• Title/Summary/Keyword: pulverized

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Chloride Penetration Resistance of Ternary Blended Concrete and Discussion for Durability (삼성분계 혼합콘크리트의 염화물 침투 저항성 및 내구성에 대한 고찰)

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn-Chu;Kim, Jae-Hwan;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.439-449
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    • 2008
  • Mineral admixtures are used to improve the quality of concrete and to develop sustainability of concrete structures. Supplementary cementitious materials (SCM), such as silica fume (SF), granulated blast furnace slag (GGBS) and pulverized fly ash (PFA), are gradually recognized as useful mineral admixture for producing high performance concrete. The study on ternary blended concrete utilizing mainly three major mineral admixtures is limited and the study on durability and chloride induced corrosion resistance of ternary blended concrete is very few. This study examines the durability characteristics of the ternary blended concrete composed of different amount of the SCM with ordinary Portland concrete and the study experimentally focuses on corrosion resistance evaluation of ternary blended concrete subjected to chloride attack. In this study, 50% replacement ratio of mineral admixture to OPC was used, while series of combination of $20{\sim}40%$ GGBS, $5{\sim}15%$ SF and $10{\sim}45%$ PFA binder were used for chloride corrosion resistance test. This study concerned the durability properties of the ternary blended concrete including the corrosion resistance, chloride binding, chloride transport and acid neutralization capacity. It was found that the ternary blended concrete utilizing the SCM densified the pore structures to lower the rate of chloride transport. Also, increased chloride binding and buffering to acid were observed for the ternary blended concrete with chlorides in cast.

Properties of Carbon-Rich Particles and Purified Ash Obtained from Countercurrent Column Flotation (부유분리법에 의해 분리한 고순도 정제석탄회와 고탄소 석탄회의 특성)

  • 이정언;안영철;김성찬;구재현;나성수;신진혁;이재근
    • Resources Recycling
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    • v.8 no.4
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    • pp.11-19
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    • 1999
  • Fly ash generated from (he pulverized coal power plant have caused the serious ocean pollution due to the disposal in the ash pond, the life reduction of a power plant and the waste of re-utilizable resource The research to reuse the unburned carbon and mineral composing of the ash has been progressed. In this study. the physical and chemical characteristics of high grade ash and unburned carbon particles obtained from countercurrent column flotation are investigated. The cleaned ash of the less 0,5% loss on Ignition(LOI) in carbon content is a spherical sphere and 39.8${\mu}m$ in size of MMD(Mass Median Diameter). 2.22 $m^2/g$ of specific area. The morphology of high LOI carbon particles is a amorphousness, 76.6 ${\mu}m$ of particle size and 15.2 $m^2/g$ of specific The high grade cleaned ash and the high LOI ash have some difference in the light of physical. chemical and morphological characteristics

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Recycling of Waste XLPE Using a Modular Intermeshing Co-Rotating Twin Screw Extruder (모듈라 치합형 동방향회전 이축 스크류식 압출기를 이용한 폐 XLPE의 재활용)

  • Bang, Dae-Suk;Oh, Soo-Seok;Lee, Jong-Keun
    • Elastomers and Composites
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    • v.39 no.2
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    • pp.131-141
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    • 2004
  • The recycling of waste XLPE(crosslinked polyethylene), which is a major source of scraps from high voltage power transmission cables, has been discussed. The waste XLPE scraps were ground into fine powder with various sizes from less than $100{\mu}m$ up to about $1000{\mu}m$ using two types of tailor-made pulverizers. The compounds were prepared in a modular intermeshing co-rotating twin screw extruder at various conditions such as different compositions, types and powder sizes of waste XLPE, screw configurations and various polymer matrices (LDPE, HDPE, PP, PS). The mechanical and rheological properties and the fracture surface or the compounds were investigated. It was found that an improved impact strength was obtained from the compound with white XLPE powder pulverized from the scraps without outer/inner semi-conductive layers. Generally, the impact strength increases with the content of XLPE but decreases with the size of XLPE. Especially for LDPE, the extrusion was possible up to 80 wt% loading of XLPE. Also, the impact strength increases with the number of kneading disc blocks in the given screw configurations. The melt viscosity of the compounds increases with increasing XLPE loading. However, the higher shear thinning behavior of the compounds at common shear rates implies proper processibility of the compounds. In addition, the impact strength for other polymer matrices used increases with XLPE and it is noticeable that the impact strength of PS/XLPE (80/20 wt%) compound was improved twice that of pure PS.

Characterization of Heavy Metals Including Mercury and Fine Particulate Emitted from a Circulating Fluidized Bed Power Plant Firing Anthracite Coals (무연탄 순환유동층 발전소로부터 배출되는 수은을 포함한 중금속 및 미세분진의 배출 특성)

  • Kim, Jeong-Hun;Yoo, Jong-Ik;Seo, Yong-Chil
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.268-274
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    • 2010
  • Emission of heavy metals as hazardous air pollutants has been focused with tightening regulatory limits due to their hazardousness. Measurements and characteristic investigations of heavy metals emitted from a commercial power plant burning anthracite coal have been carried out. The plant consists of a circulating fluidized bed combustor, a cyclone, a boiler and an electrostatic precipitator(ESP) in series. Dust and gaseous samples were collected to measure main heavy metals including gaseous mercury before ESP and at stack. Dust emissions as total particulate matter (TPM), PM-10 and PM-2.5 at inlet of ESP were very high with 23,274, 9,555 and $7,790mg/Sm^3$, respectively, as expected, which is much higher than those from pulverized coal power plants. However TPM at stack was less than $0.16mg/Sm^3$, due to high dust removal efficiency by ESP. Similarly heavy metals emission showed high collection efficiency across ESP. From particle size distribution and metal enrichment in sizes, several metal concentrations could be correlated with particle size showing more enrichment in smaller particles. Mercury unlike other solid metals behaved differently by emitting as gaseous state due to high volatility. Removal of mercury was quite less than other metals due to it's volatility, which was 68% only. Across ESP, speciation change of mercury from elemental to oxidized was clearly shown so that elemental mercury was half of total mercury at stack unlike other coal power plants which equipped wet a scrubber.

Analysis for Water Vapour Adsorption and Desorption Performance of Waste Paper-Mulberry according to Particle Size Control (폐닥나무의 입도제어에 따른 흡·방습 특성 분석)

  • Jo, Ki-Sic;Kim, Tae-Yeon;Seo, Sung-Kwan;Lee, Oh-Kyu;Chu, Yong-Sik
    • Resources Recycling
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    • v.29 no.2
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    • pp.8-17
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    • 2020
  • In this study, adsorption and desorption characteristics of pulverized waste paper-mulberry pellet and bast fiber were measured to confirm the applicability to humidity control products. Paper-mulberry powder was classified by 710-355㎛, 355-100㎛, 100-45㎛ and less than 45㎛ and used in experiment. Specific surface area increased from 1.02㎡/g to 1.35㎡/g as the particle size decreased from 710㎛ to under 45㎛. Adsorption and desorption performance decreased in the order of 355-100㎛, 710-355㎛, 100-45㎛, less than 45㎛ and bast fiber, adsorption content on each particle sizes were 141.1g/㎡, 147.1g/㎡, 135.7g/㎡, 129.0g/㎡ and desorption content were 117.2g/㎡, 123.6g/㎡, 110.2g/㎡, 93.3g/㎡. As a result, adsorption and desorption performance of paper-mulberry powder were superior to those of the bast fiber and these phenomenon can be considered that it caused by pore distribution in pellet and damage of fiber.

Leaching of Copper from Waste Printed Circuit Boards Using Electro-generated Chlorine in Hydrochloric Acid (전해생성(電解生成)된 염소(鹽素)에 의한 폐인쇄회로기판(廢印刷會路基板)으로부터 동(銅)의 침출(浸出))

  • Kim, Min-Seuk;Lee, Jae-Chun;Jeong, Jin-Ki;Kim, Byung-Su;Kim, Eun-Young
    • Resources Recycling
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    • v.14 no.5 s.67
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    • pp.45-53
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    • 2005
  • Electro-generated chlorine leaching of waste printed circuit boards was investigated in hydrochloric acid solutions. Non-magnetic component of $0.6{\sim}1.2mm$ was prepared by grinding, magnetic separation, and sieving. The non-magnetic component of pulverized printed circuit board contained about 45% of metal component, in which copper was about 83.6%. The leaching rate of copper was greatly affected by current density and agitation speed. The leaching of copper up to 98% was achieved at $20mA/cm^2$, $50^{\circ}C$, 180 minutes, and 600 rpm in 1M HCl solutions. Increasing agitation and lowering current density enhanced utilization efficiency of electro-generated chlorine. Leaching of copper was suppressed at the initial stage, while the minor metal elements, such as aluminum, lead, and tin, were dominantly leached out.

Separation of Tantalum from Electronic Components on Laptop Printed Circuit Board Assembly (노트북 인쇄회로기판 전자부품으로부터 탄탈럼의 분리)

  • Kwon, Seokje;Park, Seungsoo;Kim, Seongmin;Joe, Aram;Song, Youjin;Park, Poongwon;Park, Jaikoo
    • Resources Recycling
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    • v.25 no.1
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    • pp.24-30
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    • 2016
  • The study to obtain tantalum concentration from electronic components (ECs) on Printed circuit board assembly (PCBA) of laptop was conducted. Electronic components on laptop PCBA were detached from boards by using self-developed experimental apparatus. The detached electronic components were sieved and 93.2 wt.% of tantalum capacitors were concentrated from the size interval from 2.80 mm to 6.35 mm. The tantalum capacitors were pulverized by hammer mill and electrodes (anode and cathode) were removed from the grinding products by using magnetic separators under the magnetic force of 300 Gauss. Finally, tantalum concentrate was concentrated from the magnetic separator products by using Knelson concentrator, and the maximum efficiency of 76.9% was achieved under the operating condition of bowl rotating speed of 200 rpm, and fluidizing water flowrate of 7 L/min. The grade and recovery of Ta concentrate under the condition were 81.1% and 78.8%, respectively.

Preparation and Thermal Stability of FeS2 Fine Powder for Thermal Battery (열전지용 FeS2 미세 분말의 제조 및 열적 안정성)

  • Choi, Yusong;Yu, Hye-Ryeon;Cheong, Haewon;Cho, Sungbaek;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.72-77
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    • 2014
  • Microstructure and thermal stability of mechanically ball milled $FeS_2$ were investigated. The average particle size and distribution of $FeS_2$ powder were changed in two steps with the increased ball milling time. The average particle size drastically decreased from $98.4{\mu}m$ to 1.01 and $0.89{\mu}m$ after ball milling of 10 h and 30 h, respectively. However, the distribution was broad and a shoulder appeared at $2{\mu}m$ because the pulverization was still in process at 10 h ball milling. After 60 h ball milling, the distribution became narrower. After ball milling of 120 h, the average particle size increased because of $FeS_2$ particle agglomeration. Therefore, the particle size distribution became broaden again. Finally, after ball milling of 170 h, $FeS_2$ with the narrowest size distribution can be obtained. Thermal stability of $FeS_2$ was unstable as the $FeS_2$ particle was pulverized. Therefore, the activation energy of the fine size particles is 27% lower than that of the as-received $FeS_2$.

Discrimination of Geographical Origin for Herbal Medicine by Mineral Content Analysis with Energy Dispersive X-Ray Fluorescence Spectrometer (에너지분산형 X-선 형광분석기를 이용한 한약재의 무기질 분석 및 이에 의한 원산지 판별)

  • Jeong, Myeong-Sil;Lee, Soo-Bok
    • Korean Journal of Food Science and Technology
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    • v.40 no.2
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    • pp.135-140
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    • 2008
  • In this study, the macromineral content ratios of four herbal medicine samples(Saposhnikoviae Radix, Bupleuri Radix, Cnidii Rhizoma, and Astragali Radix) were analyzed to discriminate their geographical origins using an energydispersive x-ray fluorescence (EDXRF) technique. EDXRF is a rapid, non-destructive, and multi-elemental analysis technique. Initially, samples of both domestic and imported herbal medicines were pulverized, and then their macromineral contents, including P, S, K, and Ca, were analyzed using EDXRF. For the discrimination of their geographical origins, canonical discriminant analysis was carried out based on the estimated macromineral relative content ratios of the samples. According to the results, the discrimination accuracies were as follows: 93.3% for Saposhnikoviae Radix, 95.7% for Bupleuri Radix, 98.8% for Cnidii Rhizoma, and 87.5% for Astragali Radix. Overall, the results imply that this technique could be used as a standard method, to discriminate their geographical origins between domestic and imported herbal medicines.

Effect of rice variety on the processability for preparing rice cookies (쌀 품종이 쿠키 가공적성에 미치는 영향)

  • Kang, Tae-Young;Jo, Hye-Eun;Sohn, Kee Hyuk;Yoon, Mi-Ra;Lee, Jeom-Sig;Lee, Suyong;Ko, Sanghoon
    • Korean Journal of Food Science and Technology
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    • v.48 no.5
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    • pp.492-495
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    • 2016
  • This study aimed at investigating the influence of different rice varieties (Palbangmi, Saegoami, Mimyeon, Dasan-1, Hanarm, Boramchan, and Baegjinju) on the preparation process of rice cookies. Rice grains were pulverized by dry milling and subsequently screened using a 100-mesh sieve. Dasan-1, Hanarm, and Palbangmi flours showed low water absorption index (WAI) compared to other rice flours. The spread ratios of the cookies prepared with Dasan-1, Hanarm, and Palbangmi flours reached higher values than those obtained with other rice varieties. As a result, the hardness of the cookies prepared with Dasan-1, Hanarm, and Palbangmi flours was relatively low. On the contrary, cookies prepared with Saegoami, Boramchan, and Baegjinju flours showed inadequate qualities because they contained relatively high levels of damaged starch, which increased water absorption in the cookie dough. The WAI value of rice flour could be the most important indicator to determine the quality of rice cookies.