• Title/Summary/Keyword: pure state

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Impedance Properties of Phase-Pure Titanium Dioxide Ceramics Sintered at Different Temperatures

  • Cui, Liqi;Niu, Ruifeng;Wang, Weitian
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.181-185
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    • 2022
  • In this study, phase-pure titanium dioxide TiO2 ceramics are sintered using standard high-temperature solid-state reaction technique at different temperatures (1,000, 1,100, 1,200, 1,300, 1,400 ℃). The effect of sintering temperature on the densification and impedance properties of TiO2 ceramics is investigated. The bulk density and average grain size increase with the increase of sintering temperature. Impedance spectroscopy analysis (complex impedance Z* and complex modulus M*), performed in a broad frequency range from 100 Hz to 10 MHz, indicates that the TiO2 ceramics are dielectrically heterogeneous, consisting of grains and grain boundaries. The complex impedance Z* -plane indicates the resistance of grains of the TiO2 ceramics increases with increasing sintering temperature, while that of grain boundaries develops in the opposing direction. The complex modulus M*-plane shows a grain capacitance that seems to be independent of the sintering temperature, while that of the grain boundaries decreases with increasing sintering temperature. These results suggest that different sintering temperatures have effects on the microstructure, leading to changes in the impedance properties of TiO2 ceramics.

New Monte-Carlo based simulation program suitable for low-energy ions irradiation in pure materials

  • Ghadeer H. Al-Malkawi;Al-Montaser Bellah A. Al-Ajlony;Khaled F. Al-Shboul;Ahmed Hassanein
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1287-1299
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    • 2023
  • A new Monte-Carlo-based computer program (RDS-BASIC) is developed to simulate the transport of energetic ions in pure matter. This computer program is utilizing an algorithm that uses detailed numerical solutions for the classical scattering integral for evaluating the outcomes of the binary collision processes. This approach is adopted by several prominent similar simulation programs and is known to provide results with higher accuracy compared to other approaches that use approximations to shorten the simulation time. Furthermore, RDS-BASIC simulation program contains special methods to reduce the displacement energy threshold of surface atoms. This implementation is found essential for accurate simulation results for sputtering yield in the case of very low energy ions irradiation (near sputtering energy threshold) and also successfully solve the problem of simultaneously obtaining an acceptable number of atomic displacements per incident ions. Results of our simulation for several irradiation systems are presented and compared with their respective TRIM (SRIM-2013) and the state-of-the-art SDTrimSP simulation results. Our sputtering simulation results were also compared with available experimental data. The simulation execution time for these different simulation programs has also been compared.

Addition effects of nanoscale NiO on microstructure and superconducting properties of MgB2

  • Ranot, Mahipal;Jang, S.H.;Oh, Y.S.;Shinde, K.P.;Kang, S.H.;Chung, K.C.
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.37-40
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    • 2016
  • We have investigated the addition effect of NiO magnetic nanoparticles on crystal structure, microstructure as well as superconducting properties of $MgB_2$. NiO-added $MgB_2$ samples were prepared by the solid-state reaction method. The superconducting transition temperature ($T_c$) of 37.91 K was obtained for pure $MgB_2$, and $T_c$ was found to decrease systematically on increasing the addition level of NiO. X-ray diffraction (XRD) analysis revealed that no substitution of Ni for Mg in the lattice of $MgB_2$ was occurred. The microstructural analysis shows that the pure $MgB_2$ sample consists of plate shape $MgB_2$ grains, and the grains get refined to smaller size with the addition of NiO nanoparticles. At 5 K, high values of critical current density ($J_c$) were obtained for small amount NiO-added $MgB_2$ samples as compared to pure sample. The enhancement in $J_c$ could be attributed to the refinement of $MgB_2$ grains which leads to high density of grain boundaries in NiO-added $MgB_2$ samples.

Effect of Hybridization on Carcass Traits and Meat Quality of Erlang Mountainous Chickens

  • Yin, H.D.;Gilbert, E.R.;Chen, S.Y.;Wang, Y.;Zhang, Z.C.;Zhao, X.L.;Zhang, Yao;Zhu, Q.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.10
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    • pp.1504-1510
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    • 2013
  • Native chickens hold a significant share of the market in China. In response to the huge demand from the market, the productivity of Chinese native chickens needs to be improved. Cross breeding is an effective method to increase productivity, although it might affect meat quality. In this study, two pure lines (SD02 and SD03) of Erlang mountainous chickens were hybridized with a yellow feather and faster growing line (SD01). The effect of hybridization on carcass and meat quality (physiochemical and textural traits) was measured in the $F_1$ population at d 91 of age. The hybrids exhibited higher body weight and dressed weight, and amount of semi-eviscerated, eviscerated, breast muscle and abdominal fat (p<0.05). Abdominal fat yield also increased (p<0.05) compared to the offspring of the two pure-lines. Meanwhile, there was no significant difference in meat quality traits except for the myofiber diameter and density and the shear force of the breast muscle. Overall, the offspring of cross-lines were similar to pure lines in meat color, pH value, inosinic acid, crude protein, crude fat, dry matter, moisture content and amino acid composition in the breast muscle. These results suggest that productivity can be improved via cross-breeding while maintaining meat quality of the Erlang mountainous chicken.

Performance Review and Revitalizing Support Plans for Rural Residence though Current Status Survey (현황조사를 통한 농촌주거의 성능검토 및 재생지원방안)

  • Park, Junmo;Kim, Okkyue
    • Korean Journal of Construction Engineering and Management
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    • v.16 no.2
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    • pp.3-11
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    • 2015
  • The urban has been improved houses and facilities as accelerating industry and society, while the rural area was inferior to the city. Furthermore, there was not a maintenance in time as ageing, and did not expect to rebuilding of using proper techniques and materials for financial reasons. This study find a way to make a revitalizing plan for appropriate real state. For this, perform a current status survey that 900 rural residences of 36 rural villages in Chungcheong area. As a result, Korean traditional structure is a half in residential type, and has poor residential conditions by comparison with western pattern. The structural type comprises two type that a pure structure and a mixed structure, and Korean traditional structure is a mixed structure more than a pure structure. It is considered continuous changes by a resident due to a pure structure was not satisfy various functions. It need appropriate plan to improve a rural residence for each characteristics.

Effect of Ethanol as a Dispersant and pH on the Particle Size and Phase Formation in the Synthesis of K+-β"-Al2O3 by Solution State Reaction (액상반응에 의한 K+-β"-Al2O3 합성시 분산첨가제 에탄올과 pH가 입도 및 상형성에 미치는 영향)

  • Cho, Do-Hyung;Kim, Woo-Sung;Shin, Jae-Ho;Lim, Sung-Ki
    • Applied Chemistry for Engineering
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    • v.16 no.1
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    • pp.45-51
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    • 2005
  • $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$ in the $K_2O-Li_2O-Al_2O_3$ ternary system was synthesized using aluminum nitrate solution as a starting material. For the synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$, raw materials with chemical composition of $0.84K_2O{\cdot}0.082Li_2O{\cdot}5.2Al_2O_3$ were mixed in solution state. The effects of dispersant and solution-pH were investigated in minimizing the particle size and on the synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$. Ethanol was used for a dispersant, and $NH_4OH$ solution and nitric acid were added for pH adjustment. The solution pH was increased from 1.0 to 7.5 by 0.5 increments. Each sample was calcined at $1200^{\circ}C$ for 2 h and characterized with X-ray diffraction and particle size analyzer. The pH of solution significantly effected both particle size and phase formation, while the addition of ethanol only effected particle size. The synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$ was favored by addition of nitric acid (for pH control).

Growth and Electrochemical Behavior of Poly[Ni(saldMp)] on Carbon Nanotubes as Potential Supercapacitor Materials

  • Zhang, Yakun;Li, Jianling;Kang, Feiyu;Wang, Xindong;Ye, Feng;Yang, Jun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1972-1978
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    • 2012
  • The polymer of (2,2-dimethyl-1,3-propanediaminebis(salicylideneaminato))-nickel(II), Ni(saldMp), was deposited on multi-walled carbon nanotubes (MWCNTs) substrate by the route of potential linear sweep. The nano structures of poly[Ni(saldMp)] have been obtained by adjusting the monomer concentration of 0.1, 0.2, 0.5, 1.0 and 1.5 mmol $L^{-1}$. The poly[Ni(saldMp)] prepared in acetonitrile solution with monomer concentration of 1.0 mmol $L^{-1}$ shows the fastest growth rate. The effects of potential window on charge-discharge efficiency and electrodeposition scan number on capacitance performance were discussed. Poly[Ni(saldMp)] prepared with less electrodeposition scans exhibits higher capacitance, but this goes against the improvement of the whole electrode capacitance. Sample with 8 deposition scans is the best compromise with the geometric specific capacitance 3.53 times as high as that of pure MWCNTs, and 1.24 times for the gravimetric specific capacitance under the test potential window 0.0-1.0 V.

Effect of additives on the hydrothermal synthesis of manganese ferrite nanoparticles

  • Kurtinaitiene, Marija;Mazeika, Kestutis;Ramanavicius, Simonas;Pakstas, Vidas;Jagminas, Arunas
    • Advances in nano research
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    • v.4 no.1
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    • pp.1-14
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    • 2016
  • Superparamagnetic iron oxide nanoparticles (Nps), composed of magnetite, $Fe_3O_4$, or maghemite, ${\gamma}-Fe_2O_3$, core and biocompatible polymer shell, such as dextran or chitozan, have recently found wide applications in magnetic resonance imaging, contrast enhancement and hyperthermia therapy. For different diagnostic and therapeutic applications, current attempt is focusing on the synthesis and biomedical applications of various ferrite Nps, such as $CoFe_2O_4$ and $MnFe_2O_4$, differing from iron oxide Nps in charge, surface chemistry and magnetic properties. This study is focused on the synthesis of manganese ferrite, $MnFe_2O_4$, Nps by most commonly used chemical way pursuing better control of their size, purity and magnetic properties. Co-precipitation syntheses were performed using aqueous alkaline solutions of Mn(II) and Fe(III) salts and NaOH within a wide pH range using various hydrothermal treatment regimes. Different additives, such as citric acid, cysteine, glicine, polyetylene glycol, triethanolamine, chitosan, etc., were tested on purpose to obtain good yield of pure phase and monodispersed Nps with average size of ${\leq}20nm$. Transmission electron microscopy (TEM), X-ray diffraction, energy dispersive X-ray spectroscopy (EDX), $M\ddot{o}ssbauer$ spectroscopy down to cryogenic temperatures, magnetic measurements and inductively coupled plasma mass spectrometry were employed in this study.

A Study on efficiency of security police through cooperation with private sector (민간영역과의 공조에 의한 경비경찰 효율화에 관한 연구)

  • Kim, Jin-Hyeok
    • Korean Security Journal
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    • no.20
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    • pp.119-140
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    • 2009
  • It seems that security police's business to secure safety of state and citizens has existed since the mankind began to create a community. State was not fully responsible for such security business from the beginning. The business was carried out autonomously by the private sector for a long period. However, as the state system had been strengthened, the public sector absorbed the function. But in the modern society where various risks exist, safety of society could not be guaranteed only by public police. Accordingly, cooperation with the private sector is indispensable. In the limit of public police, autonomous organization of security companies and general citizens is expanding its scope. As a result, they should exercise partnership as a tripod to build social safety net. Security police failed to secure manpower exclusively responsible for security, despite various businesses and excessive mobilization. Accordingly, their professionalism and ability to cope with crisis are being questioned. In particular, efficiency of security police is becoming a more urgent issue in an era of international terrorism. Private sector can be classified into security companies and private autonomous organization. In case of security companies, the problem is quality and business ability of guards compared to a rapid external growth such as quantitative expansion and advancement into various businesses. In terms of pure private activity, the necessity of understanding of public police activity and conditions for organizational and continuous activity should be prepared. To tide over such problems and effectively achieve the common goal, changes in the method of employment, new establishment of security police department, and strengthening of professionalism and crisis management ability are necessary in the public police sector. In case of security companies, improvement of relations with public police through joint education, strengthening of business ability and activation of business cooperation through these matters are necessary. To maximize activity of pure private sector, it needs to establish reserve police, manage such private autonomous organization and bolster publicity with citizens.

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Data Envelopment Analysis of the Management Efficiency of National Shipping Enterprises in South Korea -Chiefly on the Corporate Entertainment and Advertisement Cost- (DEA모형을 이용한 국적선사의 경영효율성 분석 -접대비와 광고·선전비를 중심으로-)

  • Park, Hyun-Jun;Kim, Hyuna;Lim, Young-Tae
    • Journal of Korea Port Economic Association
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    • v.32 no.2
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    • pp.123-135
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    • 2016
  • This study uses Data Envelopment Analysis(DEA) to investigate the management efficiency of Korean shipping companies based on business administration costs such as corporate entertainment, advertisement, and labor costs. We analyze shipping enterprises listed on the Korean stock market of the period of 2010-2014. Corporate entertainment, advertisement and labor costs are used as input variables and sales and net income are used as output variables. We use technical efficiency, pure technical efficiency, scale efficiency and returns to scale to propose a plan to improve the efficiency of inefficiency decision-making units (DMUs). The results of the efficiency analysis show that six of the DMUs in the technical efficiency of CCR model and eight of the DMUs in the pure technical efficiency of BCC model are in efficient state. In terms of return to scale, six of the DMUs(24% of all DMUs) show increasing returns to scale, while 13 DMUs(52% of all DMUs) showdecreasing returns to scale. Because multiple efficient state for DMUs exist in the technical efficiency analysis, we conduct a super efficiency analysis. The results show that the efficient state of the twomost efficient DMUs are 1.314 and 1.243, respectively. This implies that these DMUs could maintain their current levels of the efficiency if they increase the amount spent on advertisements, corporate entertainment and labor costs by 31.4% and 24.3%. respectively. We conclude this study by providing the efficiency states of each DMU and target for improving the inefficiencies in each case.