• 제목/요약/키워드: pulp

검색결과 3,936건 처리시간 0.028초

금속 이온에 의한 과산화수소의 촉매분해 (Catalytic Decomposition of Hydrogen Peroxide by Transition Metal Ions)

  • 김세종;윤병호
    • 펄프종이기술
    • /
    • 제38권3호
    • /
    • pp.79-84
    • /
    • 2006
  • Hydrogen peroxide has been a bleaching chemical for varied pulp, especially mechanical and deinking pulp. It is catalytically decomposed by some transition metals in pulp slurry. In this paper, some metals which can be contained in pulp such as manganese, copper, iron, magnesium and calcium were used to investigate their effect on the decomposition of hydrogen peroxide. From the result, hydrogen peroxide was more decomposed in the order of Mn, Cu, $Fe^{3+}\;and\;Fe^{2+}$, while Mg and Ca had little effect on the decomposition of hydrogen peroxide. The effect of Mg/Mn ratio on the decomposition of hydrogen peroxide was also investigated. At the specific ratio of them(Mg/Mn=10), hindering effect of peroxide decomposition by Mg was decreased.

Wet compaction test를 이용한 혼합지료의 적용 (Application of WCT (Wet Compaction Test) to Mixed Fiber Furnishes)

  • 서영범;이춘한
    • 펄프종이기술
    • /
    • 제37권4호통권112호
    • /
    • pp.8-17
    • /
    • 2005
  • WCT (Wet compaction test) is a new fiber evaluation method developed recently by Seo and its test results can be used as a predictor for pulp quality and its paper property Bleached chemical pulps (SwBKP, HwBKP), recycled pulp (OCC), and mechanical pulp (BCTMP) were used for the furnishes to be tested by WCT We compared the WCT results to conventional fiber evaluation tests such as WRV (Water Retention Value), free ness, and fiber length in this study, and found that WCT always gave better regression coefficients in relation to pulp quality (drainage), and paper properties (density, tensile, tear, and burst strength). WCT may be used on-line in papermachine.

Deinking of ONP with Cellulolytic Enzymes and Synthetic Collecter in Alkaline pH

  • Yoon, Kyong-Dong;Eom, Tae-Jin
    • 한국펄프종이공학회:학술대회논문집
    • /
    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
    • /
    • pp.451-454
    • /
    • 2006
  • This paper presents an overview of ONP deinking efficiency with cellulolytic enzymes and synthetic collector in alkaline pH. Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently - often much more efficiently. We propose the blended deinking agent with cellulolutic enzymes and synthetic collector in deinking pulp of conventional alkaline method. The deinking efficiency of old news print in alkaline pH was enhanced with enzyme treatments. The brightness of deinked pulp was increased with less residual ink particles and yield of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method.

  • PDF

효소처리에 의한 제지적성 개선

  • 김형진;조병묵
    • 한국펄프종이공학회:학술대회논문집
    • /
    • 한국펄프종이공학회 2000년도 춘계학술발표논문집
    • /
    • pp.39-46
    • /
    • 2000
  • In pulp and papermaking process, enzymatic treatment of pulp fibres has been a topic of increasing interest in last decade. Lots of patents, papers and research reports were published on the application of enzymes in the fields of enzymatic bleaching, deinking, slime control, pitch control, waste water treatment and fibre modification. Cellulase and hemicellulase are the principal enzymes used for the modification of fibre property. This study was carried out for determinating the behaviors of enzyme to pulp fibres. A commercial enzyme, Denimax BT which is consisted with cellulase and hemicellulase, was treated to the kraft pulp produced from domestic hardwood mixtures. Results were mainly concentrated on the behaviors of freeness, drainability and fines content of fibres, and physical properties of paper with enzyme treatment. The freeness levels and dewatering ability were developed, and the fines contents were decreased. The creation of fines were controlled by the method of pre-enzyme treatment prior to fibre beating. The mechanical strength of paper, like tensile, burst, tear strength and folding endurance, were remarkably improved by the pre-enzyme treatment.

  • PDF

Effect of Urea Addition on Soda Pulping of Oak Wood

  • Cho, Nam-Seok;Matsumoto, Yuji
    • 한국펄프종이공학회:학술대회논문집
    • /
    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
    • /
    • pp.285-290
    • /
    • 2006
  • As an alternative method to solve air pollution problem and difficulty of pulp bleaching of kraft pulping process, NaOH-Urea pulping was applied. The properties of NaOH-Urea pulp were compared to those of NaOH and kraft pulps. Addition of urea in low alkali charges retarded delignification rate compared to NaOH pulping. But, in high alkali application, delignification was significantly enhanced not from the addition of urea but from the high alkalinity. It was disclosed that urea did not participate on delignification reaction by the experiment using lignin model compound. Compared to paper strengths at the same level of sheet density, NaOH-Urea pulp gave as almost same breaking length and tensile index as those of kraft pulp. Especially tensile energy absorption and burst index were higher than those of kraft pulp.

  • PDF

Use of Polycarboxylic Acid to Inhibit Heat-and Moisture-Induced Yellowing of ECF/TCF Bleached Hardwood Kraft Pulp

  • Kawae, Ayano;Uchida, Yosuke
    • 한국펄프종이공학회:학술대회논문집
    • /
    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
    • /
    • pp.331-336
    • /
    • 2006
  • The aim of this work was to inhibit the heat-and moisture-induced yellowing of ECF/TCF bleached hard wood kraft pulp (HBKP) retaining hexenuronic acid (HexA). We have already reported that one of the derivatives of HexA, 5-formyl-2-furancarboxylic acid (FFA), causes yellowing of HBKP in acidic paper, and that FFA might polymerize or react with pulp components to form new chromophoric groups (1). In this study, it was shown that the carboxylic base of FFA interacts with that of glucuronic acid or galacturonic acid, resulting in strong yellowing. Therefore, it seems that preventing the reaction of carboxylic bases could be effective in suppressing this yellowing. We have discovered that polycarboxylic acids (for example, citric acid, tartaric acid, etc.) are useful as a yellowing inhibitor.

  • PDF

White ledger 오존 탈묵의 현미경적 관찰 (Microscopic Observation of White Ledger Ozone Deinking)

  • 원종명;윤승락
    • 펄프종이기술
    • /
    • 제32권2호
    • /
    • pp.40-44
    • /
    • 2000
  • A microscopic study was carried out to get the fundamental informations for the ozone deinking technology. The differential interference microscopic observation showed that ozone treatment was helpful to detach the toner ink from the surface of pulp fiber. The modifications of fiber surfaces by ozone treatment were observed with scanning electron microscope. Modification of fiber surfaces was not severe at the early stage of ozone treatment, but it increased with ozone treatment time and pulp consistency, Therefore, it would be possible to improve the properties of deinked pulp by controlling the condtion of ozone treatment.

  • PDF

Pulp and Paper from Kenaf Bast Fibers

  • Ashori Alireza
    • Fibers and Polymers
    • /
    • 제7권1호
    • /
    • pp.26-29
    • /
    • 2006
  • Samples of kenaf (Hibiscus cannabinus) grown in Malaysia were examined to determine the kraft pulp and paper-making properties of their bast (or bark) fibers. Using kraft pulping process showed that bast fibers were relatively easy to cook resulting good pulp yields in the range of 45-51 %. The bast pulp produced sheets with great density, tear index and dry zero-span breaking length. Kenaf bast fiber is considered promising for production of high-grade printing, writing and specialty papers.