray (CS) technique. In comparison with other deposition methods, e.g., Physical vapor deposition (PVD), laser coating, or Chemical vapor deposition techniques (CVD), the CS technique is more cost efficient due to lower energy consumption and high deposition rates, making it more suitable for industry-scale production. The Cr-coated samples were tested at different conditions ($500^{\circ}C$ steam, $1200^{\circ}C$ steam, and Pressurized water reactor (PWR) pressurization test) and were precharacterized and postcharacterized by various techniques, such as scanning electron microscopy, Energy-dispersive X-ray spectroscopy (EDX), or nanoindentation; results are discussed. Results of the steady-state fuel performance simulations using the Bison code predicted the concept's feasibility. It is concluded that CS Cr coating has high potential benefits but requires further optimization and out-of-pile and in-pile testing.

Investigation of gamma radiation shielding capability of two clay materials

  • Olukotun, S.F.;Gbenu, S.T.;Ibitoye, F.I.;Oladejo, O.F.;Shittu, H.O.;Fasasi, M.K.;Balogun, F.A.
    • Nuclear Engineering and Technology
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    • 제50권6호
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    • pp.957-962
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    • 2018
  • The gamma radiation shielding capability (GRSC) of two clay-materials (Ball clay and Kaolin)of Southwestern Nigeria ($7.49^{\circ}N$, $4.55^{\circ}E$) have been investigated by determine theoretically and experimentally the mass attenuation coefficient, ${\mu}/{\rho}(cm^2g^{-1})$ of the clay materials at photon energies of 609.31, 1120.29, 1173.20, 1238.11, 1332.50 and 1764.49 keV emitted from $^{214}Bi$ ore and $^{60}Co$ point source. The mass attenuation coefficients were theoretically evaluated using the elemental compositions of the clay-materials obtained by Particle-Induced X-ray Emission (PIXE) elemental analysis technique as input data for WinXCom software. While gamma ray transmission experiment using Hyper Pure Germanium (HPGe) spectrometer detector to experimentally determine the mass attenuation coefficients, ${\mu}/{\rho}(cm^2g^{-1})$ of the samples. The experimental results are in good agreement with the theoretical calculations of WinXCom software. Linear attenuation coefficient (${\mu}$), half value layer (HVL) and mean free path (MFP) were also evaluated using the obtained ${\mu}/{\rho}$ values for the investigated samples. The GRSC of the selected clay-materials have been compared with other studied shielding materials. The cognizance of various factors such as availability, thermo-chemical stability and water retaining ability by the clay-samples can be analyzed for efficacy of the material for their GRSC.