• Title/Summary/Keyword: pseudoplastic

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Rheological Properties of Gelatinized Chestnut Starch Solution (밤전분 호화액의 유동특성)

  • Park, Young-Hee;Kim, Sung-Kon;Lee, Shin-Young;Kim, Ju-Bong
    • Korean Journal of Food Science and Technology
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    • v.16 no.3
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    • pp.314-318
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    • 1984
  • Rheological properties of gelatinized chestnut starch solution were investigated with a narrow gap rotational viscometer. The starch solutions at 1.2-1.8% concentration showed pseudoplastic behaviour with yield stress. At higher concentrations (1.65 and 1.8%), the starch solution showed more pseudoplastic tendency and time-dependent characteristics. Values of yield stress were small and independent of concentrations 1.2, 1.35 and 1.5%. Significant increase of yield stress was observed at 1.65% concentration. Consistency index was exponentially dependent on concentration and temperature. The activation energy for 1.65% starch solution was about 5 Kcal/g.mol.

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New Extracellular Biopolymer Produced by Methylobacterium organophilum from Methanol (Methylobacterium organophilum에 의한 메탄올로부터 생성되는 새로운 생물고분자)

  • Choi, Joon H.;Lee, Un T.;Kim, Jung H.;Rhee, Joon S.
    • Microbiology and Biotechnology Letters
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    • v.17 no.4
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    • pp.397-402
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    • 1989
  • A new extracellular biopolymer was produced by Methylobacterium organophilum from methanol as a sole carbon and energy source. The purified biopolymer was found to have a high molecular weight of about 4-5$\times$10$^6$ dalton and contained 66% (w/w) of carbohydrate but no polyhydro xybutyrate. Other organic constituents were consisted of protein, pyruvic acid, uronic acid, and acetic acid, whereas content of inorganic ash was 22%. Based on the chemical analysis of the biopolymer by TLC method, the polymer was consisted of glucose, galactose, and mannose with an approximate molar ratio of 2:3:2. The biopolymer solution showed a characteristics of pseudoplastic non-Newtonian fluid. The viscosity of the 1%-biopolymer solution was found to be 18,000 cp at a shear rate, 1 sec$^{-1}$, which was almost 10 times higher than that of a commercial xanthan gum.

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A Study on Compression Molding Process of Long Fiber Reinforced Plastic Composites -Effect of Needle Punching on Viscosity- (장섬유강화 플라스틱 복합재의 압축성형 공정에 관한 연구 -점도에 미치는 니들펀칭의 영향-)

  • 송기형;조선형;이용신
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.184-187
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    • 2002
  • Compression molding was specifically developed for replacement of metal components with composites. As the mechanical properties of the products are dependent on the separation and orientation, it is important to research the fiber mat structure and molding conditions. In this study, the effects of the fiber mat structure(NP: 5, 10, 25punches/$\textrm{cm}^2$) and the mold closure speed($\dot{\textrm{h}}$=0.1, 1, 10mm/min) on the viscosity of composites were discussed. The composites is treated as a Non-Newtonian power-law fluid. The parallel-plate plastometer is used and the viscosity is obtained from the relationship between the compression load and the thickness of the specimen.

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Effects of Temperature and Concentration on the Rheological Properties of the Biopolymer Produced by Bacillus sp. K-1 Strain and Mutants (Bacillus sp. K-1과 변이주들에 의해 생산된 Biopolymer의 물성에 미치는 온도 및 농도의 영향)

  • Jeong, Nak-Hyeon;Yun, Gwang-Seop;Im, Mu-Hyeon
    • Food Science and Preservation
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    • v.4 no.3
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    • pp.343-349
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    • 1997
  • The rheological Voperties of biopolymers produced by Bacilli sp. K-1 and its mutant strains(KM-21, KM-83) were studied at the temperature ranges with 20∼80$^{\circ}C$, at the concenration of 2∼6%, at the pH ranges from 3.0 to 9.0 and at the shear rate of 9.3-930sec-1 The apparent viscosity of biopolymers was decreased with increasing shear rate, and thereby biopolymers showed pseudoplastic characteristics. It was found that the apparent viscosity models respected 19 temperature, concentration and both temperature and concentration were expressed by Arrhenius Model, Exponential Model and combined of the above two Models. Therefore, the apparent viscosity could be predictable by Arrhenius and Exponential Models with high R2.

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Effects of Particle Size of Alumina on the Behaviors of Tape Casting and Sintering of Alumina-Talc System (알루미나-활석계에서 알루미나의 입자 크기가 테이프 케스팅 및 소결 거동에 미치는 영향)

  • 윤원균;김호양;이정아;김정주
    • Journal of the Korean Ceramic Society
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    • v.34 no.12
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    • pp.1213-1220
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    • 1997
  • Effect of particle size of alumina and amount of talc on tape casting and densification behaviors of alumina-talc system were investigated. The pseudoplastic behaviors of slurries increased with increase in amount of talc addition and decrease in alumina particle size. In case of using coarse alumina powder, densification of specimens were accelerated with increase of sintering temperature and amount of talc addition. On the contrary, fine alumina powder retarded of rearrangement of alumina particle during liquid phase sintering due to premature densification of alumina matrix region before formation of liquid phase and then densification of specimens were suppressed with increase of sintering temperature and amount of talc addition.

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Flow Properties of Doenjang (시판된장의 리올로지(Rheology) 특성에 관한 연구)

  • 양신철;김선화
    • Journal of Applied Tourism Food and Beverage Management and Research
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    • v.13 no.1
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    • pp.55-68
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    • 2002
  • Flow properties of doenjang samples at various total solid contents (30, 32, 34, 36, 38, 40%) were evaluated in this study. Flow properties of doenjang samples was determined by using Haake concentric cylinderical viscometer and Instron testing machine with capillary extrusion viscometer, and consistency index(K), and flow behavior index(n) was also determined from power models, and yield stress was derived form Casson models and vanes methods. Doenjang samples showed shear-thinning (pseudoplastic) fluid with small magnitude of flow behavior index(n) (n=0.30-0.55). Casson yield stress was from 2.11 to 64.02(Pa). Vane yield stress was more effective than casson yield stress in property of reactivation. Apparent viscosity was decreased with the increase in temperature and activation energy was in the range of 6.58 to 10.70 kJ/mole. From the capillary extrusion method, K and n was increased with the increase in solid content with good correlation with. The result revealed that capillary extrusion method is useful for measuring the flow properties of doenjang.

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Rheological Properties of Biopolymer Produced by Pseudomonas delafieldii (Pseudomonas delafieldii가 생성하는 다당류의 레올로지 특성)

  • Yoo, Jin-Young;Chung, Dong-Hyo
    • Microbiology and Biotechnology Letters
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    • v.17 no.5
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    • pp.475-480
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    • 1989
  • The extracellular polysaccharide was isolated from the culture of Ps. delafieldii and its rheological property was evaluated. The aqueous solution was extremely viscous and shows pseudoplastic behaviour. The flow behaviour index and apparent viscosity of 1 %solution were 0.09 and 1169 mPa·s. The solution was stable over pH change but did not have thermal stability. The activation energy of flow of 1 % solution was 4.44 kcal/mole. The concentration dependency could be expressed double logarithmically.

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Rheological Properties of Mycelial Broth in Submerged Culture of Aspergillus niger No. PFST-38

  • Oh, Sung-Hoon;O, Pyong-Su
    • Journal of Microbiology and Biotechnology
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    • v.3 no.3
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    • pp.209-213
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    • 1993
  • The flow behavior of the mycelial broth of glucoamylase hyperproducer Asp. niger No. PFST-38 for the production of glucoamylase were studied. The mycelial broth followed Bingham-pseudoplastic flow model described by Herschel-Bulkley equation. The yield stress increased with the increase in mycelial concentration. The dependency of the consistency index and the flow behavior index on the mycelial concentration could be expressed by a linear relationship. The consistency index increased proportionally with the mycelial concentration while the flow behavior index decreased with the increase in mycelial concentration. The flow property of the broth was related to the morphological data obtain in the previous study. The changes in apparent viscosity of the broth could be expressed as a function of the hyphal thickness as shown below.

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Fabrication of Discontinuous Al2O3-Dispersed TZP Fibers by a Sol-Gel Method (졸-겔법을 이용한 Al2O3가 분산된 TZP 단섬유의 제조)

  • Sim, Soo-Man
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.56-60
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    • 2015
  • Discontinuous, polycrystalline $Al_2O_3$-dispersed TZP fibers were prepared by the centrifugal spinning of a colloidal $ZrO_2$ sol containing Y and Al nitrates and poly(vinyl alcohol). Factors affecting the rheological properties of the sols, such as sol concentrations, aging, and the amounts and types of additives, were investigated by measuring the shear viscosities. The flow characteristics of the sols were studied in relation to the spinnability by measuring the viscosity with respect to the shear rate. The spinnability was obtained through the addition of a polymer which increases the viscosity to a range of optimum viscosity values for spinning. Aging the sols containing the additives did not noticeably change the sol viscosities at room temperature up to 30 days. The flow behavior of the spinnable sols progressively changed from nearly Newtonian to pseudoplastic with an increase in the sol concentration.

Flow Analysis with Ratio of Expansional /Contractional Viscosity during Compression Molding of Continuous Fiber-Reinforced Polymeric Composites (연속섬유강화 플라스틱 복합재의 압축성형에 있어서 확대/축소 점도비를 고려한 유동해석)

  • Kim, Hyeong-Cheol;Chae, Gyeong-Cheol;Jo, Seon-Hyeong;Kim, Lee-Gon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.3 s.174
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    • pp.581-592
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    • 2000
  • To obtain an excellent product and decide on optimum molding conditions, it is important to establish the relationship between molding conditions and viscosity. The composites is treated as a pseudoplastic fluid, and the expansional/contractional viscosity of the fiber-reinforced polymeric composites is measured using the parallel plastometer, and the model for flow state has been simulated with the viscosity. The effects of expansional slip parameter $\alpha_{e}$, and expansional/contractional viscosity ratio ${\mu}_{\gamma}$, on the mold filling parameters are also discussed.