• 제목/요약/키워드: pure state

검색결과 552건 처리시간 0.032초

마그네타이트와 금속(Ti, Al)의 기계적 합금화에 의한 복합분말의 합성 (Fabrication of Composite Powders by Mechanical Alloying of Magnetite-M (M = Ti, Al) Systems)

  • 홍대석;이성희;이충효;김지순;권영순
    • 한국분말재료학회지
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    • 제11권3호
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    • pp.247-252
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    • 2004
  • Recently, it has been found that mechanical alloying (MA) facilitates the nanocomposites formation of metal-metal oxide systems through solid-state reduction during ball milling. In this work, we studied the MA effect of Fe$_{3}$O$_{4}$-M (M = Al, Ti) systems, where pure metals are used as reducing agents. It is found that composite powders in which $Al_{2}$O$_{3}$ and TiO$_{2}$ are dispersed in $\alpha$-Fe matrix with nano-sized grains are obtained by mechanical alloying of Fe$_{3}$O$_{4}$ with Al and Ti for 25 and 75 hours, respectively. It is suggested that the large negative heat associated with the chemical reduction of magnetite by aluminum is responsible for the shorter MA time for composite powder formation in Fe$_{3}$O$_{4}$-Al system. X-ray diffraction results show that the reduction of magnetite by Al and Ti if a relatively simple reaction, involving one intermediate phase of FeAl$_{2}$O$_{4}$ or Fe$_{3}$Ti$_{3}$O$_{10}$. The average grain size of $\alpha$-Fe in Fe-TiO$_{2}$ composite powders is in the range of 30 nm. From magnetic measurement, we can also obtain indirect information about the details of the solid-state reduction process during MA.

In-situ 스퍼터링을 이용한 마이크로 박막 전지의 제작 및 전지 특성 평가 (Fabrication and Electrochemical Characterization of All Solid State Thin Film Micro-Battery by in-situ sputtering)

  • 전은정;신영화;남상철;조원일;손봉희;윤영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.159-162
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    • 1999
  • All solid state thin film micro-batteries consisting of lithium metal anode, an amorphous LiPON electrolyte and cathode of vanadium oxide have been fabricated and characterized, which were fabricated with cell structure of Li/LiPON/V$_2$O$\sub$5/Pt. The vanadium oxide thin films were formed by d.c. reactive sputtering on Pt current collector. After deposition of vanadium oxide films, in-situ growths of lithium phosphorus oxynitride film were conducted by r.f. sputtering of Li$_3$PO$_4$ target in mixture gas of N$_2$ and O$_2$. The pure metal lithium film was deposited by thermal evaporation on thin film LiPON electrolyte. The cell capacity was about 45${\mu}$Ah/$\textrm{cm}^2$ $\mu\textrm{m}$ after 200 cycle. No appreciable degradation of the cell capacity could be observed after 50 cycles .

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액상유체 환경하에서 레이저빔의 산란 해석 (Laser Beam Scattering Analysis in Aqueous Environments)

  • 최해운
    • 한국기계가공학회지
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    • 제18권2호
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    • pp.91-95
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    • 2019
  • A new experimental approach is proposed to detect a specific polymer dissolved in a liquid. Distinctive optical properties were found using a laser scattering technique when there is a polymer compound with almost no difference in optical properties (index of refraction) in a liquid phase. The index of refraction, which determines the refraction of light, is obtained by dissolving PCL and PLA. The used samples are biodegradable materials with similar properties and dissolved in a mixture of Chloroform 7: Methanol 3. To predict the optical properties, a 632-nm diode laser was used as the light source of the device, and an integrating sphere was used as the light receiver. Although PCL and PLA had a similar index of refraction of 1.46-1.48, the dissolved PCL showed a relative transmittance of 43%, and the dissolved PLA had a relative transmittance of 34%. The difference in optical properties of the pure polymer compound in the solid state or liquid state is not significantly different, and the difference in the dissolved state in the specific solvent is remarkable because the solubility differs in a specific solution and is randomly distributed.

수정된 Carnahan-Starling 상태방정식을 이용한 혼합냉매의 물성계산 (Estimation of Thermodynamic Properties of Refrigerant Mixtures Using a Modified Carnaha-Starling Equation of State)

  • 김민수;김동섭;노승탁
    • 대한기계학회논문집
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    • 제15권6호
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    • pp.2189-2205
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    • 1991
  • 본 연구에서는 혼합냉매의 열역학적 물성치를 정확하게 예측하기 위하여 척력 과 인력항으로 된 간단한 형태의 상태방정식을 택하고 이를 이용하여 순수성분에 대한 열역학적 물성치 자료와 혼합냉매에 대한 기액평형상태 자료를 이용하여 혼합물에 대 한 열역학적 물성치를 보다 더욱 정확하게 예측 할 수 있는 방법에 관해 연구하고자 한다.혼합냉매에 대한 상태방정식과 이상기체 상태의 비열자료를 기초로 열역학적 관계식을 이용하여, 압력-엔탈피, 온도-엔트로피 관계를 공식화하며, 혼합냉매에 대한 열펌프 및 냉동사이클 해석에 필요한 자료를 제시한다.

In vitro Biofumigation of Brassica Tissues Against Potato Stem Rot Caused by Sclerotinia sclerotiorum

  • Ojaghian, Mohammad Reza;Jiang, Heng;Xie, Guan-Lin;Cui, Zhou-Qi;Zhang, Jingze;Li, Bin
    • The Plant Pathology Journal
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    • 제28권2호
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    • pp.185-190
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    • 2012
  • Sclerotinia sclerotiorum is a serious pathogen which causes yield loss in many dicotyledonous crops including potato. The objective of this study was to assess the potential of biofumigation using three Brassica crops including Brassica napus, B. juncea and B. campestris against potato stem rot caused by S. sclerotiorum by in vitro tests. Both macerated and irradiated dried tissues were able to reduce radial growth and sclerotia formation of five pathogen isolates on PDA, but macerated live tissues were more effective. Compared with other tested crops, B. juncea showed more inhibitory effect against the pathogen. The volatile compounds produced from macerated tissues were identified using a gas chromatograph-mass spectrometer. The main identified compounds were methyl, allyl and butyl isothiocyanates. Different concentrations of these compounds inhibited mycelial growth of the pathogen in vitro when applied as the vapor of pure chemicals. A negative relationship was observed between chemicals concentrations and growth inhibition percentage. In this study, it became clear that the tissues of local Brassica crops release glucosinolates and have a good potential to be used against the pathogen in field examinations.

Multivoltine and Bivoltine Silkworm F1 Hybrids Adaptable to Type One (1) Climatic Conditions in the Philippines

  • Marlyn M. Viduya;Maricris E. Ulat;Gemma E. Supsup;Julieta P. Abuan;Edgar P. Sanchez;Roel D. Supsup
    • International Journal of Industrial Entomology and Biomaterials
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    • 제47권1호
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    • pp.34-43
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    • 2023
  • The eighteen (18) F1 hybrid combinations were tested to identify potential combinations adaptable to type 1 climatic conditions in the Philippines. The six (6) bivoltine purelines (DMMMSU 108, DMMMSU 109, DMMMSU 110, DMMMSU 111, DMMMSU 113, and DMMMSU 119); and three (3) multivoltine purelines (DMMMSU 1000, DMMMSU 1007, and DMMMSU 1014), were crossed (multivoltine x bivoltine) in a mating plan. These were arranged in a Completely Randomized Design (CRD), replicated three times, and analyzed using Analysis of Variance (ANOVA). A test of significance was done using ANOVA across years and Tukey's Honest Significant Difference Test (HSD). The multiple trait evaluation index (EI) method was also used in the identification of potential F1 hybrids. Three major phases were done: (1) parental rearing of multivoltine and bivoltine pure lines for breed multiplication; (2) hybridization process; and (3) evaluation of F1 hybrids. Rearing evaluations were conducted for three consecutive years. Based from the three evaluations, 10 potential crosses were identified: DMMMSU MV-12, DMMMSU MV-11, DMMMSU MV-13, DMMMSU MV-16, DMMMSU MV-07, DMMMSU MV-14, DMMMSU MV-05, DMMMSU MV-09, DMMMSU MV-03, and DMMSU MV-10. The topmost combinations with the best economic and commercial characters and are consistently adaptable during two (2) cropping seasons were DMMMSU MV-07, DMMMSU MV-12, DMMMSU MV-05, DMMMSU MV-09 and DMMMSU MV-11. These newly-identified F1 hybrids are considered potential breeds that could improve cocoon production.

제주도 연안의 각망어업에 있어서 수중음악에 의한 어군의 유집에 관한 연구 (A Study on the Luring of fish Shoals into the Fyke net by the Underwater Sound Emission)

  • 안장영;서두옥;김삼곤
    • 수산해양기술연구
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    • 제32권1호
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    • pp.50-58
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    • 1996
  • The authors carried out a field experiment to confirm the effect of underwater sound on the luring of fish schools in a setnet in the coast of Cheju Island. The effects of the acoustic emission on the luring of fish schools were observed using a manufectured underwater speaker in the setnet, and pure sound, of which frequency was 600Hz and the source level was 126dB, was emitted on and off at 5 minutes intervals in the set net during the night of ,July 29 and ,July 31. So we had recorded behavior of fish schools by the telesounder with two channel and shape of the setnet by underwater video camera and analyzed them. When the flood and ebb currents were around the setnet, the nets rised to the surface of water and it happened occasionaly at the stand of tide. Therefore, it was in the state that fish schools feel constraint to enter into the setnet, and was required a new design of the setnet stand up to strong tidal current. As the pure sound, of which frequency was 600Hz was emitted for the luring of fish schools in a setnet, the catch ammounts of fish, the young horce mackereWI'rachllrlls japonicus), was increased 4~6 times than not emitted.

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공기 불요 연료전지 동력 시스템 (Air-independent Fuel Cell Power System)

  • 김태규
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 춘계학술대회 논문집
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    • pp.331-334
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    • 2009
  • 본 연구에서는 우주 및 수중 동력원을 위한 연료전지 기반 공기 불요 추진 시스템을 개발하였다. 공기 불요 동력 시스템을 위해 과산화수소를 산화제로 선택하였고, 촉매 분해 반응을 통해 산소와 물을 발생하였다. 순수한 산소는 연료전지에 공급되고, 물은 분리한 후 저장된다. 본 연구에서는 고체 상태의 수소화붕소나트륨을 수소원으로 사용하였고, 촉매 가수분해 반응을 통해 순수한 수소를 발생할 수 있었다. 연료전지 기반 공기 불요 동력 시스템을 검증하기 위해 연료전지 시스템을 구축하였고 다양한 조건에서 평가를 수행하였다.

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Anodic Dissolution Property and Structure of Passive Films on Equiatomic TiNi Intermetallic Compound

  • Lee, Jeong-Ja;Yang, Won-Seog;Hwang, Woon-Suk
    • Corrosion Science and Technology
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    • 제6권6호
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    • pp.311-315
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    • 2007
  • The anodic polarization behavior of equiatomic TiNi shape memory alloy with pure titanium as a reference material was investigated by means of open circuit potential measurement and potentiodynamic polarization technique. And the structure of passive films on TiNi intermetallic compounds was also conducted using AES and ESCA. While the dissolved Ni(II) ion did not affect the dissolution rate and passivation of TiNi alloy, the dissolved Ti(III) ion was oxidated to Ti(IV) ion on passivated TiNi surface at passivation potential. It has also been found that the Ti(IV) ion increases the steady state potential, and passivates TiNi alloy at a limited concentration of Ti(IV) ion. The analysis by AES showed that passive film of TiNi alloy was composed of titanium oxide and nickel oxide, and the content of titanium was three times higher than that of nickel in outer side of passive film. According to the ESCA analysis, the passive film was composed of $TiO_2$ and NiO. It seems reasonable to suppose that NiO could act as unstabilizer to the oxide film and could be dissolved preferentially. Therefore, nickel oxide contained in the passive film may promote the dissolution of the film, and it could be explained the reason of higher pitting susceptibility of TiNi alloy than pure Ti.

수소와 산소를 이용한 가스터빈의 구동에 관한 실험 연구 (An Experimental Study about the Running of a Gas Turbine by using Hydrogen and Oxygen)

  • 강진성;오병수
    • 한국수소및신에너지학회논문집
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    • 제8권1호
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    • pp.5-10
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    • 1997
  • Because of environmental pollution and reserve limitations of fossil fuels, several alternative energies have been developing. One of them, the hydrogen is researched as a highly probable solution. In this study pure hydrogen gas and oxygen gas are burned in combustor to reduce the emission, and a gas turbine is used. Cooling water around the combustor recovers the cooling heat loss to useful work by being expanded from liquid to vapor, being injected into the combustor and making pressure rise with working fluid to get more turbine power. Because pure hydrogen and oxygen are used, there is no carbonic emission such as CO, $CO_2$, HC nor $NO_x$, and $SO_x$. The power is obtained by turbine system, which makes lower noise and vibration than any reciprocating engine. Running of a turbine is searched under various conditions of hydrogen flow rate and water injection rate. Maximum speed of the turbine is obtained when the combustion reaches steady state. It is enable to determine the optimum rate between hydrogen flow and water injection which makes turbine run maximum speed.

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