• Title/Summary/Keyword: pseudoplastic

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Flow Behaviors of Native and Gelatinized Rice Starch Solutions (쌀 전분의 현탁액과 호화액의 유동 거동)

  • Lee, Shin-Young;Pyun, Yu-Ryang;Cho, Hyung-Yong;Yu, Ju-Hyun;Lee, Sang-Kyu
    • Korean Journal of Food Science and Technology
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    • v.16 no.1
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    • pp.29-36
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    • 1984
  • Flow behaviors of rice starch-water systems containing 3-9% (w/v) of native and gelatinized starch solutions were studied with the capillary tube rheometer in the temperature range of $30-80^{\circ}C$. Flow behaviors of rice starch-water systems showed non-Newtonion behavior which could be expressed as ${\gamma}{\;}=\;{\psi}(^{\tau}g_c-{\tau}_yg_c)^N$. Flow parameters ${\psi}$, N and $^{\tau}_y$ were determined for native and gelatinized solutions. These parameters indicated that native rice starch solution shows a dilatancy and the gelatinized solution ranges from pseudoplastic to mixed type flow behavior with increasing concentrations. The value of flow behavior index for gelatinized solutions was about 1.2 in all samples but for native solutions, the values were 0.87-0.90. The values of yield stress, which were negligible below 5%, were increased with the increase in concentration from 5 to 9%. The value of consistency index was exponentially dependent on concentration and temperature. The values of activation energy for native and gelatinized solutions were 0.13-2.71 and 5.39-9.57 kcal/g mole, respectively.

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Physicochemical Characteristics of Rice Flour Gelatinized by Extrusion-Cooking (압출성형에 의한 알파미분의 물리화학적 특성)

  • Han, Ouk;Lee, Sang-Hyo;Lee, Hyun-Yu;Kim, Young-Myoung;Min, Byong-Lyoung
    • Korean Journal of Food Science and Technology
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    • v.20 no.4
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    • pp.470-475
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    • 1988
  • The extrusion-cooking method was used to make gelatinized rice extrudate from rice grits of the Chuchung and the Samgang varieties. The water contents of raw rice grits varied from 15% to 25%, and the physicochemical properties of extrudates were evaluated. Low moisture content showed high expansion ratio in rice extrudate and resulted in some decrease in gelatinization, bulk density and break strength. Increasing the water content to 25% resulted in increase in water absoption index but decrease in water solubility index. With regards to Brabender Amylograph values and rheological patterns, higher moisture content in raw materials revealed stronger pseudoplastic flow behavior with lower viscogram property. Hunter's color values of rice flours extruded at low water content were low in b values. Scanning electron microscopy demonstrated the break-down of starch granules during extrusion.

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Rheological Properties of Dandelion Root Concentrates by Extraction Solvents

  • Lee, Ok-Hwan;Kang, Suk-Nam;Lee, Boo-Yong
    • Food Science and Biotechnology
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    • v.15 no.1
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    • pp.33-38
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    • 2006
  • This study was performed to provide basic rheological data of dandelion root concentrates in order to predict their processing aptitude and usefulness as functional foods material. The hot water and 70% ethanol extracts of dandelion root were concentrated at 5, 20, and 50 Brix, and their static viscosity, dynamic viscosity, and Arrhenius plots were investigated. Almost all hot water concentrates showed the typical flow properties of a pseudoplastic fluid, but evaluation using the power law model indicated that the 70% ethanol concentrates showed a flow behavior close to a Newtonian fluid. The apparent viscosity of hot water and 70% ethanol concentrates decreased with increasing temperature. Yield stresses of hot water and 70% ethanol concentrates by Herschel-Bulkley model application were in the range of 0.026 - 1.368 Pa and 0.022 - 0.238 Pa, respectively. The effect of temperature and concentration on the apparent viscosity was examined by Arrhenius equation. The activation energies of hot water and 70% ethanol concentrates were in the range of $8.762-23.778{\times}10^3\;J/mol{\cdot}kg$ and $3.217-20.384{\times}10^3\;J/mol{\cdot}kg$ with increasing concentration, respectively. Storage (G') and loss (G") moduli were generally increased with increasing frequency. For the 70% ethanol concentrates, G" predominated over G' at all applied frequencies and so they showed the typical flow behavior of a low molecular solution. However, for the hot water concentrates, G' predominated over G" at more than 1.9 rad/sec (cross-over point) and so they showed the typical flow behavior of a macromolecular solution.

Topical Formulation and Antimicrobial Activity of Ketonic Fraction from Leptospermum scoparium (Leptospermum scoparium의 케톤체 분획물을 함유한 외용제제의 항균력)

  • Kim, Eun-Hee;Hwang, Sung-Joo;Park, Song-Hee;Park, Seung-Youg;Rhee, Gye-Ju
    • Journal of Pharmaceutical Investigation
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    • v.30 no.3
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    • pp.151-158
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    • 2000
  • Gel and cream containing 5% and 10% ketonic fraction (KF) of Leptospermum scoparium, respectively were formulated. Antimicrobial activity, stability, anti-inflammatory effect, rheological properties, drug release and acute toxicity for these topical efficacy were evaluated. Gel and cream containing neomycin or gentamycin in combination with KF has potent antimicrobial activity. Gel and cream were physically stable and did not show any creaming for 6 months storage. Gel showed plastic flow with yield value and cream showed pseudoplastic flow with hysteresis loop. The gel and cream containing KF showed higher viscosity than control or commercial one. The viscosity increased as the concentration of KF increased. Both 10% gel and cream showed a significant decrease in swelling when applied to the carrageenan- injected paw, suggesting local antiinflammatory activity. Particularly, 10% gel preparation showed similar antiinflammatory activity when compared with commercially available drugs. Percent of drug released and diffusion coefficient were in the order of 5% gel, 10% gel, 5% cream, and 10% cream, respectively. There were no significant changes of body weight in rats percutaneously administered with 10% cream and gel when compared with control. There were no induced acute toxicity when 10% cream or gel was applied to rats. Leptospermum scoparium could be practicaly used in topical preparations.

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Rheological Properties of Fucoidans from Laminaria religiosa, Sporophylls of Undaria pinnatifida, Hizikia fusiforme and Sagassum fulvellum in Korea (국내산 다시마, 미역포자엽, 톳, 모자반 fucoidan의 리올리지 특성)

  • KOO Jae-Geun;JO Kil-Suk;PARK Jin-Hee
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.3
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    • pp.329-333
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    • 1997
  • Rheological properties of partially purified fucoidans of Laminaria religiosa, sporophylls of Undaria pinnatifida, Hizikia fusiforme, and Sargassum fulvellum in Korea were investigated, The fucoidans produced aqueous solutions of low apparent viscosity with pseudoplastic flow behavior. The viscosity of $5\%$ solution of the fucoidan from sporophylls of U. pinnatifida was 2.2 mPa.s. The activaton energies of L. religiosa, sporophylls of U. pinnatifida, H. fusiforme and S. fulvellum were $8.269\times10^6,\;7.498\times10^6,\;7.141\times10^6,\;and\;6.677\times10^6\;J/Kg.mol$ at 1,500 1/s of shear rate, respectively. The viscosity of the fucoidan solution was increased by the addition of sugar, but that was not changed by addition of NaCl.

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Flow Properties of Red Flower Cabbage Pigment Solutions (꽃양배추 색소 추출액의 유동특성)

  • Rhim, Jong-Whan;Lee, Jung-Ju
    • Korean Journal of Food Science and Technology
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    • v.33 no.2
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    • pp.221-225
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    • 2001
  • Flow properties of red flower cabbage pigment solutions were determined over a wide range of temperatures ($20-50^{\circ}C$) and soluble solid concentrations (1-65%) using a cone and plate rotational viscometer. Flow properties of the pigment solutions were adequately described by the simple power law model. Within the tested ranges of concentration, temperature and shear rate, the flow behavior index (n) and the consistency index (K) of the solutions were in the ranges of 0.841-0.998 and $0.008-31.525\;Pa{\cdot}s^n$, respectively. The effect of temperature on the apparent viscosity of the solutions followed an Arrhenius type relationship. Activation energy of flow varied from 9.36 to 52.48 kJ/mol depending on the solid concentration and shear rate. The combined effect of temperature and concentration on the apparent viscosity at the shear rate of $100\;s^{-1}$ could be represented by a single equation as ${\ln}\;{\eta}_a\;=\;6.11\;-\;3103.94(1/T)\;-\;0.03C$.

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Rheological Properties of Mungbean Starch (녹두전분의 리올로지 성질)

  • Kweon, Soon-Hye;Kim, Myung-Hee;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.22 no.1
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    • pp.38-43
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    • 1990
  • Effects of concentration (5-8%, db) and heating temperature $(80^{\circ}C-95^{\circ}C)$ on rheological of mungbean starch were examined. The pasting curve by amylograph revealed no peak viscosity and the viscosity continued to increase during cooking, regardless the starch concentrations. Mungbean starch paste showed a pseudoplastic flow behavior with yield stress. The consistency index of paste increased as the heating temperature was raised at a given concentration. However, flow behavior index showed opposite trend. The percent sag of starch gel stored at $4^{\circ}C$ decreased with the increase of concentration and heating temperature. The firmness of fresh gel prepared from 7 and 8% starch suspensions by heating at $95^{\circ}C$ for 15 min with amylograph was about 2-times higher than that of 6% gel. However, the time constant, reciprocal of rate constant, of starch gels during aging at $4^{\circ}C$ was not significantly influenced by concentrations and heating temperatures.

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Rheological Properties of Soymilk and Curd Prepared with Micronized Full-fat Soyflour (콩미세분말로 제조된 두유 및 전두부의 물성)

  • 심재진;서지현;소한섭;유병승;이삼빈
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.1
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    • pp.75-81
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    • 2003
  • Rheological properties of micronized full-fat soyflour (MFS ) milk were determined according to solid content, heat-treatment and type of coagulants. Heat-treated MFS milk showed a pseudoplastic flow pattern. The consistency and flow index of heated MFS milk was greatly affected by increasing the concentration of MFS and/or soy protein isolate (SPI). Apparent viscosity of MFS milk was gradually decreased by heating below 6$0^{\circ}C$, but was drastically increased by raising temperature further. Addition of coagulants and SPI resulted in dropping the temperature that allows to increase apparent viscosity drastically. A coagulant for MFS tofu was formulated based on the gelling Property of a single coagulant. The textural properties of MFS tofu were improved using 7.1% total protein fortified with SPI.

Dynamic Characteristics of External loop Air-Lift Reactor (외부 순환 공기리프트 반응기의 동특성)

  • 강귀현;김춘영정봉우
    • KSBB Journal
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    • v.7 no.1
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    • pp.59-65
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    • 1992
  • Hydrodynamics and mixing characteristics such as circulation time, mixing time, circulation velocity and axial dispersion coefficient were investigated using highly viscous pseudoplastic solutions of carboxymethyl cellulose(CMC) in an external circulation loop air-lift reactor with 13$\ell$ working volume. The superficial gas velocity was changed from 1.9 to 6.2cm/s and CMC concentration from 0 to 1.0wt%. The theoretical model based on the pressure balance is developed mathematically to predict liquid circulation velocity. Gas hold-up, circulation velocity and axial dispersion coefficient of liquid phase increased with increasing gas velocity and decreased slightly with increasing liquid viscosity. Mixing time and circulation time decreased with increasing gas velocity and increased with increasing liquid viscosity. Experimental data on liquid circulation velocity were in good agreement with the predicted values.

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Effect of Phosphate on Rheological Properties of Gelatinized Rice Starch Solution (인산염이 쌀 전분 호화액의 리올로지에 미치는 영향)

  • Kim, Il-Hwan;Kim, Sung-Kun;Lee, Shin-Young
    • Korean Journal of Food Science and Technology
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    • v.19 no.4
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    • pp.366-370
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    • 1987
  • Rheological properties of gelatinized rice starch solutions (5%) were examined with a Brookifield viscometer. Gelatinized rice starch solutions showed pseudoplastic flow having yield stress, i.e., Binghamplastic flow behavior. The yield stress of gelatinized rice starch solutions was reduced by the phosphate. Phosphate increased the pseudoplasticity of gelatinized nonwaxy rice starch solutions. but decreased that of gelatinized waxy rice starch solution. The yield stress of gelatinized nonwaxy rice starch solutions held for one hour at $90^{\circ}C$ was slightly decreased, but that of waxy starch solution was reduced by 10-fold. Phosphate reduced the yield stress for both gelatinized nonwaxy and waxy rice starch solutions. Phosphate decreased the consistency index, but did not affect the flow behavior index of the gelatinized rice starch solutions.

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